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公开(公告)号：KR101369021B1
公开(公告)日：2014-02-28
申请号：KR1020120119219
申请日：2012-10-25
Applicant: 한국화학연구원
CPC classification number: Y02A50/2341 , B01J23/8926 , B01D53/46 , B01J31/02 , B01J38/06
Abstract: The present invention relates to a low temperature oxidation catalyst with improved water-stability for removing toxic gas and more specifically, to a low temperature oxidation catalyst for removing toxic gas which is used for the oxidation reaction for directly removing the toxic gas without a preprocessing step at a high temperature by putting water soluble salt of 8B class metal and copper metal used as an active component into a poly(styrene-vinyl benzene) copolymer carrier with moisture. The catalyst of the present invention has extended catalyst lifetime by not generating inactivation even in a condition with the moisture, and also the inactivated catalyst can be recycled after exposing to steam for one or two hours for the large scale processing of the toxic gas.
Abstract translation: 本发明涉及一种低温氧化催化剂，其具有改善的用于除去有毒气体的水稳定性，更具体地涉及一种用于除去有毒气体的低温氧化催化剂，所述低温氧化催化剂用于氧化反应，用于直接除去有毒气体而不进行预处理步骤 通过将作为活性成分的8B类金属和铜金属的水溶性盐水分放入具有水分的聚（苯乙烯 - 乙烯基苯）共聚物载体中，在高温下进行。 本发明的催化剂即使在具有水分的条件下也不会产生失活而延长了催化剂寿命，并且在暴露于蒸汽一两个小时之后，还可以将灭活的催化剂再循环用于有毒气体的大规模加工。
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公开(公告)号：KR1020130088099A
公开(公告)日：2013-08-07
申请号：KR1020130075561
申请日：2013-06-28
Applicant: 한국화학연구원
IPC: C10G35/085 , C10G35/095 , C07C5/10 , C10L1/08
CPC classification number: C10G35/095 , B01J23/40 , B01J23/74 , C10G35/09 , C10G2300/1037 , C10L1/08
Abstract: PURPOSE: A process for ring opening is provided to obtain improved conversion ratio and selectivity in comparison with the case of using hydrogen as a reducing agent. CONSTITUTION: A cyclic hydrocarbon and a reducing agent are provided as supplying materials. The supplying materials are transferred into a reactor (5) and reacted under the presence of a catalyst. A product is separated from the effusion of reaction zone. The catalyst is a heterogeneous catalyst having both acid site and metallic component. The product is obtained by evaporating and heating a mixture containing 100 parts by weight of porous molecular sieve and 0.01-20 parts by weight of water soluble metallic salt. The cyclic hydrocarbon is a naphthene group cyclic hydrocarbon which is pentagonal or hexagonal compound, or an alkyl derivative thereof selected from cyclopentane and cyclohexane. The alkyl derivative is methyl, ethyl, profile, butyl, isopropyl or an isobutyl derivative.
Abstract translation: 目的：与使用氢作为还原剂的情况相比，提供了开环方法以获得改进的转化率和选择性。 构成：提供环状烃和还原剂作为供给材料。 将供料物质转移到反应器（5）中并在催化剂存在下反应。 产物与反应区的积液分离。 催化剂是具有酸性位点和金属组分的多相催化剂。 通过蒸发和加热含有100重量份多孔分子筛和0.01-20重量份水溶性金属盐的混合物获得产物。 环状烃是环戊烷和环己烷的五烷基或六
方晶系化合物或其烷基衍生物的环烷基环状烃。 烷基衍生物是甲基，乙基，异型，丁基，异丙基或异丁基衍生物。-
公开(公告)号：KR101290742B1
公开(公告)日：2013-07-29
申请号：KR1020110034400
申请日：2011-04-13
Applicant: 한국화학연구원
IPC: B01J23/30 , B01J23/28 , B01J27/199 , C07D211/94
Abstract: 본 발명은 수용성 복합금속 산화물염으로 W, V의 복합금속 산화물염 및 Mo, V의 복합금속 산화물염 중 선택된 어느 하나 이상의 복합금속 산화물염과 과산화수소를 사용하여 고리형 2차 아민으로부터 니트록실 라디칼을 갖는 유도체를 제조하기 위한 신규한 산화용 촉매에 관한 것으로, 본 발명에 따른 산화용 촉매를 사용하는 경우 생성물을 높은 수율 및 순도로 얻을 수 있다.
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公开(公告)号：KR101268831B1
公开(公告)日：2013-05-29
申请号：KR1020110102696
申请日：2011-10-07
Applicant: 한국화학연구원
IPC: B01J23/755 , B01J23/02 , B01J35/10
Abstract: 본발명은, 선택적고리열림반응용니켈담지촉매에관한것이다. 구체적으로본 발명은, 다공성고상담체에니켈및 1 종이상의알칼리토금속이담지되고, 담지된니켈및 1 종이상의알칼리토금속의합이촉매총 중량을기준으로 46~80 중량% 인것을특징으로하는, 고리형탄화수소의선택적고리열림반응용니켈담지촉매에관한것으로서, 수소존재하에서 MCH (methylcyclohexane), MCP (methylcyclopentane) 등과같은고리형탄화수소의선택적고리열림반응 (SRO, selective ring opening)에서, Ir, Pt, Rh 등과같은귀금속이담지된촉매와동등하거나더 우수한전환율과선택도를보인다. 또한, 본발명은상기고리형탄화수소의선택적고리열림반응용니켈담지촉매의제조방법으로서, 하기단계를포함하는방법을제공한다: (a) 물, 고상담체, 니켈염, 알칼리토금속염및 공침제를포함하는혼합용액을제조하는단계, (b) 상기혼합용액을숙성시켜혼합금속침전물을얻는단계, (c) 상기침전물을소성하는단계, 및 (d) 소성된침전물을환원시키는단계.
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公开(公告)号：KR1020130019489A
公开(公告)日：2013-02-27
申请号：KR1020110081464
申请日：2011-08-17
Applicant: 한국화학연구원
IPC: B01J29/16 , B01J29/076 , C07C46/06 , C07C50/04
Abstract: PURPOSE: A heterogeneous catalyst for preparation of para-benzoquinone and catechol and a preparation method using the same are provided to prepare para-benzoquinone and catechol of 90 weight% or greater based on the weight of a total product from a reaction of phenol and hydrogen peroxide in an organic solvent by using a heterogeneous catalyst. CONSTITUTION: A heterogeneous catalyst for preparation of para-benzoquinone and catechol includes a porous carrier. The porous carrier carries at least one metal ion selected from the group consisting of vanadium and copper. The porous carrier further carries at least one metal ion selected from alkali metals. The vanadium and copper ions are supplied from a nitrate, a sulfate, an acetate, or a halogen salt. A preparation method using the heterogeneous catalyst for preparation of para-benzoquinone and catechol prepares 90 weight% or more of para-benzoquinone and catechol based on the total weight of a product produced from a reaction of phenol and hydrogen peroxide in an organic solvent.
Abstract translation: 目的：提供用于制备对苯醌和儿茶酚的非均相催化剂及其制备方法，以制备基于酚和氢的反应的总产物重量为90重量％或更高的对苯醌和邻苯二酚 过氧化物通过使用多相催化剂在有机溶剂中。 构成：用于制备对苯醌和邻苯二酚的非均相催化剂包括多孔载体。 多孔载体携带至少一种选自钒和铜的金属离子。 多孔载体还携带至少一种选自碱金属的金属离子。 钒和铜离子由硝酸盐，硫酸盐，乙酸盐或卤素盐提供。 基于由苯酚和过氧化氢在有机溶剂中的反应产生的产物的总重量，使用非对称催化剂制备对苯醌和儿茶酚的制备方法制备了对苯醌和邻苯二酚的90重量％或更多。
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Patent Agency Ranking
公开(公告)号：KR101085048B1
公开(公告)日：2011-11-21
申请号：KR1020100029423
申请日：2010-03-31
Applicant: 한국화학연구원
IPC: H01M4/583 , H01M4/48 , C10C3/00 , H01M10/0525
Abstract: 본 발명은 흑연과, 금속 또는 산화금속 혼합물의 밀링 및 산화처리를 통한 핏치 첨가제의 제조 단계, 및 상기 핏치 첨가제를 석유화학 부산물과 함께 반응시키는 단계를 포함하는 핏치의 제조 방법에 관한 것이다.
본 발명은 종래의 기술과는 달리 핏치 제조 시, 흑연 및 금속 혼합물, 또는 흑연 및 산화금속 혼합물을 투여하는 것에 차이가 있으며, 이러한 흑연 및 금속 혼합물 또는 흑연 및 산화금속 혼합물이 핏치 제조 시 촉매로 작용하여, 수율이 향상되며, 아울러 이러한 핏치를 이용한 전지의 전지용량이 향상되게 된다.-
公开(公告)号：KR1020110105047A
公开(公告)日：2011-09-26
申请号：KR1020100024066
申请日：2010-03-18
Applicant: 한국화학연구원 , 주식회사 휘닉스소재
Abstract: 본 발명은 임피던스법을 이용한 리튬이차전지의 출력 측정 방법에 관한 것으로서, 더욱 상세하게는 리튬이차전지에 주파수를 변조하면서 교류 전류 및 전압을 인가하여 측정한 임피던스 값과 직류 저항과의 관계를 구하고, 이러한 관계를 이용하여 임피던스 값으로부터 출력을 측정하는 방법에 관한 것이다.
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公开(公告)号：KR1020100127620A
公开(公告)日：2010-12-06
申请号：KR1020090046141
申请日：2009-05-26
Applicant: 한국화학연구원
Abstract: PURPOSE: A solvent extract method of hydroxybenzene and phenol inside an aqueous solution is provided to secure the excellent extraction result when using a solvent including a phosphate group and a ketone group. CONSTITUTION: A solvent extract method of hydroxybenzene and phenol inside an aqueous solution comprises a step of adding triphenyl phosphate, ketone, or trialkyl phosphate with the aqueous solution as an extraction solvent, and centrifugal separating the solution. The aqueous solution contains 0.1~3M of phenol, 0.01~1M of hydro-quinone, 0.01~1M of Catechol, and 0.001~0.1M of benzoquinone.
Abstract translation: 目的：提供水溶液中羟基苯和苯酚的溶剂萃取方法，以确保使用包括磷酸酯基和酮基在内的溶剂时的优异萃取效果。 构成：水溶液中的羟基苯和苯酚的溶剂萃取方法包括以水溶液作为萃取溶剂添加磷酸三苯酯，酮或磷酸三烷基酯的步骤，并离心分离溶液。 该水溶液含有苯酚0.1〜3M，氢醌0.01〜1M，邻苯二酚0.01〜1M，苯醌0.001〜0.1M。
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公开(公告)号：KR1020100125798A
公开(公告)日：2010-12-01
申请号：KR1020090044672
申请日：2009-05-21
Applicant: 한국화학연구원
CPC classification number: C01B32/05 , B01J20/20 , B01J20/28078 , C01B32/90
Abstract: PURPOSE: A mesoporous carbon producing composition and a producing method of mesoporous carbon using thereof are provided to simply produce the mesoporous carbon, and to economically enlarge the size of pores. CONSTITUTION: A mesoporous carbon producing composition contains the following: 100 parts of solvent by weight mixed with water, alcohol, or their mixture; 1~20 parts of non-ionic surfactant by weight; 1~20 parts of hydrochloric acid by weight; 1~40 parts of pore size controlling material by weight; 5~100 parts of silica precursor b weight; and 1~50 parts of resol by weight as a carbon precursor. The non-ionic surfactant is selected from the group consisting of a fluorine polymer, and a tetraalkyl ammonium system and an ethylene oxide-propylene oxide-ethylene oxide block copolymer.
Abstract translation: 目的：提供介孔碳产生组合物及其使用的介孔碳的制造方法，以简单地生产中孔碳，并且经济地扩大孔的尺寸。 构成：介孔碳产生组合物包含以下物质：100份溶剂与水，醇或它们的混合物混合; 1〜20份非离子表面活性剂重量; 1〜20份重量的盐酸; 1〜40份重量的孔径控制材料; 5〜100份二氧化硅前体b重量; 和1〜50份重量份的碳前体。 非离子表面活性剂选自氟聚合物，四烷基铵体系和环氧乙烷 - 环氧丙烷 - 环氧乙烷嵌段共聚物。
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