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公开(公告)号：KR1020130125744A
公开(公告)日：2013-11-19
申请号：KR1020130119137
申请日：2013-10-07
Applicant: 한국과학기술연구원
CPC classification number: Y02A50/235 , B01D53/32 , B01D53/86 , B01D2251/104 , B01D2257/708 , B01D2259/804 , B01D2259/818
Abstract: As a method for treating volatile organic compounds in the atmosphere, a method for removing volatile organic compounds which includes a step of generating ozone and a step of generating reaction active species, whereby the volatile organic compounds are decomposed. [Reference numerals] (1) Ozone generator;(2) Air blower;(3) Catalyst layer;(AA) Polluted gas to be treated;(BB) Purified gas
Abstract translation: 作为用于处理大气中的挥发性有机化合物的方法，包括产生臭氧的步骤的挥发性有机化合物的除去方法和产生反应活性物质的步骤，由此使挥发性有机化合物分解。 （附图标记）（1）臭氧发生器;（2）鼓风机;（3）催化剂层;（AA）待处理的污染气体;（BB）净化气体
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公开(公告)号：KR101094672B1
公开(公告)日：2011-12-20
申请号：KR1020090022412
申请日：2009-03-17
Applicant: 한국과학기술연구원
CPC classification number: B01D53/261 , B01D53/56 , B01D53/8625 , B01D2251/104 , B01D2253/106 , B01D2255/104 , B01D2255/20723 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/20761 , B01D2257/404 , B01D2257/80
Abstract: 본 발명은 오존과 촉매 하이브리드 시스템을 이용한 질소산화물의 처리방법 및 처리장치에 관한 것으로, 구체적으로 1) 처리하고자 하는 질소산화물 오염공기의 수분을 제거하는 단계; 2) 수분이 제거된 질소산화물 오염공기를 오존과 접촉시켜 오염공기 내 일산화질소(NO)를 이산화질소(NO
2 )로 산화시키는 단계; 3) 잔여 오존을 촉매와 반응시켜 산소라디칼을 발생시킨 후 단계 2)를 거친 질소산화물 오염공기를 산소라디칼과 반응시켜 오염공기 내 이산화질소(NO
2 )를 질산기(NO
3
- )로 산화시키는 단계를 포함하는, 오존과 촉매 하이브리드 시스템을 이용한 질소산화물의 처리방법 및 처리장치에 관한 것이다. 본 발명에 따른 질소산화물의 처리방법 및 처리장치는 고온의 반응이나 환원제로 암모니아 가스의 사용 없이 상온에서 오존과 촉매 하이브리드 시스템을 이용하여 인체에 유해한 일산화질소, 이산화질소 등의 질소산화물을 효율적으로 제거함과 동시에 오존의 사용으로 인한 2차 대기오염을 예방할 수 있어 다양한 분야에서 질소산화물의 제거에 유용하게 적용될 수 있다.
질소산화물, 일산화질소, 이산화질소, 오존, 촉매, 하이브리드-
公开(公告)号：KR101030252B1
公开(公告)日：2011-04-22
申请号：KR1020100102577
申请日：2010-10-20
Applicant: 한국과학기술연구원
IPC: B82B3/00 , B01J37/02 , C23C16/442 , B01J8/00
CPC classification number: B01J37/0215 , B01J35/023 , B82Y40/00
Abstract: PURPOSE: An apparatus for preparing nanocatalyst is provided to obtain uniform catalytic particles on the surface of a three-dimensional base material by allowing the catalytic particles to be fluidized. CONSTITUTION: A precursor supplying part(110) supplies precursors. A catalytic particle synthesizing part(120) synthesizes catalytic particles(123) based on the chemical reaction of the precursors. A fluidizing and coating part(130) fluidizes a three-dimensional base material and coating the catalytic particles on the surface of the base material in order to form nanocatalyst. A catalytic particles inlet(133) is installed at one side of the fluidizing and coating part. An inert gas inlet(134) is installed at another side of the fluidizing and coating part. The base material is fluidized by the inert gas.
Abstract translation: 目的：提供一种制备纳米催化剂的装置，通过使催化剂颗粒流化，在三维基材表面获得均匀的催化剂颗粒。 构成：前体供应部分（110）供应前体。 催化颗粒合成部分（120）基于前体的化学反应合成催化剂颗粒（123）。 流化和涂覆部分（130）使三维基材流态化，并将催化颗粒涂覆在基材的表面上以形成纳米催化剂。 催化颗粒入口（133）安装在流化和涂覆部分的一侧。 惰性气体入口（134）安装在流化和涂覆部分的另一侧。 基体材料被惰性气体流化。
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4.发明授权
公开(公告)号：KR100887249B1
公开(公告)日：2009-03-06
申请号：KR1020070114494
申请日：2007-11-09
Applicant: 한국과학기술연구원
CPC classification number: B01J23/22 , B01D53/8662 , B01D2255/20707 , B01D2255/20723 , B01J35/0013 , B01J35/008 , B01J37/086
Abstract: A method for manufacturing a vanadia-titania catalyst is provided to degrade chlorinated organic compounds at a relatively low temperature by using a solvothermal synthesis process. A method for manufacturing a vanadia-titania catalyst comprises the following steps. A mixture of a titania precursor and a vanadia precursor is manufactured. The mixture is transferred to a high temperature portion of an electric furnace by using a transferring gas and protection air. The mixture is processed by a solvothermal synthesis process in the electric furnace. A vanadia particle is coated on a surface of a titanium dioxide carrier. A vanadia-titania catalyst is manufactured to form a core-shell shaped particle.
Abstract translation: 提供一种制备氧化钒 - 二氧化钛催化剂的方法，通过使用溶剂热合成方法在相对较低的温度下降解氯化有机化合物。 一种制备氧化钒 - 二氧化钛催化剂的方法包括以下步骤。 制备二氧化钛前体和氧钒前体的混合物。 通过使用转移气体和保护空气将混合物转移到电炉的高温部分。 该混合物通过电炉中的溶剂热合成方法进行处理。 将氧化钒颗粒涂覆在二氧化钛载体的表面上。 制造氧化钒 - 二氧化钛催化剂以形成核 - 壳形颗粒。
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公开(公告)号：KR100760236B1
公开(公告)日：2007-10-04
申请号：KR1020060019131
申请日：2006-02-28
Applicant: 한국과학기술연구원
Abstract: 본 발명은 연소 설비 배출 가스 중의 수은의 저감 방법에 관한 것이며, 보다 상세하게는 할로겐 화합물을 첨착한 활성탄을 분말상으로 연소 설비 배출 가스 중에 직접 혼합하여 투입하거나, 입상으로 고정상 흡착탑으로서 설치하여 배출 가스 중의 수은을 저감시키는 방법에 관한 것이다.
본 발명에 따라 연소 설비에 할로겐 화합물을 첨착한 활성탄을 사용하면 기존의 방법과 비교하여 연소 설비 배출 가스 중의 수은을 현저히 저감시켜, 연소 설비를 친환경적으로 운영할 수 있다.
연소 설비, 배출 가스, 수은, 요오드, 염소, 할로겐 화합물, 첨착 활성탄-
Patent Agency Ranking6.发明授权촉매 담지용 티타니아 담체, 이를 포함하는 망간산화물-티타니아 촉매, 그 제조장치 및 제조방법, 그리고 질소산화물의 제거방법 有权用于支持催化剂的泰坦尼亚载体，包含其的氧化锰 - 氧化钛催化剂，用于制备钛铁氧体和氧化锰 - 催化剂的装置和方法，以及除去氮氧化物的方法
公开(公告)号：KR101391814B1
公开(公告)日：2014-05-12
申请号：KR1020120069008
申请日：2012-06-27
Applicant: 한국과학기술연구원
CPC classification number: B01J21/063 , B01D53/9413 , B01D2255/20707 , B01D2255/2073 , B01D2255/9205 , B01D2255/9207 , B01J23/22 , B01J23/34 , B01J35/002 , B01J35/023 , B01J35/1019 , B01J35/1038 , B01J37/0201 , Y10T428/2982
Abstract: 본 발명은 질소산화물 제거용 촉매를 담지하기 위한 티타니아 담체, 이를 포함하는 망간산화물-티타니아 촉매, 그 제조장치 및 제조방법, 그리고 질소산화물의 제거방법에 관한 것이다. 본 발명은, 비표면적이 100㎡/g 내지 150㎡/g이고, 평균기공부피가 0.1㎤/g 내지 0.2㎤/g이며, 평균입자크기가 5㎚ 내지 20㎚인 것을 특징으로 하는 티타니아 담체, 이의 제조장치 및 제조방법을 제공한다. 또한, 본 발명은 상기 티타니아 담체에 망간산화물이 담지된 망간산화물-티타니아 촉매 및 그 제조방법, 그리고 상기 촉매를 이용한 질소산화물의 제거방법을 제공한다. 본 발명에 따르면, 촉매의 활성 및 분산도 등이 높아, 특히 200℃ 내외의 저온 영역대에서도 우수한 탈질 효율을 갖는다.
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公开(公告)号：KR1020140010558A
公开(公告)日：2014-01-27
申请号：KR1020120076675
申请日：2012-07-13
Applicant: 한국과학기술연구원
CPC classification number: B01J23/22 , B01D53/9409 , B01D53/9418 , B01D2255/20707 , B01D2255/20723 , B01D2255/9207 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J37/0201 , B01J37/0211 , B01J37/0213 , B01J37/0238
Abstract: The present invention relates to a vanadia-titania catalyst for removing nitrogen oxides and a manufacturing method thereof. The present invention provides a manufacturing method for the vanadia-titania catalyst for removing nitrogen oxides comprising: an evaporation step of vaporizing titanium precursors; a reactant transport step of transferring the vaporized titanium precursor with an oxygen source to a reaction part; a reaction step of making the vaporized titanium precursor transferred to the reaction part react with the oxygen source and synthesizing titania particles; a collection step of collecting the titania particles by condensing the titania particles; a mixture step of mixing the collected titania particles and a vanadium precursor solution; a dry step of drying the mixture of the titania particles and vanadium precursor solution; and a firing step of firing the dried mixture under oxygen or air, and vanadia-titania catalyst manufactured thereby. The present invention manufactures the vanadia-titania catalyst by being impregnated with vanadia through impregnation and burning on the titania particles (carriers), thereby having high specific surface area and uniform nanoparticle size, exhibiting the excellent dispersion of vanadia and showing excellent nitrogen oxide removal efficiency at low temperatures of 200-250°C. [Reference numerals] (AA) Dip vanadia; (BB) Titanium particles manufactured by a chemical vapor condensation method; (CC) Vanadia-titania catalyst (Example 1)
Abstract translation: 本发明涉及用于除去氮氧化物的氧化钒 - 二氧化钛催化剂及其制造方法。 本发明提供了用于除去氮氧化物的氧化钒 - 二氧化钛催化剂的制造方法，包括：蒸发钛前体的蒸发步骤; 将蒸发的钛前体与氧源转移到反应部分的反应物输送步骤; 使蒸发的钛前体转移到反应部分的反应步骤与氧源反应并合成二氧化钛颗粒; 收集二氧化钛粒子的收集工序; 混合收集的二氧化钛颗粒和钒前体溶液的混合步骤; 干燥二氧化钛颗粒和钒前体溶液的混合物的干燥步骤; 以及在氧气或空气下烧制干燥的混合物的煅烧步骤，以及由此制备的氧化钒 - 二氧化钛催化剂。 本发明通过在二氧化钛颗粒（载体）上浸渍和燃烧浸渍氧化钒，从而具有高比表面积和均匀的纳米颗粒尺寸，显示出优异的氧钒分散性并显示出优异的氮氧化物去除效率，从而制造氧化钒 - 二氧化钛催化剂 在200-250℃的低温下。 （标号）（AA）Dip vanadia; （BB）通过化学气相冷凝法制造的钛颗粒; （CC）氧钒二氧化钛催化剂（实施例1）
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公开(公告)号：KR100933876B1
公开(公告)日：2009-12-29
申请号：KR1020090063423
申请日：2009-07-13
IPC: C10M175/00 , C10M177/00
CPC classification number: C10M175/06 , C10M175/0016 , C10M175/0058 , C10N2040/16 , C10N2240/201
Abstract: PURPOSE: A recycle facility for waste material containing polychlorinated biphenyl is provided, which prevents explosion by blocking contact of powder metallic sodium and air. CONSTITUTION: A recycle facility for waste material comprises a device(220) for eliminating waste oil containing polychlorinated biphenyl; a waste oil storage tank(240); a device(250) for eliminating moisture and foreign material contained in the waste oil flowing in from the waste oil storage tank; and an apparatus for reducing concentration of polychlorinated biphenyl(270) which makes chlorine isolated from the polychlorinated biphenyl contained in the waste oil by reacting the waste with the powder metallic sodium.
Abstract translation: 目的：提供含有多氯联苯的废料回收设施，通过阻止粉末金属钠和空气的接触来防止爆炸。 构成：用于废料的回收设备包括用于消除含有多氯联苯的废油的装置（220） 废油储罐（240）; 用于消除从废油储存罐流入的废油中包含的水分和异物的装置（250）; 以及通过使废物与粉末状金属钠反应，从而使氯离子从废油中所含的多氯联苯中分离的多氯联苯（270）的浓度降低的装置。
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公开(公告)号：KR100400275B1
公开(公告)日：2003-10-10
申请号：KR1020010036057
申请日：2001-06-23
Applicant: 한국과학기술연구원
IPC: G01N9/32
Abstract: PURPOSE: An apparatus is provided to achieve improved efficiency of refrigerating machine by measuring, through the use of electric conductivity, refrigerant contamination index and LiBr(Lithium Bromide) solution concentration in an accurate and easy manner. CONSTITUTION: An apparatus comprises a high temperature regenerator(9) having a heating source; a low temperature regenerator(13) having, as a heating source, refrigerant vapor generated from the high temperature regenerator; a condenser(11) for cooling the refrigerant vapor generated from the low temperature regenerator; an evaporator(2) for generating cool water by the refrigerant solution generated from the condenser; an absorber(4) for absorbing the refrigerant vapor evaporated by the evaporator; an absorption solution pump(6) for feeding the dilute solution contained in the absorber to the high temperature regenerator through low temperature and high temperature heat exchangers(7,8); an absorption solution concentration detecting conductivity meter(21) arranged at the outlet pipe of the high temperature regenerator, which senses concentration of lithium bromide solution in a real time basis; a refrigerant circulation pump(17) for circulating refrigerant solution to the evaporator and to the high temperature regenerator when the refrigerant is polluted; a refrigerant contamination index detecting conductivity meter(22) arranged at the outlet pipe of the refrigerant circulation pump; absorption solution cutoff valves(26,27) for cutting off fuel and absorption solution flowing in the high temperature regenerator when the absorption solution has a concentration higher than a predetermined level; refrigerant cutoff valves(24,25) for cutting off refrigerant circulating to the evaporator and guiding the refrigerant toward the high temperature regenerator when the refrigerant contamination index is higher than a predetermined level; and a control unit(23) for receiving signals from the absorption solution concentration detecting conductivity meter and the refrigerant contamination index detecting conductivity meter and transmitting signals to valves.
Abstract translation: 目的：提供一种装置，通过使用电导率，准确和容易地测量制冷剂污染指数和溴化锂（溴化锂）溶液浓度，来提高制冷机的效率。 构成：一种设备包括具有加热源的高温再生器（9） 低温再生器（13），其具有从高温再生器产生的制冷剂蒸气作为加热源; 冷凝器（11），用于冷却从低温再生器产生的制冷剂蒸气; 蒸发器（2），用于通过冷凝器产生的制冷剂溶液产生冷却水; 吸收器（4），用于吸收由蒸发器蒸发的制冷剂蒸汽; 一个吸收溶液泵（6），用于通过低温和高温热交换器（7,8）将包含在吸收器中的稀溶液供给高温再生器; 布置在高温再生器的出口管上的吸收溶液浓度检测电导率计（21），其实时检测溴化锂溶液的浓度; 制冷剂循环泵（17），用于当制冷剂被污染时将制冷剂溶液循环至蒸发器和高温再生器; 检测制冷剂污染指数的电导率计（22），其设置在制冷剂循环泵的出口管上; 吸收液截止阀（26,27），用于在吸收液浓度高于预定水平时切断在高温再生器中流动的燃料和吸收液; 制冷剂截止阀（24,25），用于当制冷剂污染指数高于预定水平时，切断循环到蒸发器的制冷剂并将制冷剂导向高温再生器; 和一个控制单元（23），用于接收来自吸收溶液浓度检测电导率仪和制冷剂污染指数检测电导率仪的信号并将信号传送给阀。
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公开(公告)号：KR1020140096181A
公开(公告)日：2014-08-04
申请号：KR1020130008150
申请日：2013-01-24
Applicant: 한국과학기술연구원
CPC classification number: B01J19/2415 , B01J19/088 , B01J21/063 , B01J21/08 , B01J35/002 , B01J35/004 , B01J35/023 , B01J35/1014 , B01J37/0018 , B01J37/08 , B01J2219/00135 , B01J2219/00159 , C01G23/07 , C01G23/075 , C01P2002/72 , C01P2002/85 , C01P2004/04 , C01P2004/82
Abstract: The present invention relates to a manufacturing apparatus of a silica-titania catalyst and to a manufacturing method thereof. The present invention provides a manufacturing apparatus of a silica-titania catalyst and a manufacturing method of a silica-titania catalyst using the apparatus, the apparatus comprising: a precursor supplying part for vaporizing a silica precursor and a titania precursor and supplying the silica precursor and the titania precursor which have been vaporized to a reaction part; an oxygen supplying line for supplying an oxygen source to the reaction part; the reaction part for synthesizing vaporized products of the silica precursor and the titania precursor supplied from the precursor supplying part in order to generate the silica-titania catalyst; and a recovery part for cooling and condensing the silica-titania catalyst generated in the reaction part in order to recover the silica-titania catalyst. The recovery part includes a cooler for cooling the silica-titania catalyst flowing in from the reaction part, wherein the cooler has a swirl formation portion formed in a flow passage through which the silica-titania catalyst passes. According to the present invention, the silica-titania catalyst which has a high specific surface area, a uniform nanoparticle size and excellent thermal stability can be easily manufactured through a simple process using a chemical vapor condensation method.
Abstract translation: 本发明涉及二氧化硅 - 二氧化钛催化剂的制造装置及其制造方法。 本发明提供一种二氧化硅 - 二氧化钛催化剂的制造装置和使用该装置的二氧化硅 - 二氧化钛催化剂的制造方法，该装置包括：用于使二氧化硅前体和二氧化钛前体蒸发并供给二氧化硅前体的前体供给部， 已经蒸发到反应部分的二氧化钛前体; 用于向反应部供给氧源的氧供给管线; 用于合成二氧化硅前体的蒸发产物的反应部分和从前体供应部分供应的二氧化钛前体以产生二氧化硅 - 二氧化钛催化剂; 以及用于冷却和冷凝在反应部分中产生的二氧化硅 - 二氧化钛催化剂以回收二氧化硅 - 二氧化钛催化剂的回收部分。 回收部分包括用于冷却从反应部分流入的二氧化硅 - 二氧化钛催化剂的冷却器，其中冷却器具有形成在二氧化硅 - 二氧化钛催化剂通过的流动通道中的涡流形成部分。 根据本发明，通过使用化学气相冷凝法的简单方法，可以容易地制造具有高比表面积，均匀的纳米颗粒尺寸和优异的热稳定性的二氧化硅 - 二氧化钛催化剂。
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