公开(公告)号：KR100816538B1

公开(公告)日：2008-03-25

申请号：KR1020060091237

申请日：2006-09-20

Applicant: 한국화학연구원

Inventor： 장종산 ,  황영규 ,  정성화 ,  홍도영 ,  김덕규 ,  제라드페레이 ,  크리스찬세레

IPC: B82B3/00 ,  B01J31/00

CPC classification number: B01J31/02 ,  B01J37/00 ,  B82Y30/00 ,  B82Y40/00

Abstract: A method for preparing a surface-functionalized porous organic-inorganic hybrid material or mesoporous material is provided to be applicable to an adsorber, a gas storage material, a sensor, a membrane, a functional thin film, a catalyst, a catalyst carrier and the like. A method for preparing a surface-functionalized porous organic-inorganic hybrid material or mesoporous material comprises reaction of porous organic-inorganic hybrid materials having coordinatively unsaturated metal sites with at least one compound selected from silane, an organic metal compound and polyoxometallate. Particularly, the porous organic-inorganic hybrid material is a crystalline polymer compound of a microporous structure, which is formed by combination of a core metal ion thereof with an organic ligand. In the method, the reaction comprises depositing the silane or the organic metal compound onto the porous organic-inorganic hybrid material, or introducing the porous organic-inorganic hybrid material into a solution of the organic metal compound or polyoxometallate.

Abstract translation: 提供了一种制备表面官能化多孔有机 - 无机混合材料或介孔材料的方法，可应用于吸附剂，储气材料，传感器，膜，功能薄膜，催化剂，催化剂载体和 喜欢。 制备表面官能化的多孔有机 - 无机杂化材料或介孔材料的方法包括具有配位不饱和金属位点的多孔有机 - 无机杂化材料与至少一种选自硅烷，有机金属化合物和多金属氧酸盐的化合物的反应。 特别地，多孔有机 - 无机混合材料是由其核心金属离子与有机配体组合形成的微孔结构的结晶高分子化合物。 在该方法中，反应包括将硅烷或有机金属化合物沉积到多孔有机 - 无机杂化材料上，或将多孔有机 - 无机杂化材料引入有机金属化合物或多金属氧酸盐的溶液中。