公开(公告)号：KR100792038B1

公开(公告)日：2008-01-04

申请号：KR1020060091377

申请日：2006-09-20

Applicant: 한국화학연구원

Inventor： 장종산 ,  정성화 ,  황영규 ,  윤지웅 ,  시몬엠.험프리 ,  파울티.우드

IPC: C08J9/04 ,  C08J9/06 ,  C08F8/04

Abstract: A method for preparing a porous coordination polymer is provided to obtain a porous crystalline material having a three-dimensional framework structure and useful for selective gas adsorption and separation, and ultrapure semiconductor gas purification. A method for preparing a porous coordination polymer comprises a step of hydrothermally reacting a divalent metal chloride(MCl2, wherein M is Co2+, Ni2+, Cr2+, Fe2+, Mn2+, Zn2+ or Al2+) hydrated in a basic aqueous solution with pyridine-2,4-dicarboxylic acid to form a porous coordination polymer hydrate. In the method, the reaction mixture is purged with an inert gas before the hydrothermal reaction, and then heated to 150-250 deg.C in an autoclave reactor.

Abstract translation: 提供一种制备多孔配位聚合物的方法，以获得具有三维骨架结构并可用于选择性气体吸附和分离的多孔结晶材料，以及超纯的半导体气体净化。 制备多孔配位聚合物的方法包括将在碱性水溶液中水合的二价金属氯化物（MCl 2，其中M是Co 2+，Ni 2+，Cr 2+，Fe 2+，Mn 2+，Zn 2+或Al 2+）与吡啶-2,4 二羧酸形成多孔配位聚合物水合物。 在该方法中，在水热反应之前用惰性气体吹扫反应混合物，然后在高压釜反应器中加热至150-250℃。