公开(公告)号：KR101414992B1

公开(公告)日：2014-07-04

申请号：KR1020120055975

申请日：2012-05-25

Applicant: 한국에너지기술연구원

Inventor： 유윤종 ,  김홍수 ,  이동철

IPC: B01D53/62 ,  B01D53/02 ,  B01J20/28 ,  C01B32/50

CPC classification number: Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06 ,  Y02C10/08 ,  Y02P20/152

Abstract: 본 발명에 따른 고체 이산화탄소 흡수제의 제조 방법은 1) a) 세라믹 섬유 10 ~ 80 중량%, b) 다공성 무기 물질 10 ~ 80 중량% 및 c) 유기 바인더, 무기 바인더 또는 그 혼합물 5 ~ 20 중량%를 혼합하여 종이를 제조하는 단계: 2) 상기 종이를 편파성형체로 성형한 후 감아서 원통형 허니컴 성형체를 제조하는 단계; 3) 상기 허니컴 성형체를 이산화탄소 흡수 물질이 용해된 용액에 침적한 후 건조하는 단계; 및 4) 상기 이산화탄소 흡수 물질이 담지된 허니컴 성형체를 소성한 후 냉각하는 단계를 포함하며, 이에 따라 제조된 고체 이산화탄소 흡수제를 이용하면 배기가스 중 이산화탄소를 제거할 때 공기의 흐름에 따른 흡수제의 깨짐 현상이나 공정 압력의 강하가 발생하지 않으며, 농축 이산화탄소의 필터링이나 주기적 보충이 불필요하고, 공정 단순화를 통해 장치비용과 운전비용이 절감된 안정적인 건식 이산화탄소 흡수 및 분리 농축 공정을 실현할 수 있다.

公开(公告)号：KR1020130131970A

公开(公告)日：2013-12-04

申请号：KR1020120055975

申请日：2012-05-25

Applicant: 한국에너지기술연구원

Inventor： 유윤종 ,  김홍수 ,  이동철

IPC: B01D53/62 ,  B01D53/02 ,  B01J20/28 ,  C01B32/50

CPC classification number: Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06 ,  Y02C10/08 ,  Y02P20/152 ,  B01D53/62 ,  B01D53/02 ,  B01J20/28 ,  C01B32/50

Abstract: A method for manufacturing a solid carbon dioxide absorbent comprises the steps of: manufacturing papers by mixing 10-80 wt% of a fiber material capable of enduring at over 100°C, 10-80 wt% of a porous inorganic material, and 5-20 wt% of inorganic/organic binder; manufacturing a cylindrical honeycomb molded body by molding the papers in a polarization molded body then winding it; dipping the honeycomb molded body in a solution in which a carbon dioxide absorbing material is dissolved, then drying it; and hardening the honeycomb molded body dipped with the carbon dioxide absorbing material and cooling it. The solid carbon dioxide absorbent manufactured by the method does not generate a breaking phenomenon of the absorbent or a process pressure descent due to the air flow during the removal of carbon dioxide from exhaust gas, does not require a regular filling or filtering of concentrated carbon dioxide, and can realize a stable dry process of absorbing, separating and concentrating carbon dioxide with reduced operating cost and facility cost through process simplification. [Reference numerals] (AA) ceramic paper(comprising ceramic fiber, porous inorganic, binder);(BB) molding in cylindrical honeycomb having cross section with holes by molding a side in wave shape and winding;(CC) dipping absorbent in solution(K2CO3 or Na2CO3 or CaCO3, Amine);(DD) drying, 100-120°C;(EE) plasticizing, 450-600°C

Abstract translation: 制造固体二氧化碳吸收剂的方法包括以下步骤：通过混合10-80重量％的能够在100℃以上耐受的纤维材料，10-80重量％的多孔无机材料和5- 20重量％的无机/有机粘合剂; 通过在偏振成型体中模制纸张然后卷绕来制造圆柱形蜂窝成型体; 将蜂窝成型体浸渍在其中溶解有二氧化碳吸收材料的溶液中，然后将其干燥; 并使用二氧化碳吸收材料浸渍的蜂窝模制体硬化并冷却。 通过该方法制造的固体二氧化碳吸收剂在从废气中除去二氧化碳期间由于空气流动而不产生吸收剂的破裂现象或过程压力下降，不需要定期填充或过滤浓缩的二氧化碳 ，通过简化过程，可以实现吸收，分离和浓缩二氧化碳的稳定干燥过程，降低运行成本和设备成本。 （AA）陶瓷纸（包括陶瓷纤维，多孔无机，粘合剂）;（BB）成形为圆形蜂窝体，其横截面通过成型波浪形和绕组侧面;（CC）浸渍吸收剂在溶液中 K2CO3或Na2CO3或CaCO3，胺）;（DD）干燥，100-120℃;（EE）塑化，450-600℃

公开(公告)号：KR101392232B1

公开(公告)日：2014-05-08

申请号：KR1020120106029

申请日：2012-09-24

Applicant: 한국에너지기술연구원

Inventor： 유윤종 ,  김현욱 ,  송광섭 ,  김태환 ,  이영주 ,  이동철

IPC: C01B31/02 ,  B01J6/00 ,  H01M8/02

CPC classification number: Y02P70/56

Abstract: 본발명은오존처리되어친수성작용기를갖는탄소섬유의습식침강에의한탄소종이제조방법, 그에따라제조된탄소종이및 이를포함하는연료전지에관한것으로서, 구체적으로는습식공정에의한탄소종이제조방법에있어서, 오존처리에의해서표면이산화된탄소섬유를포함하는탄소섬유분산액을이용하는것을특징으로하는탄소종이제조방법, 그에따라제조된탄소종이및 이를포함하는연료전지에관한것이다. 본발명에따르면, 탄소섬유들이비등방성배열을가지며고르게분산됨으로써우수한전기전도도및 기체투과도를갖는탄소종이를제공할수 있다.

公开(公告)号：KR1020140007729A

公开(公告)日：2014-01-20

申请号：KR1020120106029

申请日：2012-09-24

Applicant: 한국에너지기술연구원

Inventor： 유윤종 ,  김현욱 ,  송광섭 ,  김태환 ,  이영주 ,  이동철

IPC: C01B31/02 ,  B01J6/00 ,  H01M8/02

CPC classification number: Y02P70/56 ,  C01B32/05 ,  B01J6/00 ,  D01F9/12 ,  H01M8/02

Abstract: The present invention relates to a manufacturing method for carbon paper by the wet sedimentation of ozone-treated carbon fibers with hydrophilic functional groups, carbon paper manufacture thereby and a fuel cell comprising the carbon paper and, more specifically, to a manufacturing method for carbon paper by a wet process which is characterized by using a carbon fiber dispersion containing carbon fibers in which surface is oxidized by ozone treatment, carbon paper manufactured thereby and a fuel cell comprising the same. The present invention is able to provide carbon paper with excellent conductivity and gas transmittance since carbon fibers have aeolotropy arrangement and are evenly dispersed. [Reference numerals] (AA) Carbon fibers; (BB) Ozonation reaction of carbon fibers; (CC) Oxidized carbon fibers

Abstract translation: 本发明涉及通过具有亲水性官能团的臭氧处理碳纤维的湿沉降，碳纸制造的碳纸的制造方法和包含碳纸的燃料电池，更具体地涉及碳纸的制造方法 通过湿法，其特征在于使用含有表面被臭氧处理氧化的碳纤维的碳纤维分散体，由此制造的碳纸和包含该碳纤维的燃料电池。 本发明能够提供碳纤维具有优异的导电性和气体透射率，因为碳纤维具有均匀分布并均匀分散。 （AA）碳纤维; （BB）碳纤维的臭氧化反应; （CC）氧化碳纤维

公开(公告)号：KR101304489B1

公开(公告)日：2013-09-05

申请号：KR1020120080526

申请日：2012-07-24

Applicant: 한국에너지기술연구원

Inventor： 유윤종 ,  김현욱 ,  송광섭 ,  김태환 ,  이영주 ,  이동철

IPC: H01M4/86 ,  H01M8/02 ,  H01M8/10 ,  C01B31/02

CPC classification number: Y02P70/56 ,  D21H13/50 ,  D04H1/4242 ,  H01M4/96 ,  H01M8/0234

Abstract: PURPOSE: A manufacturing method of carbon paper provides carbon paper with excellent electric conductivity and air permeability by uniformly dispersing carbon fibers in an anisotropic arrangement. CONSTITUTION: A manufacturing method of carbon paper by a wet process includes a step of controlling the charge density of a dispersion solution in which carbon fiber is dispersed to 2-50 meq/L and the viscosity of the dispersion to 110-507 cP. The charge density and the viscosity of the dispersion liquid are controlled by adding a thickening agent and the anionic material into the dispersion. The thickening agent is selected from carboxymethyl cellulose, polyethylene oxide, polyethylene glycol, hydroxyethyl, cellulose, acrylic tackier and a mixture thereof.

Abstract translation: 目的：碳纸的制造方法通过在各向异性布置中均匀分散碳纤维来提供具有优异导电性和透气性的碳纸。 构成：通过湿法制造碳纸的方法包括将碳纤维分散的分散液的电荷密度控制在2-50meq / L，分散体的粘度为110-507cP的步骤。 通过向分散体中加入增稠剂和阴离子材料来控制分散液的电荷密度和粘度。 增稠剂选自羧​​甲基纤维素，聚环氧乙烷，聚乙二醇，羟乙基，纤维素，丙烯酸增粘剂及其混合物。