公开(公告)号：KR1020120097986A

公开(公告)日：2012-09-05

申请号：KR1020110017620

申请日：2011-02-28

Applicant: 충남대학교산학협력단

Inventor： 이용택 ,  공창인 ,  염인아 ,  오덕규

IPC: B01D69/12 ,  B01D69/02 ,  B01D71/00

CPC classification number: B01D69/12 ,  B01D69/02 ,  B01D71/028 ,  B01D2323/02 ,  B01D2325/04

Abstract: PURPOSE: A method for manufacturing a polyvinyl alcohol(PVA)-zeolite composite membrane and a method for manufacturing the same are provided to concentrate organic materials by efficiently separating water from the mixture of the water and the organic materials. CONSTITUTION: A method for manufacturing a PVA-zeolite composite membrane includes the following: a PVA aqueous solution containing 5-20 weight% of PVA and 80-95 weight% of distilled water based on the total weight of the aqueous solution is prepared; 5-10 parts by weight of a cross-linking agent is added into 100 parts by weight of the PVA aqueous solution, and the mixture is stirred for 12 hours to 3 days at a temperature between 5 and 40 degrees Celsius; zeolite powder is added into the stirred solution and is stirred for 12 hours to 10 days at a temperature between 5 and 40 degrees Celsius to prepare a PVA-zeolite solution; and the PVA-zeolite solution is applied and dried for 20 to 50 hours at a temperature between 30 and 100 degrees Celsius to obtain a PVA-zeolite composite membrane.

Abstract translation: 目的：提供一种聚乙烯醇（PVA） - 沸石复合膜的制造方法及其制造方法，通过有效地从水和有机材料的混合物中分离水来浓缩有机材料。 构成：制造PVA-沸石复合膜的方法包括以下步骤：制备基于水溶液总重量的含5-20重量％PVA和80-95重量％蒸馏水的PVA水溶液; 将5-10重量份交联剂加入到100重量份的PVA水溶液中，并将混合物在5至40摄氏度的温度下搅拌12小时至3天; 将沸石粉末加入到搅拌的溶液中，并在5至40摄氏度的温度下搅拌12小时至10天以制备PVA-沸石溶液; 并将PVA-沸石溶液在30至100摄氏度的温度下进行20-50小时的干燥，得到PVA-沸石复合膜。

公开(公告)号：KR1020120097987A

公开(公告)日：2012-09-05

申请号：KR1020110017621

申请日：2011-02-28

Applicant: 충남대학교산학협력단

Inventor： 이용택 ,  조문희 ,  염인아 ,  오덕규

IPC: B82B3/00 ,  B82Y30/00

CPC classification number: C01B39/14 ,  B82Y30/00 ,  B82Y40/00 ,  C01P2004/64

Abstract: PURPOSE: A manufacturing method of hydrophilic NaA zeolite nano-particles is provided to enhance dispersibility between particles and to obtain uniformity of particle sizes. CONSTITUTION: A manufacturing method of hydrophilic NaA zeolite nano-particles comprises the following steps: manufacturing a solution I by including 40-60 wt% of silica sol and 40-60 wt% of distilled water based on the total weight of the solution I; manufacturing a solution II by including 5-7 wt% of Al (OiPr), 30-40 wt% of tetramethyl ammonium hydroxide 5 hydrate (TMAOH·5H2O), 3-5 wt% of 1M NaOH and 50-60 wt% of H2O based on the total weight of the solution II; agitating the solution I and solution II by mixing at the weight ratio of 1:2-1:5 at room temperature for 12 hours-10 days; and agitating the mixture of the solution I and II in a 60-100 deg. Celsius thermo-bath for 5 hours-3 days.

Abstract translation: 目的：提供亲水性NaA沸石纳米颗粒的制造方法，以增强颗粒间的分散性，并获得粒径的均匀性。 构成：亲水性NaA沸石纳米粒子的制造方法包括以下步骤：通过包含40-60重量％的硅溶胶和基于溶液I的总重量的40-60重量％的蒸馏水来制备溶液I. 通过包括5-7重量％的Al（OiPr），30-40重量％的氢氧化四甲基氢氧化物5水合物（TMAOH·5H 2 O），3-5重量％的1M NaOH和50-60重量％的H 2 O制备溶液II 基于溶液II的总重量; 通过在室温下以1：2-1：5的重量比混合12小时-10天来搅拌溶液I和溶液II; 并在60-100℃搅拌溶液I和II的混合物。 摄氏温度5〜3天。