公开(公告)号：WO2014038851A1

公开(公告)日：2014-03-13

申请号：PCT/KR2013/007986

申请日：2013-09-04

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C08K9/10 ,  C08K3/04 ,  C01B31/02 ,  H01B1/24

CPC classification number: H01B1/24

Abstract: 본 발명은 CNT-exfoliated-Garphene 혹은 나노금속 균일하게 흡착된 CNT-exfoliated-Garphene을 포함하는 마이크로캡슐의 제조방법과 상기 캡슐들을 함유한 전도성 고분자 충전제가 첨가된 전도성 열가소성 수지 조성물의 제조 방법을 제시하고 있다.

Abstract translation: 本发明涉及一种制备包含均匀吸附的纳米金属的CNT-剥离的石墨烯或CNT-剥离的石墨烯的微胶囊的制备方法，以及一种包含导电性聚合物填料的导电性热塑性树脂组合物的制造方法。

公开(公告)号：WO2010150982A9

公开(公告)日：2010-12-29

申请号：PCT/KR2010/003291

申请日：2010-05-25

Applicant: 한밭대학교 산학협력단 ,  김창섭 ,  김상헌 ,  장용

Inventor： 김창섭 ,  김상헌 ,  장용

IPC: A61K38/16 ,  A61K39/145 ,  A61K39/42 ,  A61K9/16 ,  C07K14/11 ,  A61P31/12

Abstract: 본 발명은 막 융합 (membrane fusion) 기능이 결여 또는 저하되어 생체 안전성이 뛰어난 인플루엔자 바이러스 백신용 항원성 에피토프 (antigenic epitope)로서의 재조합 HA (hemagglutinin) 단백질, 상기 재조합 HA 단백질을 함유하는 PLGA [poly(lactic- co -glycolic acid)] 미립자를 제조하는 방법 및 상기 방법에 의해 제조된 인플루엔자 바이러스 백신용 PLGA 미립자에 관한 것이다.

公开(公告)号：KR101362124B1

公开(公告)日：2014-02-12

申请号：KR1020130067515

申请日：2013-06-13

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C01G15/00 ,  C01G19/00 ,  C01G9/00 ,  B82B1/00

Abstract: The present invention relates to a manufacturing method of indium zinc tin oxide (IZTO) powder having a micro particle size, and more specifically a method to yield a large amount of non-cohesive nano IZTO by adding organic additives in a reaction solution so as to produce micro-sized IZTO power, spraying into droplets using a spray pyrolysis technique, producing a hollow or a porous form of precursor powder, and by a frit sealing and a milling process.

Abstract translation: 本发明涉及一种具有微粒尺寸的铟锌锡氧化物（IZTO）粉末的制造方法，更具体地，涉及通过在反应溶液中加入有机添加剂而产生大量非粘性纳米IZTO的方法，以便 产生微型IZTO动力，使用喷雾热解技术喷射到液滴中，产生中空或多孔形式的前体粉末，以及通过玻璃料密封和研磨过程。

公开(公告)号：KR101186962B1

公开(公告)日：2012-09-28

申请号：KR1020110120008

申请日：2011-11-17

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C08L33/16 ,  C08L33/06 ,  C08F220/22 ,  C08L101/00

Abstract: PURPOSE: A transparent flame-retardant plastic additive is provided to have excellent flame retardance, transparence and scratch resistance, and to be uniformly dispersed when mixing with thermoplastic plastic. CONSTITUTION: A transparent flame-retardant plastic additive comprises 0.01-10 parts by weight of transparent flame additives based on 100.0 parts by weight of thermoplastic resin. The additives are copolymers. The copolymer contains: one or more monomers selected from a fluorine atom-containing fluorinated (meth)acrylate group; one or more monomers selected from C1-7 alkyl(meth)acryl-based monomers; one or more monomers selected from a (meth)acrylate group having C8-30 substituent having a structure of chemical formula 2b; and one or more components selected from acrylonitrile, vinyl acetate or acrylic acid.

Abstract translation: 目的：提供透明阻燃塑料添加剂，具有优异的阻燃性，透明性和耐刮擦性，并与热塑性塑料混合时均匀分散。 构成：透明阻燃塑料添加剂包含0.01-10重量份基于100.0重量份热塑性树脂的透明火焰添加剂。 添加剂是共聚物。 共聚物含有：选自含氟原子的氟代（甲基）丙烯酸酯基中的一种或多种单体; 一种或多种选自C 1-7烷基（甲基）丙烯酸基单体的单体; 一种或多种选自具有化学式2b结构的具有C8-30取代基的（甲基）丙烯酸酯基团的单体; 和一种或多种选自丙烯腈，乙酸乙烯酯或丙烯酸的组分。

公开(公告)号：KR101173039B1

公开(公告)日：2012-08-10

申请号：KR1020110133652

申请日：2011-12-13

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C08F14/22 ,  C08F20/18 ,  C08L27/16 ,  C08L69/00

CPC classification number: C08F14/22 ,  C08F259/08 ,  C08L27/16 ,  C08L69/00

Abstract: PURPOSE: A transparent flame-retardant plastic additive composition is provided to reinforce heat durability of alkyl methacrylic based resin, and to uniformly disperse particles at mixing with thermoplastic plastic. CONSTITUTION: A transparent flame-retardant plastic additive composition contains a flame retardant improver. The flame retardant improver comprises polyvinylidene fluoride or a polyvinylidene fluoride copolymer core layer, and acryl-based resin shell layer which is manufactured by comprising one or more monomers selected from an alkyl(meth)acryl-based monomer, a vinyl-based monomer, or a (meth)acrylic acid monomer. The transparent flame-retardant plastic thermoplastic resin composition comprises 100.0 parts by weight of a thermoplastic resin, 0.001-10 parts by weight of the additives of the transparent flame-retardant plastic thermoplastic resin composition.

Abstract translation: 目的：提供一种透明阻燃塑料添加剂组合物，以增强烷基甲基丙烯酸系树脂的耐热性，并使颗粒与热塑性塑料混合均匀分散。 构成：透明阻燃塑料添加剂组合物含有阻燃改进剂。 阻燃改进剂包括聚偏二氟乙烯或聚偏二氟乙烯共聚物芯层，以及丙烯酸类树脂壳层，其通过包含一种或多种选自（甲基）丙烯酸烷基酯单体，乙烯基类单体或 （甲基）丙烯酸单体。 透明阻燃塑料热塑性树脂组合物包含100.0重量份的热塑性树脂，0.001-10重量份的透明阻燃塑料热塑性树脂组合物的添加剂。

公开(公告)号：KR101241750B1

公开(公告)日：2013-03-25

申请号：KR1020120098024

申请日：2012-09-05

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C08K9/10 ,  C08K3/04 ,  C01B31/02 ,  H01B1/24

CPC classification number: H01B1/24 ,  C08K9/10 ,  C01B32/15 ,  C01B32/158 ,  C01B32/168 ,  C01B32/182 ,  C01B32/194 ,  C01B2202/20 ,  C08K3/04

Abstract: PURPOSE: A manufacturing method for a microcapsule-shaped conductive filler is provided to have excellent electrostatic properties despite using a small amount of carbon nanotube-exfoliated-graphene or a carbon nanotube-exfoliated graphene with a uniformly attached nanometal. CONSTITUTION: A manufacturing method for a microcapsule-shaped conductive filler comprises: a step of refluxing graphene and a carbon nanotube using a nitric acid, cleaning and irradiating the result with solar rays, and manufacturing a carbon nanotube-exfoliated graphene which is separated by a carbon nanotube; a step of mixing the graphene with an aqueous solution comprising an emulsifier and water, or an aqueous solution comprising an emulsifier, water, and an aqueous polymer in order to obtain a dispersed solution; and a step of adding a polymerizable monomer into the dispersed solution, polymerizing the same, and microcapsulating the graphene by a thermoplastic resin layer.

Abstract translation: 目的：尽管使用少量的碳纳米管剥离石墨烯或具有均匀附着的纳米金属的碳纳米管剥离的石墨烯，但是提供了一种微胶囊状导电填料的制造方法以具有优异的静电性能。 构成：微胶囊状导电填料的制造方法包括：使用硝酸回流石墨烯和碳纳米管的步骤，用太阳射线清洗并照射结果，制造碳纳米管剥离的石墨烯，其被 碳纳米管; 将石墨烯与包含乳化剂和水的水溶液或包含乳化剂，水和水性聚合物的水溶液混合以获得分散溶液的步骤; 以及将可聚合单体加入到分散溶液中的步骤，使其聚合，并通过热塑性树脂层将石墨烯微胶囊化。

公开(公告)号：KR101198087B1

公开(公告)日：2012-11-09

申请号：KR1020110120006

申请日：2011-11-17

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: C08K9/10 ,  C08K3/04 ,  C08L53/00 ,  B01J13/14

CPC classification number: C08K3/04 ,  B01J13/14 ,  B82Y30/00 ,  C08F10/02 ,  C08F12/16 ,  C08F20/06 ,  C08K3/08 ,  C08K9/10 ,  C08K2201/011 ,  C08L53/005 ,  C08L53/02

Abstract: PURPOSE: A manufacturing method of thermoconductive polymer filler is provided to prevent re-coherence of graphene which was dispersed in a polymerization step by using a water-soluble block copolymer, and to maintain the dispersed state. CONSTITUTION: A manufacturing method of thermoconductive polymer filler comprises: a step of mixing graphene, a water-soluble block copolymer, an emulsifier and water, and obtaining aqueous solution of graphene by high rate-dispersing the mixture by a homogenizer; a step of microcapsulation by emulsification polymerizing the aqueous solution and one or more monomers comprising an addition-polymerizable ethylene group to make the graphene be surrounded with a thermoplastic resin layer; and a step of forming a flock by binding the microcapsules.

Abstract translation: 目的：提供一种导热聚合物填料的制造方法，以防止通过使用水溶性嵌段共聚物在聚合步骤中分散的石墨烯的重新相干性并保持分散状态。 构成：导热聚合物填料的制造方法包括：将石墨烯，水溶性嵌段共聚物，乳化剂和水混合的步骤，通过均化器高速分散混合物，得到石墨烯的水溶液; 通过乳化聚合水溶液和一种或多种包含可加聚乙烯基团的单体以使石墨烯被热塑性树脂层包围的微胶囊化步骤; 以及通过结合微胶囊形成绒毛的步骤。

公开(公告)号：KR101938341B1

公开(公告)日：2019-04-10

申请号：KR1020170063028

申请日：2017-05-22

Applicant: 한밭대학교 산학협력단 ,  주식회사 더나인칼라

Inventor： 김상헌 ,  김상필 ,  한종수 ,  장윤진 ,  이재환

IPC: C09D193/00 ,  C09D5/24 ,  C09D7/40 ,  H01B1/02 ,  H01B1/04 ,  H05K9/00

公开(公告)号：KR101458505B1

公开(公告)日：2014-11-07

申请号：KR1020140027130

申请日：2014-03-07

Applicant: 한밭대학교 산학협력단

Inventor： 김상헌

IPC: H01M4/525 ,  H01M4/505

CPC classification number: C01G45/12 ,  C01P2004/82 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525

Abstract: 본 발명은 옥살산 음이온 열분해법을 이용한 리튬-니켈-코발트-망간 복합 산화물의 제조방법에 관한 것으로, 단순하고 친환경적인 공정이 가능한 리튬-니켈-코발트-망간 복합 산화물의 제조방법을 제공하고자 한다.

Abstract translation: 本发明涉及通过使用草酸盐阴离子的热降解来制造锂镍钴钴复合氧化物的方法。 提供了一种制造锂 - 钴 - 钴 - 锰复合氧化物的方法，其可以简单和环保的方法。 该方法包括以下步骤：A）将镍源，钴源和锰源溶解在水中以制备金属前体的水溶液; B）通过在前体水溶液中加入草酸沉淀剂形成草酸基沉淀; C）通过干燥草酸基沉淀物使草酸沉淀物脱水; 和D）将脱水的草酸沉淀物和锂源混合并在氧气氛下进行热处理。

公开(公告)号：KR101157460B1

公开(公告)日：2012-06-22

申请号：KR1020110002877

申请日：2011-01-11

Applicant: 한밭대학교 산학협력단 ,  주식회사 나노신소재

Inventor： 김상헌

IPC: C01G9/02 ,  B01J2/04

Abstract: PURPOSE: A manufacturing method of aluminium oxide doped zinc oxide(azo) powder by using a spray pyrolysis is provided to manufacture porous typed or hollowed powders by mixing an organic additive with AZO precursor spray solution. CONSTITUTION: A manufacturing method of aluminium oxide doped zinc oxide(azo) powder by using a spray pyrolysis comprises the following steps: manufacturing a precursor mixed solution by mixing an additive which includes organic carboxylic acid and glycol, with zinc precursor, aluminum precursor, and water; forming porous aluminum-doped zinc oxide(AZO) powder by spraying the precursor mixed solution in a furnace; and plasticizing and milling the aluminum-doped zinc oxide powder(AZO).

Abstract translation: 目的：提供通过使用喷雾热解法制备氧化铝掺杂氧化锌（偶氮）粉末的方法，通过将有机添加剂与AZO前体喷雾溶液混合来制造多孔型或中空粉末。 构成：通过使用喷雾热解制备氧化铝掺杂氧化锌（偶氮）粉末的方法包括以下步骤：通过将包含有机羧酸和二醇的添加剂与锌前体，铝前体和 水; 通过将前体混合溶液喷雾在炉中形成多孔铝掺杂氧化锌（AZO）粉末; 并对铝掺杂的氧化锌粉末（AZO）进行增塑和研磨。