公开(公告)号：KR100811116B1

公开(公告)日：2008-03-06

申请号：KR1020060112215

申请日：2006-11-14

Applicant: 한국과학기술연구원

Inventor： 심재혁 ,  진선아 ,  조영환

IPC: C01B3/00 ,  C01F5/00

CPC classification number: C01B3/0026 ,  C01B3/0078 ,  Y02E60/327 ,  Y10S420/90

Abstract: A method for preparing magnesium-based hydrogen storage materials is provided to improve the hydrogen storage rate of magnesium hydroxide while minimizing the reduction of hydrogen storage capacity of the magnesium hydroxide, by using high-energy ball milling. A mixture of magnesium hydroxide and transition metal halide is formed(S10). The mixture and balls are inputted into a case(S20). Inert gas or hydrogen gas fills the case(S30). A high-energy ball milling process is performed on the mixture for 5-30 minutes(S40). In the step of forming the mixture, 0.1-5 mol% of transition metal halide powder is added based on the mixture. The balls have diameters of 5-30 mm. A weight ratio of the mixture to the balls is 1:1-1:100.

Abstract translation: 提供一种制备镁基储氢材料的方法，以通过使用高能球磨将氢氧化镁的储氢能力降至最低，从而提高氢氧化镁的储氢率。 形成氢氧化镁和过渡金属卤化物的混合物（S10）。 将混合物和球输入到壳体（S20）中。 惰性气体或氢气填充（S30）。 在混合物上进行高能球磨过程5-30分钟（S40）。 在形成混合物的步骤中，基于该混合物加入0.1-5mol％的过渡金属卤化物粉末。 球的直径为5-30毫米。 混合物与球的重量比为1:1-1:100。

公开(公告)号：KR101001946B1

公开(公告)日：2010-12-17

申请号：KR1020080103633

申请日：2008-10-22

Applicant: 한국과학기술연구원

Inventor： 이영수 ,  진선아 ,  심재혁 ,  조영환

IPC: C01B6/15

Abstract: 수소 저장 물질 및 그 제조 방법에서, 수소 저장 물질은 리튬붕소수소화물과 세륨계 물질의 혼합체를 포함한다. 따라서, 리튬붕소수소화물 및 세륨계 물질을 혼합함으로 두 물질 간의 화학반응을 통해 순수한 리튬붕소수소화물과 비교하여 낮은 온도에서 탈수소화반응을 일으킬 수 있다. 또한, 탈수소생성물의 수소화반응이 상대적으로 용이하여 탈수소화/수소화 반응의 가역성을 높일 수 있다.
수소저장, 수소화, 탈수소화, 가역성

公开(公告)号：KR1020100044482A

公开(公告)日：2010-04-30

申请号：KR1020080103633

申请日：2008-10-22

Applicant: 한국과학기술연구원

Inventor： 이영수 ,  진선아 ,  심재혁 ,  조영환

IPC: C01B6/15

CPC classification number: C01B35/04 ,  C01B3/001 ,  C01F17/00

Abstract: PURPOSE: A hydrogen storage material and a manufacturing method thereof are provided to facilitate a hydrogenation of a dehydrogenated product in a lower temperature, and to improve reversibility of the dehydrogenation and the hydrogenation. CONSTITUTION: A hydrogen storage material includes lithium borohydride and a cerium-based material. The cerium-based material can form cerium hydride by reacting with the cerium hydride, metal cerium and the lithium borohydride. The molar ratio of the cerium hydride for the lithium borohydride is 3:1~10:1. The manufacturing method of the hydrogen storage material comprises the following steps: forming mixed powder including the lithium borohydride and the cerium-based material(S100); and ball-milling the mixed powder(S200).

Abstract translation: 目的：提供储氢材料及其制造方法，以便于在较低温度下氢化脱氢产物，并提高脱氢和氢化的可逆性。 构成：储氢材料包括硼氢化锂和铈基材料。 铈基材料可以通过与氢化铈，金属铈和硼氢化锂反应而形成氢化铈。 硼氢化锂的氢化铈摩尔比为3：1〜10：1。 储氢材料的制造方法包括以下步骤：形成包括硼氢化锂和铈基材料的混合粉末（S100）; 并对该混合粉末进行球磨（S200）。