公开(公告)号：KR101204458B1

公开(公告)日：2012-11-23

申请号：KR1020110104177

申请日：2011-10-12

Applicant: 한국과학기술원

Inventor： 조성오 ,  김용남

IPC: C08J5/18 ,  C08K3/08 ,  C08J7/18 ,  G01N33/53

Abstract: PURPOSE: A manufacturing method of patterned octahedral gold nano-particle film using electronic beam irradiation, thermal process and washing and a patterned octahedron gold nano-particle film manufactured by the same are provided to effectively manufacture gold precursor - copolymer film. CONSTITUTION: A manufacturing method of patterned octahedral gold nano-particle film using electronic beam irradiation comprises the following steps: manufacturing a gold precursor - copolymer mixed solution by mixing gold precursors with copolymers; forming a composite film by coating the gold precursor-copolymer mixed solution on a substrate surface; forming a gold precursor - copolymer film which is patterned by selectively irradiating the gold precursor-copolymer film with electron beam and developing thereof; forming the octahedron gold nano-particle - copolymer film by heat-treating the patterned gold precursor - copolymer film; and manufacturing the octahedron gold nano-particle film by washing the patterned octahedron gold nano-particle copolymer film. [Reference numerals] (AA) Selective electromagnetic beam irradiation; (BB) Phenomenon; (CC) Patterned gold precursor-copolymer complex film; (DD) Heat treating; (EE) Copolymer film including octahedron gold nano-particle; (FF) Reactive ion etching; (GG) Carbon coated octahedron gold nano-particle film; (HH) Oxidation degradation; (II) Patterned octahedron gold nano-particle film

Abstract translation: 目的：提供使用电子束照射，热处理和洗涤的图案化八面体金纳米颗粒膜的制造方法和由其制造的图案化八面体金纳米颗粒膜，以有效地制造金前体共聚物膜。 构成：使用电子束照射的图案化八面体金纳米颗粒膜的制造方法包括以下步骤：通过将金前体与共聚物混合来制造金前体 - 共聚物混合溶液; 通过将金前体共聚物混合溶液涂布在基材表面上来形成复合膜; 形成通过用电子束选择性地照射金前体共聚物膜并显影的图案化的金前体共聚物膜; 通过热处理图案化的金前体 - 共聚物膜形成八面体金纳米颗粒 - 共聚物膜; 并通过洗涤图案化的八面体金纳米颗粒共聚物膜制造八面体金纳米颗粒膜。 （附图标记）（AA）选择性电磁波束照射; （BB）现象; （CC）图案金前体共聚物复合膜; （DD）热处理; （EE）包括八面体金纳米颗粒的共聚物膜; （FF）反应离子蚀刻; （GG）碳涂八面体金纳米颗粒膜; （HH）氧化降解; （二）图案八面体金纳米颗粒膜

公开(公告)号：KR101079744B1

公开(公告)日：2011-11-03

申请号：KR1020090003832

申请日：2009-01-16

Applicant: 한국과학기술원

Inventor： 조성오 ,  김용남

IPC: C08J5/18 ,  B29D7/01 ,  B82B3/00

Abstract: 본발명에따르면선택적전자선조사를통하여대면적에패턴화된금 전구체필름을효율적으로생산할수 있고, 열분해를통하여고순도의패턴화된금 전구체필름을대면적및 고속생산할수 있다. 또한, 본발명에따른금 나노입자필름은전기적, 광학적특성이매우우수하므로, 미소량의생화학물질을감지할수 있는민감도가우수한생화학센서로활용될수 있을뿐만아니라, 단백질과같은특정생물학적작용기를인식하는바이오칩 (biochip)에도유용하게사용할수 있다.

公开(公告)号：KR1020100084372A

公开(公告)日：2010-07-26

申请号：KR1020090003832

申请日：2009-01-16

Applicant: 한국과학기술원

Inventor： 조성오 ,  김용남

IPC: C08J5/18 ,  B29D7/01 ,  B82B3/00

Abstract: PURPOSE: A method for manufacturing patterned gold nanoparticle films is provided to efficiently produce a gold precursor film which is patterned on a large area through selective electron irradiation and to produce the patterned gold precursor film of high purity with a fast rate through pyrolysis. CONSTITUTION: A method for manufacturing patterned gold nanoparticle films comprises the following steps: manufacturing a gold precursor solution; manufacturing a gold precursor mixture solution by mixing a photosensitive and cationic polymer solution and ethylene glycol with the gold precursor solution; forming a gold precursor film by coating the mixture solution on the surface of a substrate; forming a patterned gold precursor film through development after crosslinking the precursor materials by selectively irradiating electron on the gold precursor film; and forming the gold nanoparticle film through the pyrolysis of the patterned gold precursor film.

Abstract translation: 目的：提供一种用于制造图案化的金纳米颗粒膜的方法，以有效地生产通过选择性电子辐射在大面积上图案化的金前体膜，并通过热解快速产生高纯度的图案化金前体膜。 构成：制造图案化金纳米颗粒膜的方法包括以下步骤：制备金前体溶液; 通过将光敏阳离子聚合物溶液和乙二醇与金前体溶液混合制备金前体混合物溶液; 通过将混合溶液涂布在基材的表面上形成金前体膜; 在通过在金前体膜上选择性地照射电子来交联前体材料之后，通过显影形成图案化的金前体膜; 并通过图案化的金前体膜的热解形成金纳米颗粒膜。