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公开(公告)号：KR100068203B1
公开(公告)日：1993-12-02
申请号：KR1019910003947
申请日：1991-03-12
Applicant: 한국과학기술원
IPC: C07D251/56
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公开(公告)号：KR100340760B1
公开(公告)日：2002-06-20
申请号：KR1020000023417
申请日：2000-05-02
IPC: C07B55/00
Abstract: 본 발명은 4-(시스-2,6-다이메틸피페리딘)-(R)-다이나프토다이옥사포스페핀(Ⅰ), 4-(R,R-2,5-다이페닐피롤리딘)-(R)-다이나프토다이옥사포스페핀(Ⅱ)을 구리(Ⅱ)트리플레이트와 반응시켜 구리와 복합체를 형성하고, 이를 키랄 촉매로 사용하여 다이메틸징크를 2-시클로펜타데세논과 1,4-첨가반응시켜 고 광학순도, 고 수율로 (R)-(-)-무스콘(
l -muscone)을 입체선택적으로 제조하는 방법을 제공하는 것이다.-
Patent Agency Ranking
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公开(公告)号：KR1020000049811A
公开(公告)日：2000-08-05
申请号：KR1020000023417
申请日：2000-05-02
IPC: C07B55/00
CPC classification number: C07B55/00
Abstract: PURPOSE: A stereo-selective method for preparing (R)-(-)-muscone with high optical purity and high yield is provided. CONSTITUTION: A method for preparing (R)-(-)-muscone comprises steps of: (i) reacting 4-(cis-2, 6-dimethylpiperidine)-(R)-dinaphtodioxaphosphepin of the following formula (I) and 4-(R, R-2, 5-diphenylpyrrolidine)-(R)-dinaphtodioxaphosphepin of the following formula (II) with Cu(OTf)2 to form a complex with copper; and (ii) 1, 4-addition reacting dimethylzinc with 2-cyclopentadecenone using the complex of step (i) as a chiral catalyst.
Abstract translation: 目的：提供用于制备具有高光学纯度和高产率的（R） - （ - ） - 肌肉的立体选择性方法。 构成：制备（R） - （ - ） - 肌肉酮的方法包括以下步骤：（i）使下式（I）的4-（顺式-2,6-二甲基哌啶） - （R） - 二盐基二磷杂螺环和4- （II）的（R，R-2,5-二苯基吡咯烷） - （R） - 二萘氧基磷杂苯基与Cu（OTf）2形成与铜的络合物; 和（ii）使用步骤（i）的络合物作为手性催化剂，使二甲基锌与2-环戊烯酮1,4-加成反应。
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公开(公告)号：KR1019930005413B1
公开(公告)日：1993-06-21
申请号：KR1019910003947
申请日：1991-03-12
Applicant: 한국과학기술원
IPC: C07D251/56
Abstract: The method for preparing melamine comprises reacting a quanidine deriv. of formula (I) with hexamethyldisilazane (HMDS) as a catalyst and a solvent. In (I), R1 and R2=H, methyl or ethyl; if one of R1 and R2 is ethyl, the other is H. The quanidine deriv. of formula (I) is prepd. by reacting carbonate, chlorate, sulfate or nitrate of the cpd. with a methanol soln. of sodium methoxide. Melamine is a useful compound in the synthesis of aminoplastic polymers, dyestuffs, papers, paints or agricultural chemicals.
Abstract translation: 制备三聚氰胺的方法包括使喹啉衍生物反应。 式（I）与六甲基二硅氮烷（HMDS）作为催化剂和溶剂。 在（I）中，R 1和R 2 = H，甲基或乙基; 如果R1和R2之一是乙基，另一个是H. 式（I）的化合物是制备的。 通过使cpd的碳酸盐，氯酸盐，硫酸盐或硝酸盐反应。 与甲醇溶胶。 的甲醇钠。 三聚氰胺是合成氨基聚合物，染料，纸张，油漆或农药的有用化合物。
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公开(公告)号：KR100204659B1
公开(公告)日：1999-06-15
申请号：KR1019960018134
申请日：1996-05-28
IPC: C07D489/02
CPC classification number: C07D489/12
Abstract: 본 발명은 테바인을 출발물질로 하여 합성된 일반식(Ⅰ)의 진통제 화합물에 관한 것이다.
상기식에서 R은 수소, 메틸, 에틸 또는 시클로프로필이다. -
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