公开(公告)号：KR100695473B1

公开(公告)日：2007-03-16

申请号：KR1020060021427

申请日：2006-03-07

Applicant: 한국화학연구원

Inventor： 장종산 ,  정성화 ,  황영규 ,  채희권 ,  최재용

IPC: C08G63/83 ,  C08G63/78 ,  C08G63/88

CPC classification number: C08G79/00 ,  C08J9/286 ,  C08J2385/00

Abstract: Provided are a method for preparing a porous zinc-based carboxylic acid coordination polymer compound which has a high BET surface area of 3,000 m^2/g or more and a large pore volume. The method comprises the steps of mixing a zinc precursor, a carboxylic acid compound or its mixture, and a solvent to prepare a reaction mixture; and irradiating a microwave of 0.3-300 GHz to the reaction mixture to heat it at 20-120 deg.C. Preferably, the solvent is at least one selected from N,N-dimethylformaldehyde, N,N-diethylformaldehyde, an alcohol, a ketone and a hydrocarbon; and the carboxylic acid compound is terephthalic acid or 2,6-naphthalenedicarboxylic acid.

Abstract translation: 提供一种制备多孔锌基羧酸配位聚合物化合物的方法，其具有3000m 2 / g以上的高BET表面积和较大孔体积。 该方法包括混合锌前体，羧酸化合物或其混合物和溶剂以制备反应混合物的步骤; 并将0.3-300GHz的微波照射到反应混合物中以在20-120℃加热。 优选地，溶剂是选自N，N-二甲基甲醛，N，N-二乙基甲醛，醇，酮和烃中的至少一种; 羧酸化合物是对苯二甲酸或2,6-萘二甲酸。