Abstract:
PURPOSE: A polymer electrolyte for a lithium secondary battery and the lithium secondary battery including the same are provided to improve the electro-chemical stability and the ion-conductivity of the electrolyte and to be manufactured without a photo-initiator. CONSTITUTION: A polymer electrolyte for a lithium secondary battery includes a porous matrix, a polymer, and an organic electrolyte. 50-60 weight% of a compound, which is formed on the porous matrix and includes two or more ethyleneically unsaturated groups and 40-50 weight% of a compound with two or more thiol groups are copolymerized to form the polymer. The organic electrolyte is impregnated to the polymer and includes lithium salt and a plasticizer. The porous matrix is one or more selected from a group including polyolefin unwoven fabric, a polyolefin membrane, a polycarbonate membrane, and glass fiber.
Abstract:
PURPOSE: Electrolyte for a lithium secondary cell is provided to improve physical stability of the negative electrode active material of a lithium secondary cell which electrochemically forms the alloy with lithium ions and to enhance the cycleability of the secondary battery. CONSTITUTION: Electrolyte for a lithium secondary cell comprises 0.1-10 parts by weight of tris(pentafluorophenyl) borane of chemical formula (1) based on 100 parts by weight of the electrolyte solution for the lithium secondary cell. The electrolyte for a lithium secondary cell includes an electrolytic solution for the lithium secondary cell. The lithium secondary cell includes a positive electrode, a negative electrode, and electrolyte. The negative electrode includes at least one selected from the group consisting of silicon, tin, antimony, and aluminum as an active material.
Abstract:
Provided are a manufacturing method of carbon fiber/metal oxide composite active material, in which a carbon fiber/metal oxide becomes a composite as one body, and a lithium/air secondary battery including the same. The carbon fiber/metal oxide composite according to the present invention is characterized in that a carbon fiber and a metal oxide form an integrated complex structure without using a separate polymer binder. Therefore, discharge capacity of the battery is increased more than that of a battery using the conventional carbon fiber, and a lithium/air secondary battery having excellent reversibility can be manufactured.
Abstract:
PURPOSE: A plastic crystal electrolyte for lithium secondary battery in which metal hydroxide is introduced, a manufacturing method thereof, and a lithium secondary battery including thereof are provided to suppress or alleviate combustion at high temperature. CONSTITUTION: A plastic crystal electrolyte for lithium secondary battery includes metal hydroxide. The metal hydroxide is used more than 20 parts by weight based on 100 parts by weight of electrolyte residue. A manufacturing method of the plastic crystal electrolyte comprises the following steps: dissolving linear polymer in solvent; manufacturing plastic crystal electrolyte mixed solution by adding lithium salt and metal hydroxide to plastic crystal material; and drying coated material after spreading the mixture on substrate.
Abstract:
본 발명에서는 하기 화학식1로 표시되는 트리페닐포스포란(triphenylphosphorane) 화합물을 포함하는 리튬이차전지용 전해액, 그를 이용한 리튬이차전지 및 리튬이차전지의 제조방법을 제공한다: [화학식1]
상기 식에서, R은 NR 1 또는 CR 1 R 2 이다 (이때, R 1 , R 2 는 각각 독립적으로 H 또는 C1-C10의 직쇄상, 분지상 또는 환상을 포함하는 포화 또는 불포화 탄화수소, CN, CHO, COCH 3 , COCO 2 C 2 H 5 , CO 2 CH 3 및 Si(CH 3 ) 3 로 구성된 군으로부터 선택되는 어느 하나의 치환체이다). 상이기 화학식1로 표시되는 화합물을 포함하는 전해액은 리튬이차전지의 고전압 충방전 수명을 향상시킬 수 있다.
Abstract translation:目的:提供一种用于锂二次电池的电解液,以通过包括三苯基正膦化合物来减少由活性材料和电解质引起的副反应,从而提高锂二次电池的寿命。 构成:用于锂二次电池的电解液包括由化学式1表示的三苯基正膦化合物。在化学式1中,R是N-R 1或CR 1 R 12。 在化学式1中,R 1和R 2两个选自H,C 1-10饱和或不饱和烃,CN,CHO,COCH 3,COCO 2 C 2 H 5,CO 2 CH 3和Si(CH 3)3。 锂二次电池包括正极,负极,正极和负极之间的隔板以及添加在正极和负极之间的电解质。
Abstract:
PURPOSE: An electrolyte solution for a lithium secondary battery is provided to reduce side reaction caused by active materials and electrolyte by including triphenylphosphorane compounds, thereby improving the lifetime of the lithium secondary battery. CONSTITUTION: An electrolyte solution for a lithium secondary battery includes a triphenylphosphorane compound represented by chemical formula 1. In chemical formula 1, R is N-R^1 or CR^1r^2. In chemical formula 1, each of R^1 and R^2 is one selected from H, C1-10 saturated or unsaturated hydrocarbon, CN, CHO, COCH3, COCO2C2H5, CO2CH3, and Si (CH3)3. A lithium secondary battery includes a positive electrode, negative electrode, a separator between the positive electrode and negative electrode, and an electrolyte added between the positive electrode and negative electrode.
Abstract translation:目的:提供一种用于锂二次电池的电解液,以通过包括三苯基正膦化合物来减少由活性材料和电解质引起的副反应,从而提高锂二次电池的寿命。 构成:用于锂二次电池的电解液包括由化学式1表示的三苯基正膦化合物。在化学式1中,R是N-R 1或CR 1 R 12。 在化学式1中,R 1和R 2两个选自H,C 1-10饱和或不饱和烃,CN,CHO,COCH 3,COCO 2 C 2 H 5,CO 2 CH 3和Si(CH 3)3。 锂二次电池包括正极,负极,正极和负极之间的隔板以及添加在正极和负极之间的电解质。
Abstract:
PURPOSE: A diimonium based compound and a near infrared ray-absorbing filter using the same are provided to display wide and even absorption rate in the near infrared ray area and to improve durability and weatherability. CONSTITUTION: A diimonium based compound has a structure which is represented by chemical formula 1. In the chemical formula 1, R1 - R8 are respectively and independently indicate hydrogen atom(H), substituted or non-substituted aryl having 6-14 carbons, or substituted or non-substituted alkyl group having 1-10 carbons, and n indicates 0 or 1. Here, the substituents of R1 - R8 are selected from the alkyl group having 1-5 carbons and halogen except the fluorine. The near infrared ray absorption filter includes the diimonium group compound.
Abstract:
본 발명은 트리페닐포스페이트 화합물을 포함하는 리튬이차전지용 전해액, 상기 전해액을 포함하는 리튬이차전지 및 이의 제조방법에 관한 것으로서 보다 상세하게는 리튬이차전지용 전해액에 있어서, 리튬이차전지용 전해액에 하기 화학식(1)의 트리페닐포스페이트 화합물을 포함하는 리튬이차전지용 전해액, 상기 전해액을 포함하는 리튬이차전지 및 이의 제조방법에 관한 것이다. ...화학식(1) 상기 화학식(1)에서 R 1 은 옥사이드(O), 알킬옥사이드(RO), 설파이드(S), 알킬 설파이드(RS), 메틸렌(CH 2 ), 석시닉 언하이드라이드(C 4 H 4 O 3 )의 군으로부터 선택된 어느 하나이고, 상기 R 1 에서 알킬기는 탄소수 1 내지 20개를 가지는 알킬기의 군으로부터 선택된 어느 하나의 알킬기이다. 트리페닐포스페이트 화합물, 리튬이차전지 전해액, 리튬이차전지
Abstract translation:提供锂二次电池用电解液,含有电解质溶液的锂二次电池以及电池的制备方法,以提高能量密度和输出功率。 锂二次电池用电解液包含由式1表示的磷酸三苯酯化合物,其中,R 1为选自氧化物(O),烷基氧化物(RO),硫化物(S),烷基 硫化物(RS),亚甲基(CH 2)和琥珀酸酐(C 4 H 4 O 3); 并且R 1的烷基是选自碳数为1〜20的烷基的任何一个烷基。
Abstract:
An electrolyte solution for a lithium secondary battery, a lithium secondary battery containing the electrolyte solution, and a preparation method of the battery are provided to improve energy density and output power. An electrolyte solution for a lithium secondary battery comprises a triphenyl phosphate compound represented by the formula 1, wherein R1 is any one selected from the group of an oxide (O), an alkyl oxide (R-O), a sulfide (S), an alkyl sulfide (R-S), a methylene (CH2), and a succinic anhydride (C4H4O3); and the alkyl group of R1 is any one alkyl group selected from the group of alkyl groups having the carbon number 1 ~ 20.
Abstract translation:提供锂二次电池用电解液,含有电解质溶液的锂二次电池以及电池的制备方法,以提高能量密度和输出功率。 锂二次电池用电解液包含由式1表示的磷酸三苯酯化合物,其中,R 1为选自氧化物(O),烷基氧化物(RO),硫化物(S),烷基 硫化物(RS),亚甲基(CH 2)和琥珀酸酐(C 4 H 4 O 3); 并且R 1的烷基是选自碳数1〜20的烷基的任何一个烷基。