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公开(公告)号：KR100757200B1
公开(公告)日：2007-09-07
申请号：KR1020050010813
申请日：2005-02-04
Applicant: 한국원자력연구원 , 한국수력원자력 주식회사
Abstract: 본 발명은 제올라이트만을 이용한 염화염 폐기물(waste chloride salt)의 고정화 생성물 제조방법에 관한 것으로서, 보다 상세하게는 사용후 핵연료를 재처리하는 과정에서 발생하는 세슘(Cs), 스트론튬(Sr) 및 바륨(Ba) 등과 같은 알칼리 또는 알칼리 토금속족, 또는 세륨(Ce), 란타늄(La), 네오디늄(Nd), 이트륨(Y)과 같은 희토류계 방사성 핵종을 포함하는 염화염 폐기물과 제올라이트를 혼합하여 고정화 중간체를 제조하는 단계 및 상기 고정화 중간체를 Na계 소달라이트로 전이시키는 단계를 포함하는 제올라이트만을 이용한 염화염 폐기물의 고정화 생성물의 제조방법에 관한 것이다.
본 발명의 고정화 생성물은 보다 안정한 형태인 Na계 소달라이트로 되어 침출특성이 우수할 뿐만 아니라, 소달라이트로 전이를 시키는 과정에서 전이 촉진제 등을 첨가하지 않음으로써 그에 해당하는 양만큼의 최종 고화체(waste form)의 생성량을 줄임으로써 보다 효과적으로 염폐기물을 처리할 수 있게 한다.
LiCl계 염폐기물, 제올라이트 NaA, 소달라이트, 고정화 생성물, 세슘, 스트론튬-
公开(公告)号：KR1020060089993A
公开(公告)日：2006-08-10
申请号：KR1020050010813
申请日：2005-02-04
Applicant: 한국원자력연구원 , 한국수력원자력 주식회사
CPC classification number: G21F9/16 , B01D9/0013 , C01B39/023 , G21F9/301
Abstract: 본 발명은 제올라이트만을 이용한 염화염 폐기물(waste chloride salt)의 고정화 생성물 제조방법에 관한 것으로서, 보다 상세하게는 사용후 핵연료를 재처리하는 과정에서 발생하는 세슘(Cs), 스트론튬(Sr) 및 바륨(Ba) 등과 같은 알칼리 또는 알칼리 토금속족, 또는 세륨(Ce), 란타늄(La), 네오디늄(Nd), 이트륨(Y)과 같은 희토류계 방사성 핵종을 포함하는 염화염 폐기물과 제올라이트를 혼합하여 고정화 중간체를 제조하는 단계 및 상기 고정화 중간체를 Na계 소달라이트로 전이시키는 단계를 포함하는 제올라이트만을 이용한 염화염 폐기물의 고정화 생성물의 제조방법에 관한 것이다.
본 발명의 고정화 생성물은 보다 안정한 형태인 Na계 소달라이트로 되어 침출특성이 우수할 뿐만 아니라, 소달라이트로 전이를 시키는 과정에서 전이 촉진제 등을 첨가하지 않음으로써 그에 해당하는 양만큼의 최종 고화체(waste form)의 생성량을 줄임으로써 보다 효과적으로 염폐기물을 처리할 수 있게 한다.
LiCl계 염폐기물, 제올라이트 NaA, 소달라이트, 고정화 생성물, 세슘, 스트론튬-
公开(公告)号：KR100594841B1
公开(公告)日：2006-06-30
申请号：KR1020040109721
申请日：2004-12-21
Applicant: 한국원자력연구원 , 한국수력원자력 주식회사
IPC: G01N27/30
Abstract: 본 발명은 고온 용융염용 기준전극 및 그 제조 방법에 관한 것으로, 보다 상세하게는 알루미나 관(10)과 그 내부에 은선-염화은-용융염으로 구성된 고온 용융염용 기준전극에 있어서, 상기 기준 전극의 알루미나 관(10) 한쪽 개구부에 다공성 세라믹 층(20)이 형성된 것임을 특징으로 하는 고온 용융염용 기준전극 및 그 제조방법에 대한 것으로서, 본 발명에 의하면 물리적 또는 열적 충격에 대한 내구성 및 내부식성이 우수할 뿐만 아니라 고온 용융염에서의 재현성 및 전위 특성이 종래의 파이렉스형 기준전극보다 우수하고 안정된 이점을 갖는다.
기준전극, 다공성 세라믹, 은선, 염화은, 용융염-
公开(公告)号：KR1020050033093A
公开(公告)日：2005-04-12
申请号：KR1020030069005
申请日：2003-10-04
Applicant: 한국원자력연구원 , 한국수력원자력 주식회사
IPC: G21F9/12
Abstract: A method for improving electrosorption efficiency of uranium-containing liquid waste is provided to process the sludge liquid waste before the electrosorption process by separating a chemical salt component by a liquid-solid filtering process using a filter and a precipitator. An irresoluble solution contains small amount of radioactive uranium and high concentration chemical salts, such as NH4NO3, NaNO3, Ca(NO3)2, CaCO3. The chemical salts are separated through a liquid-solid separation process, which includes more than one of a filter and a precipitator, such that electrosorption efficiency of the uranium is enhanced. In the liquid-solid separation process, either the filter or the precipitator is used alone, or the filter is used after the precipitator. The liquid-solid separation process uses one selected from the group of a filter paper, a filter membrane, and a filter member.
Abstract translation: 提供了一种提高含铀液体废物的吸收效率的方法，通过使用过滤器和除尘器通过液固过滤方法分离化学盐成分来处理电吸附过程之前的污泥废液。 不溶解的溶液含有少量放射性铀和高浓度化学盐，如NH4NO3，NaNO3，Ca（NO3）2，CaCO3。 通过液固分离方法分离化学盐，其包括多于一种过滤器和除尘器，使得铀的电吸收效率提高。 在液固分离过程中，过滤器或除尘器单独使用，或者在除尘器之后使用过滤器。 液固分离方法使用选自滤纸，过滤膜和过滤器构件的一种。
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公开(公告)号：KR100436540B1
公开(公告)日：2004-06-19
申请号：KR1020010073174
申请日：2001-11-23
Applicant: 한국원자력연구원 , 한국수력원자력 주식회사
IPC: G21F9/00
Abstract: Disclosed is a method and device for collecting particulate contaminants removed using a CO 2 decontamination medium from an early step of a decontamination process. The device removes particulate contaminants from a contaminated subject by a decontamination stream, and simultaneously forms another stream for collecting such contaminants into a collecting filter, thus preventing such contaminants from diffusing into the atmosphere. The device forms streams between the nozzles and the surface of the contaminated subject to readily move the nozzles along the surface of the subject without frictional resistance, to reduce the sense of fatigue of the operator. The method and device are advantageous in that when the device is readily used with a conventional CO 2 blasting decontamination unit to collect particulate contaminants, removal of particulate contaminants from a contaminated subject and collection of particulate contaminants contained in the decontamination stream are simultaneously performed, also allowing compressed gas blasted through air curtain blasting nozzles to prevent contaminated gas from diffusing into the atmosphere.
Abstract translation: 公开了一种用于从去污过程的早期步骤收集使用CO SUB SUB去污介质去除的颗粒污染物的方法和设备。 该装置通过净化流从受污染的对象中去除颗粒污染物，并且同时形成另一个流，用于将这些污染物收集到收集过滤器中，从而防止这些污染物扩散到大气中。 该装置在喷嘴和受污染物表面之间形成流动物，以便容易地沿着物体表面移动喷嘴而没有摩擦阻力，从而减少操作者的疲劳感。 该方法和装置的优点在于，当该装置容易与传统的CO 2 SUB爆炸净化单元一起使用以收集颗粒污染物，从受污染的对象中去除颗粒污染物和收集包含在污染物中的颗粒污染物 同时执行净化流，还允许通过气幕喷射喷嘴喷射压缩气体以防止污染气体扩散到大气中。
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Patent Agency Ranking
公开(公告)号：KR100404742B1
公开(公告)日：2003-11-07
申请号：KR1020020013566
申请日：2002-03-13
Applicant: 한국원자력연구원
IPC: H01M10/54
CPC classification number: Y02W30/84
Abstract: PURPOSE: Provided is a method for recovering high pure cobalt in a high degree of recovery from waste electrodes generated from a process for producing lithium ion secondary batteries or wasted after using. CONSTITUTION: The method comprises the steps of: injecting LiCoO2 powder obtained from the waste electrodes into an inorganic acid containing hydrogen peroxide and dissolving and filtering, wherein the inorganic acid is hydrochloric acid or sulfuric acid; electrolyzing the filtrate to recover the cobalt electrodeposited on an anode. And the LiCoO2 powder is obtained by heating the waste electrodes at 400-600deg.C under non-oxidative atmosphere.
Abstract translation: 目的：提供一种从锂离子二次电池的制造工序中产生的废电极中回收高回收率的高纯度钴的方法，或使用后浪费的方法。 该方法包括以下步骤：将由废电极得到的LiCoO2粉末注入含有过氧化氢的无机酸中溶解过滤，其中无机酸为盐酸或硫酸; 电解滤液以回收电沉积在阳极上的钴。 通过在非氧化性气氛下在400-600℃加热废电极来获得LiCoO 2粉末。
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公开(公告)号：KR100404588B1
公开(公告)日：2003-11-05
申请号：KR1020010014570
申请日：2001-03-21
IPC: B01D11/02
Abstract: PURPOSE: A pneumatic type multistage solvent extracting apparatus is provided to extract the metallic ions by mixing water soluble phase with organic phase using air without using of an impeller in a mixing tank in the process of separating and refining the metal ions by extracting metal ions dissolved in a solution using nonmixing solution. CONSTITUTION: The pneumatic type multistage solvent extracting apparatus comprises an air suction and exhaustion distribution pipe(4) which is connected to an air suction and exhaustion unit to uniformly distribute air during suction and exhaustion of air; a mixing probe(6) which is connected to the air suction and exhaustion distribution pipe(4) to exhaust or suck an aqueous solution; a mixer and settler housing(8) in which a plural pairs of mixers(29) where the mixing probe(6) is vertically installed and settlers(58) where organic phase and water soluble phase are charged in; and an air pulse generator(10) which is installed at one side of the mixer and settler housing(8) to generate air pulse, wherein the mixing probe(6) comprises a suction and exhaustion port(18), an air chamber(20), and a nozzle head part(22) consisting of an upper nozzle, a lower nozzle and a guide groove, and the mixer and settler housing(8) comprises a water soluble phase port, first, third, fifth and seventh end parts consisting of mixers and settlers, water soluble phase projections, second, fourth, sixth and eighth end parts consisting of mixers and settlers, organic phase projections, and an organic phase port.
Abstract translation: 目的：提供一种气动式多级溶剂萃取装置，用于在通过萃取溶解金属离子而分离和精制金属离子的过程中，在不使用叶轮的情况下，使用空气将水溶性相与有机相在混合槽中混合来萃取金属离子 在使用非混合解决方案的解决方案中。 本发明提供一种气动式多级溶剂萃取装置，包括吸气排气分配管（4），吸气排气分配管（4）与吸气排气单元连接，在吸气和排气过程中均匀分布空气; 混合探针（6），其与吸气排气分配管（4）连接以排出或吸取水溶液; 混合器和沉降器壳体（8），在其中垂直安装混合探针（6）的多对混合器（29）和填充有机相和水溶性相的沉降器（58）; 和一个安装在混合器和沉降器壳体（8）的一侧以产生空气脉冲的空气脉冲发生器（10），其中混合探针（6）包括吸入和排出口（18），空气室 ）和由上喷嘴，下喷嘴和导向槽组成的喷嘴头部分（22），混合器和沉降器壳体（8）包括水溶性相端口，第一，第三，第五和第七端部分， 混合器和沉降器，水溶性相位投影，由混合器和沉降器组成的第二，第四，第六和第八端部，有机相投影和有机相端口。
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公开(公告)号：KR100382996B1
公开(公告)日：2003-05-09
申请号：KR1020000067234
申请日：2000-11-13
Applicant: 한국원자력연구원
IPC: C08J5/20
Abstract: PURPOSE: A high performance ion exchange resin with double structured functional groups and its preparation method are provided, to increase the concentration of uranium ions on surface and to improve the adsorbing power of uranium, thereby enhancing the recovery rate or soluble uranium ions. CONSTITUTION: The high performance ion exchange resin has a double structured functional groups where an ion-selective secondary functional groups are introduced on the surface of a strong ionic exchange resin. Preferably the strong ionic exchange resin contains sulfone groups or tertiary amine groups in molecule. The method comprises the steps of radiating the surface of strong ionic exchange resin to form radicals on the surface; and introducing secondary functional groups coordinate bonding with a uranium ion into the strong ionic exchange resin. Preferably the secondary function groups are selected from the group consisting of an amidoxime group and a carboxyl group.
Abstract translation: 目的：提供一种具有双官能团的高性能离子交换树脂及其制备方法，提高铀离子浓度，提高铀的吸附能力，提高铀离子的回收率。 构成：高性能离子交换树脂具有双结构官能团，其中在强离子交换树脂的表面上引入离子选择性二级官能团。 强离子交换树脂优选在分子中含有砜基或叔胺基。 该方法包括以下步骤：辐射强离子交换树脂的表面以在表面上形成自由基; 并引入次级官能团与铀离子配位键合到强离子交换树脂中。 优选第二官能团选自偕胺肟基和羧基。
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公开(公告)号：KR1020020074659A
公开(公告)日：2002-10-04
申请号：KR1020010014570
申请日：2001-03-21
IPC: B01D11/02
CPC classification number: B01D11/0469 , B01D17/02 , B01D2011/007
Abstract: PURPOSE: A pneumatic type multistage solvent extracting apparatus is provided to extract the metallic ions by mixing water soluble phase with organic phase using air without using of an impeller in a mixing tank in the process of separating and refining the metal ions by extracting metal ions dissolved in a solution using nonmixing solution. CONSTITUTION: The pneumatic type multistage solvent extracting apparatus comprises an air suction and exhaustion distribution pipe(4) which is connected to an air suction and exhaustion unit to uniformly distribute air during suction and exhaustion of air; a mixing probe(6) which is connected to the air suction and exhaustion distribution pipe(4) to exhaust or suck an aqueous solution; a mixer and settler housing(8) in which a plural pairs of mixers(29) where the mixing probe(6) is vertically installed and settlers(58) where organic phase and water soluble phase are charged in; and an air pulse generator(10) which is installed at one side of the mixer and settler housing(8) to generate air pulse, wherein the mixing probe(6) comprises a suction and exhaustion port(18), an air chamber(20), and a nozzle head part(22) consisting of an upper nozzle, a lower nozzle and a guide groove, and the mixer and settler housing(8) comprises a water soluble phase port, first, third, fifth and seventh end parts consisting of mixers and settlers, water soluble phase projections, second, fourth, sixth and eighth end parts consisting of mixers and settlers, organic phase projections, and an organic phase port.
Abstract translation: 目的：提供一种气动型多级溶剂萃取装置，通过在溶解金属离子中分离和精制金属离子的过程中，在混合罐中使用空气混合水溶性相与有机相，从而提取金属离子 在使用非混合溶液的溶液中。 构成：气动式多级溶剂萃取装置包括吸气排气管（4），其连接到空气抽吸单元，以在吸入和排出空气期间均匀分布空气; 混合探针（6），其连接到吸气和排气分配管（4）以排出或吸入水溶液; 混合器和沉降器壳体（8），其中垂直安装混合探针（6）的多个混合器（29）和其中有机相和水溶性相被加入的沉降器（58）; 和空气脉冲发生器（10），其安装在所述混合器和沉降器壳体（8）的一侧以产生空气脉冲，其中所述混合探针（6）包括抽吸和排出口（18），空气室（20） ）和由上喷嘴，下喷嘴和引导槽组成的喷嘴头部分（22），并且混合器和沉降器壳体（8）包括水溶性相口，第一，第三，第五和第七端部包括 的混合器和沉降器，水溶相投影，第二，第四，第六和第八端部分由混合器和沉降器，有机相突出和有机相端口组成。
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公开(公告)号：KR1020020013293A
公开(公告)日：2002-02-20
申请号：KR1020000046977
申请日：2000-08-14
IPC: C07D273/01
Abstract: PURPOSE: The coupling calix(4)arene azacrown ether derivatives capable of selectively adsorbing potassium ions are provided, therefore the derivatives can be used for the measurement of a potassium concentration in serum and their chelation with specific metal ions can be easily detected with the naked eye. CONSTITUTION: The coupling calix(4)arene azacrown ether derivatives capable of selectively adsorbing potassium ions are represented by last formula, in which R is C0 to C10 linear alkyl; R' is nitro, cyano or C1 to C3 ester; and n is an integer of 0 to 3, preferably R is propyl, R' is nitro, and n is 1. The method for producing the coupling calix(4)arene azacrown ether derivatives comprises the steps of: reacting the compound of formula(I) with the tosylate of formula(II) in the presence of CS2CO3 to produce tetraalkylated calix(4)arene compound of formula(III); cyclization reacting the compound of formula(III) to produce N-tosylated calix(4)arene azacrown ether compound of formula(IV); deprotection reacting the compound of formula(IV) to produce calix94)arene azacrown ether compound of formula(V); and reacting the compound of formula(V) with a coupling compound in solvent in the presence of base to produce the title compound of last formula.
Abstract translation: 目的：提供能够选择性吸附钾离子的偶联杯（4）芳吖醚醚衍生物，因此该衍生物可用于测量血清中的钾浓度，并且可以容易地用赤铁蛋白检测其与特定金属离子的螯合 眼。 构成：能够选择性吸附钾离子的偶联杯（4）芳基氮杂醚衍生物由下式表示，其中R为C0至C10直链烷基; R'是硝基，氰基或C 1至C 3酯; n为0〜3的整数，优选R为丙基，R'为硝基，n为1.制备偶联杯剂（4）的芳族氮杂蒽衍生物的方法包括以下步骤：使式 I）与式（II）的甲苯磺酸酯在CS2CO3的存在下反应，生成式（III）的四烷基化杯（4）芳烃化合物; 使式（III）化合物与式（Ⅳ）的N-甲苯磺酰化的杯芳烃（4）芳吖唑醚化合物反应; 脱保护使式（IV）化合物与式（V）的芳基氮杂冠醚化合物反应; 并使式（V）化合物与偶联化合物在溶剂中在碱存在下反应，得到最终式的标题化合物。
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