다중 술폰화된 폴리 아릴에테르케톤 공중합체 및 이를포함하는 전해질막
    1.
    发明授权
    다중 술폰화된 폴리 아릴에테르케톤 공중합체 및 이를포함하는 전해질막 有权
    多磺化聚芳醚酮酮共聚物和电解质膜

    公开(公告)号:KR100851924B1

    公开(公告)日:2008-08-12

    申请号:KR1020070010692

    申请日:2007-02-01

    Abstract: A sulfonated polyarylene ether ketone copolymer, and a polymer electrolyte membrane containing the copolymer are provided to lower gas permeation, to improve ion conductivity and structural stability and to reduce the crossover of an oxidant. A sulfonated polyarylene ether ketone copolymer comprises a ketone repeating unit represented by the formula 1; and an ether bond repeating unit containing an aryl group represented by the formula 2, wherein M1, M2 and M3 are independently H, Na, Li or K; R1 and R2 are independently H, a C5-C30 aromatic ring, a C5-C30 aromatic ring containing O, or a C1-C30 alkyl group; x and x' are independently an integer of 0-3; y, y' and z are independently an integer of 1-4; X is -O-, -S-, -NH-, -SO2-, -CO-, -C(CH3)2- or -C(CF3)2-; R3 and R4 are independently H, a C5-C30 aromatic ring, a C5-C30 aromatic ring containing O, or a C1-C30 alkyl group; and a and b are independently an integer of 1-4.

    Abstract translation: 提供磺化聚芳醚酮共聚物和含有该共聚物的聚合物电解质膜以降低气体渗透性,以提高离子传导性和结构稳定性并减少氧化剂的交叉。 磺化聚亚芳基醚酮共聚物包括由式1表示的酮重复单元; 和含有由式2表示的芳基的醚键重复单元,其中M1,M2和M3独立地为H,Na,Li或K; R 1和R 2独立地为H,C 5 -C 30芳环,含有O的C 5 -C 30芳环或C 1 -C 30烷基; x和x'独立地为0-3的整数; y,y'和z独立地为1-4的整数; X是-O - , - S - , - NH - , - SO 2 - , - CO - , - C(CH 3)2 - 或-C(CF 3) R 3和R 4独立地为H,C 5 -C 30芳环,含有O的C 5 -C 30芳环或C 1 -C 30烷基; a和b独立地为1-4的整数。

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