Abstract:
본 발명은 석탄의 용매추출공정용 황화합물 흡착제, 및 이를 이용한 황화합물 흡착방법과 석탄정제방법에 관한 것이다. 더욱 상세하게는, 본 발명은 알칼리 금속산화물, 알칼리 금속수산화물, 산화알루미나 및 활성탄으로부터 선택되는 어느 하나 또는 그 혼합물로 구성되는 석탄의 용매추출공정용 황화합물 흡착제 및 이를 이용한 황화합물 흡착방법과 석탄의 정제방법에 대한 것이다.
Abstract:
PURPOSE: A sulfide absorber for a solvent extracting process of coal and a sulfide absorption method using the same and coal purifying method are provided to effectively remove sulfide in organic solvent containing plastic component extract by using reactor including absorption. CONSTITUTION: A coal melting storage tank(10) stores an organic solvent. The stored organic solvent is moved to a reactor through high-pressure liquid pump(20). The reactor includes an absorbent(30). The reactor is heated by a high-temperature furnace(40). A pressure gauge(50) displays pressured in the reactor. The pressure is controlled by a pressure control valve(60). The absorption reaction of organic solvent is operated. The processed organic solvent is collected with a sample collecting container(70).
Abstract:
본 발명은 석탄추출물 내의 황화합물을 제거하기 위하여 황 제거용 2차 용매 및 이를 이용한 황화합물 제거방법에 관한 것으로서, 상세하게는 석탄추출물에 수소공여제 역할을 하는 2차 용매를 도입하여 석탄추출물 내 황화합물을 황화수소 가스 형태로 제거하는 것을 특징으로 하는 황화합물 제거방법에 대한 것이다.
Abstract:
PURPOSE: The secondary solvent for removing solvent compound and a removing method of sulfur compound using the same are provided to remove sulfur compound with high efficiency from coal extract of low class coal, and reduce cost of the whole procedure by showing high desulfurization efficiency from a small amount of secondary solvent. CONSTITUTION: The secondary solvent for removing solvent comprises deionized water, hydrogen peroxide, methanol, ethanol, phentanol, and one or the compound selected from PGMEA. A removal method comprises the step of introducing the secondary solvent which acts as hydrogen donor to coal extract and removes sulfide compound within coal extract obtained from the coal extracting process of low class in a form of hydrogen sulfide gas. The secondary solvent is also used with one selected from reforming catalyst of metal oxide, metal hydroxide, activated charcoal, and transition metal or desulfurizing agent composed of the mixture. The desulfurizing agent is Ni group reforming catalyst.
Abstract:
본 발명은 암모니아수 흡수용액을 이용하여 연소배가스로부터 이산화탄소를 선택적으로 흡수하기 위한 흡수탑; 상기 흡수탑에서 유출되는 암모니아를 세정하기 위한 세정탑; 이산화탄소가 흡수된 암모니아수로부터 이산화탄소를 고압에서 탈거시키기 위한 이산화탄소 탈거탑; 및 세정탑에서 생산된 세정탑-배출 암모니아수를 암모니아 기체와 물로 분리하는 암모니아 회수탑을 사용하는 이산화탄소 포집 방법에 있어서, 상기 흡수탑에서 증발하는 암모니아를 세정탑으로 공급하여 세정수로 세정한 후 암모니아 회수탑으로 이송하고, 상기 암모니아 회수탑에서 가열을 통해 생성된 수증기/암모니아 혼합 기체를 상기 암모니아 회수탑의 상단에 위치하는 열교환 부분 응축기로 이송하고, 상기 열교환 부분 응축기에서 수증기는 응축시켜 암모니아 회수탑으로 재순환시키며 회수 암모니아 기체는 암모니아 기체 이송관을 통해 흡수탑으로 재순환시키는 것을 특징으로 하는, 암모니아수 흡수용액을 사용하는 개선된 이산화탄소 포집 방법 및 상기 방법을 구현하는 장치를 제공한다.
Abstract:
PURPOSE: A capturing method of carbon dioxide and device thereof are provided to reduce the compressing cost for transferring ammonia gas, which is collected in an ammonia solution process in which the high pressure carbon dioxide is collected, to the removing tower of high pressure carbon dioxide, thereby increasing the collect rate of ammonia and the removal rate of carbon dioxide in the absorptive tower. CONSTITUTION: A capturing method of carbon dioxide uses an absorptive tower(3), a washing tower(13), a carbon dioxide removing tower(6), and an ammonia collecting tower(15). The absorptive tower selectively absorbs carbon dioxide from the combustion gas by using ammonia absorptive solution. The carbon dioxide removing tower removes the carbon dioxide from the ammonia solution, in which the carbon dioxide is absorbed, at high pressure. The ammonia collecting power separates the ammonia solution produced in the washing tower into the ammonia gas and water. The ammonia evaporating in the absorptive tower is supplied to the washing tower, is washed with cleaning water, and is transferred to the collecting tower. Vapor and ammonia gas mixture produced by being heated in the ammonia collecting tower are transferred to a heat exchanging partial condenser which is located on the top of the ammonia collecting tower. Vapor is condensed in the heat exchanging partial condenser and is recycled into the ammonia collecting tower, and the ammonia gas is recycled to the absorptive tower through an ammonia gas transferring pipe. [Reference numerals] (2) Combustion exhaust gas