公开(公告)号：KR100832302B1

公开(公告)日：2008-05-26

申请号：KR1020060132117

申请日：2006-12-21

Applicant: 한국에너지기술연구원

Inventor： 박종수 ,  김동원 ,  이신근 ,  김흥구 ,  엄기연 ,  조성호

IPC: B01D71/00 ,  B01D71/02

Abstract: A preparation method of a Pd alloy membrane for hydrogen gas separation is provided to improve hydrogen permeability and durability while maintaining excellent infinite selectivity relative to hydrogen gas by manufacturing the membrane by using a dry vacuum process only in a state that a wet coating process is completely excluded. A preparation method of a Pd alloy membrane for hydrogen gas separation under in-situ dry vacuum comprises the steps of: (a) treating a surface of a porous metal support by plasma; (b) continuously forming a Pd layer and a metal layer on an upper part of the plasma surface-treated porous metal support by dry deposition process; and (c) reflowing the Pd and the metal layer to obtain an alloy membrane. The porous support is a porous Ni support. The metal deposited onto the Pd layer is at least one metal selected from the group consisting of copper, silver, nickel, ruthenium, and molybdenum. The metal deposited onto the Pd layer is copper.

Abstract translation: 提供了用于氢气分离的Pd合金膜的制备方法，以提高氢渗透性和耐久性，同时通过仅在湿式涂覆过程完全地通过使用干式真空法制造膜来保持优异的无限选择性 排除。 在原位干燥真空下进行氢气分离的Pd合金膜的制备方法包括以下步骤：（a）通过等离子体处理多孔金属载体的表面; （b）通过干沉积工艺在等离子体表面处理的多孔金属载体的上部上连续地形成Pd层和金属层; 和（c）回流Pd和金属层以获得合金膜。 多孔载体是多孔Ni载体。 沉积在Pd层上的金属是选自铜，银，镍，钌和钼中的至少一种金属。 沉积在Pd层上的金属是铜。