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公开(公告)号：KR102238320B1
公开(公告)日：2021-04-09
申请号：KR1020190006806A
申请日：2019-01-18
Applicant: 한국과학기술연구원
CPC classification number: G01N33/246 , G01V99/005
Abstract: 본 발명은 강우량 및 지하수위 변동에 따라 깊이가 변동되는 불포화대를 모사함에 있어서 지반모사장치의 길이가 선택적으로 조절되도록 함과 다양한 지점에서의 유체 유출입 및 특성평가가 가능하도록 함으로써 불포화대의 물리화학적 특성 및 생물학적 특성을 정확하게 평가할 수 있는 불포화대 지반모사장치에 관한 것으로서, 본 발명에 따른 불포화대 지반모사장치는 수직방향을 따라 배열, 결합되어 불포화대를 모사하는 상단 컬럼부, 중단 컬럼부 및 하단 컬럼부를 포함하여 이루어지며, 상기 중단 컬럼부는 복수개의 단위 컬럼으로 구성되며, 중단 컬럼부를 구성하는 단위 컬럼의 개수 조절을 통해 지반모사장치와 불포화대의 길이를 축척상 일치시킬 수 있으며, 각각의 단위 컬럼 내에 불포화대의 깊이 방향에 따른 성상을 반영한 지반을 모사하는 것을 특징으로 한다.
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Patent Agency Ranking
公开(公告)号：KR101441570B1
公开(公告)日：2014-09-24
申请号：KR1020130017532
申请日：2013-02-19
Applicant: 한국과학기술연구원
Abstract: 본 발명은 나노영가철(nZVI) 표면에 지질층(脂質層, lipids)을 구비시킴으로써 나노영가철(nZVI) 표면에 산화막이 형성되는 것을 방지함과 함께 유기오염물질의 흡착특성을 향상시킬 수 있는 지질층을 구비한 나노영가철 및 그 제조방법에 관한 것으로서, 본 발명에 따른 지질층을 구비한 나노영가철은 나노영가철; 및 상기 나노영가철 표면에 구비되며, 상기 나노영가철과 킬레이트 결합을 이루는 지질층을 포함하여 이루어지는 것을 특징으로 하며, 상기 지질층은 카르복실산을 포함하는 물질이며, 올레인산 또는 트리올레인산으로 구성될 수 있다.
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公开(公告)号：KR101438505B1
公开(公告)日：2014-09-12
申请号：KR1020130076728
申请日：2013-07-01
Applicant: 한국과학기술연구원
Abstract: The present invention relates to an alginate-based composite carrier containing nano zero-valent iron and lipids. Nano zero-valent iron (nZVI) in an alginate bead is solidified so that the nano zero-valent iron (nZVI) is prevented from being agglomerated. Through the combination of the nano zero-valent iron (nZVI) and lipids, it is prevented that an oxide film is formed on the surface of the nano zero-valent iron (nZVI), and adsorption properties of organic contaminants can be improved. The alginate-based composite carrier according to the present invention comprises: a spherical alginate bead; a nano zero-valent iron fixed in the alginate bead; and a lipid layer which is formed in the alginate bead and bonded with the surface of the nano zero-valent iron.
Abstract translation: 本发明涉及含有纳米零价铁和脂质的藻酸盐基复合载体。 藻酸盐珠中的纳米零价铁（nZVI）被固化，使得防止纳米零价铁（nZVI）聚集。 通过纳米零价铁（nZVI）和脂质的组合，可以防止在纳米零价铁（nZVI）的表面上形成氧化膜，并且可以提高有机污染物的吸附性能。 根据本发明的藻酸盐基复合载体包括：球形藻酸盐珠粒; 固定在藻酸盐珠中的纳米零价铁; 以及在藻酸盐珠中形成并与纳米零价铁的表面结合的脂质层。
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公开(公告)号：KR101439408B1
公开(公告)日：2014-09-11
申请号：KR1020130125289
申请日：2013-10-21
Applicant: 한국과학기술연구원
Abstract: The present invention relates to nano zero-valent iron, a composite media having a liquid-based core-shell structure and a method for preparing the same in which nano zero-valent iron is provided on a core region, and hydrophobic lipid is provided on a core-shell region to suppress oxide film formation by hydrophilic inorganic ions. Organic matter is prevented from being deposited on a surface of the nano zero-valent iron to suppress a reduction in reactivity of the nano zero-valent iron, and selective reactivity with respect to a hydrophobic chlorinated organic compound is increased to improve a decomposition characteristic of a specific chlorinated organic compound. A method for preparing nano zero-valent iron and a composite media having a liquid-based core-shell structure is characterized by comprising the steps of: preparing an alginate solution in which the nano zero-valent iron is dispersed; dropping into a curing solution to cure the alginate solution, to thus prepare a first alginate bead in which the nano zero-valent iron is immobilized; introducing the first alginate bead into to form a solution layer on a surface of the first alginate bead; and dropping the first alginate bead on which the solution layer is formed into the curing solution to cure the first alginate bead in a second alginate bead shape, and thus prepare a composite media comprised of a core region that is comprised of the first alginate bead, and a shell region that is comprised of the second alginate bead formed on the surface of the first alginate bead.
Abstract translation: 本发明涉及纳米零价铁，具有液态核 - 壳结构的复合介质及其制备方法，其中在核心区域上提供纳米零价铁，疏水性脂质提供在 用于抑制亲水性无机离子形成氧化膜的核 - 壳区域。 防止有机物沉积在纳米零价铁的表面上，以抑制纳米零价铁的反应性降低，并且提高对疏水性氯化有机化合物的选择反应性，以提高分解特性 特定的氯化有机化合物。 制备纳米零价铁的方法和具有液体核 - 壳结构的复合介质的特征在于包括以下步骤：制备其中分散有纳米零价铁的藻酸盐溶液; 将其中分散有纳米零价铁的藻酸盐溶液滴加到固化溶液中以固化藻酸盐溶液，从而制备其中固定有纳米零价铁的第一藻酸盐珠粒; 将第一藻酸盐珠粒引入到其中分散脂质的藻酸盐溶液中以在第一藻酸盐珠粒的表面上形成溶液层; 并将其上形成有溶液层的第一藻酸盐珠粒滴加到固化溶液中以使第一藻酸盐珠粒形状固化，从而制备由包含第一藻酸盐珠粒的核心区域组成的复合介质， 以及由形成在第一藻酸盐珠粒表面上的第二藻酸盐珠粒组成的壳区域。
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5.发明公开
公开(公告)号：KR1020140104567A
公开(公告)日：2014-08-29
申请号：KR1020130017532
申请日：2013-02-19
Applicant: 한국과학기술연구원
Abstract: The present invention relates to zero-valent iron including lipids and a manufacturing method thereof. The present invention can prevent the formation of an oxide membrane on the surface of nanosize zero-valent iron (nZVI) by placing lipids on the surface of the nanosize zero-valent iron (nZVI), and can improve the adsorption of organic pollutants. The nanosize zero-valent iron including lipids according to the present invention comprises nanosize zero-valent iron; and lipids arranged on the surface of the nanosize zero-valent iron and chelated by the nanosize zero-valent iron. The lipids are materials including carboxylic acids and may be composed of oleic acid or trioleic acid.
Abstract translation: 本发明涉及包含脂质的零价铁及其制造方法。 本发明可以通过在纳米级零价铁（nZVI）的表面上放置脂质来防止在纳米零价铁（nZVI）的表面上形成氧化膜，并可以改善有机污染物的吸附。 包含根据本发明的脂质的纳米级零价铁包括纳米级零价铁; 和纳米级零价铁表面上的脂质，并由纳米级零价铁螯合。 脂质是包括羧酸的材料，并且可以由油酸或三油酸组成。
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公开(公告)号：KR102238320B1
公开(公告)日：2021-04-09
申请号：KR1020190006806
申请日：2019-01-18
Applicant: 한국과학기술연구원
Abstract: 본발명은강우량및 지하수위변동에따라깊이가변동되는불포화대를모사함에있어서지반모사장치의길이가선택적으로조절되도록함과다양한지점에서의유체유출입및 특성평가가가능하도록함으로써불포화대의물리화학적특성및 생물학적특성을정확하게평가할수 있는불포화대지반모사장치에관한것으로서, 본발명에따른불포화대지반모사장치는수직방향을따라배열, 결합되어불포화대를모사하는상단컬럼부, 중단컬럼부및 하단컬럼부를포함하여이루어지며, 상기중단컬럼부는복수개의단위컬럼으로구성되며, 중단컬럼부를구성하는단위컬럼의개수조절을통해지반모사장치와불포화대의길이를축척상일치시킬수 있으며, 각각의단위컬럼내에불포화대의깊이방향에따른성상을반영한지반을모사하는것을특징으로한다.
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