公开(公告)号：KR101308021B1

公开(公告)日：2013-10-15

申请号：KR1020120031854

申请日：2012-03-28

Applicant: 한국과학기술연구원

Inventor： 최웅수 ,  고영건 ,  신승수

IPC: B01J20/26 ,  C07F7/04 ,  C08G73/02

CPC classification number: B01J20/30 ,  B01J20/26 ,  C07F7/04

Abstract: PURPOSE: A surface structure in which a polyamine and a substrate are chemically combined, and a manufacturing method thereof are provided to have the surface structure which implements an excellent carbon dioxide adsorption quantity and high operation effect in the separation process; and capable of being reused. CONSTITUTION: A manufacturing method of a surface structure comprises the following steps. A step of combining a substrate in which a silane compound which includes a carbon double bond which is represented as the chemical formula 1 is chemically combined on the surface of the substrate which includes silicon; a step of forming a polyamine in which the polyamine which is represented as the chemical formula 3 forms the substrate which is chemically combined according to a reaction between silane compound which is represented as the chemical formula 1 in which the surface and one end of the substrate are chemically combined; and primary amine which is represented as the chemical formula 2. a, b, c and n are the whole number of 0-5 in the chemical formula 1. m is the whole number of 0-5 in the chemical formula 2. [Reference numerals] (AA) Silicon and silicon compound in which hydratory is combined; (BB) Silicon and silicon compound in which carbon double bond is combined; (CC) Silicon and silicon compound in which Polyallylamineis combined

Abstract translation: 目的：将多胺和基材化学结合的表面结构体及其制造方法设置为具有在分离过程中实现优异的二氧化碳吸附量和高操作效果的表面结构; 并能够重复使用。 构成：表面结构的制造方法包括以下步骤。 将包含表示为化学式1的包含碳双键的硅烷化合物的基板在包含硅的基板的表面上化学结合的基板的组合步骤; 形成多胺的步骤，其中以化学式3表示的多胺形成基于化学组合的基板，该基板根据其中表面为化学式1的硅烷化合物之间的反应，其中基板的表面和一端 化学结合; 和表示为化学式2的伯胺.a，b，c和n在化学式1中为0-5的整数。m是化学式2中0-5的整数。[参考 数字]（AA）组合水合的硅和硅化合物; （BB）其中碳双键结合的硅和硅化合物; （CC）其中聚烯丙基胺组合的硅和硅化合物