公开(公告)号：WO2020065591A1

公开(公告)日：2020-04-02

申请号：PCT/IB2019/058199

申请日：2019-09-26

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： ABE, Hidetoshi ,  SAITO, Koji

IPC: G09F9/33 ,  G09F13/22 ,  G09F13/04

Abstract: A graphic sheet including: a transparent rigid film substrate; and a receptor layer disposed on the transparent rigid film substrate, the receptor layer containing an acrylic polymer and a white pigment filler; wherein the receptor layer contains not less than 5 parts by mass and not more than 50 parts by mass of the white pigment filler per 100 parts by mass of the acrylic polymer; and a total visible light transmittance of the sheet is not less than 8% and not greater than 50% is described.

公开(公告)号：WO2018122732A1

公开(公告)日：2018-07-05

申请号：PCT/IB2017/058421

申请日：2017-12-27

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： SAITO, Koji ,  ABE, Hidetoshi

IPC: B44C1/10 ,  B44C3/02

Abstract: A decorative sheet including a base material, a three-dimensional shape printed portion provided on the base material by ultraviolet light curing inkjet printing, and an over-laminate film laminated on the base material and the printed portion, the over-laminate film including a film layer and an adhesive layer and having a three-dimensional shape following the three-dimensional shape of the printed portion.

公开(公告)号：WO2009055378A3

公开(公告)日：2009-04-30

申请号：PCT/US2008/080628

申请日：2008-10-21

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  FURUSAWA, Masaaki ,  ABE, Hidetoshi

Inventor： FURUSAWA, Masaaki ,  ABE, Hidetoshi

IPC: C08J5/18 ,  C08L33/08 ,  C08L33/10 ,  C08L33/14

Abstract: The present application provides a (meth)acrylic film having an excellent balance between film strength at room temperature and conformability properties at low temperature, and a marking film comprising the (meth)acrylic film. The present application is a (meth)acrylic film comprising a (meth)acrylic polymer containing a carboxyl group, a (meth)acrylic polymer containing an amino group, a polyacrylate with a weighted average molecular weight in a range between 1000 and 4000 and with a reactive functional group, and a cross-linking agent having a functional group that reacts with amino groups and carboxyl groups, and the present application provides a (meth)acrylic film having the polyacrylate in an amount in the range between 0.5 and 30 mass parts with regards to 100 mass parts of the sum of the (meth)acrylic polymer containing a carboxyl group and the (meth)acrylic polymer containing a amino group, as well as a marking film that contains this (meth)acrylic film.

公开(公告)号：WO2009018246A2

公开(公告)日：2009-02-05

申请号：PCT/US2008/071415

申请日：2008-07-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ABE, Hidetoshi ,  FURUSAWA, Masaaki ,  TAKAMATSU, Yorinobu

Inventor： ABE, Hidetoshi ,  FURUSAWA, Masaaki ,  TAKAMATSU, Yorinobu

IPC: C09J133/04 ,  C09J7/02 ,  B32B27/00 ,  B32B7/12

CPC classification number: B32B27/30 ,  B32B7/06 ,  B32B7/10 ,  C08L33/14 ,  C08L2666/04 ,  C09J133/08 ,  C09J2201/606 ,  Y10T428/1476 ,  Y10T428/24612

Abstract: The present invention is directed to providing a pressure-sensitive adhesive with good initial tack and good adhesion at low temperature. Generally, the pressure-sensitive adhesive composition comprises (1) a carboxylic group- containing (meth)acrylic tacky polymer having a weight average molecular weight of less than 800,000 and a glass transition temperature of -100° C to -30° C, and (2) an amino group- containing (meth)acrylic non-tacky polymer having a weight average molecular weight of from 30,000 to 100,000 and a glass transition temperature of 20° C to 90° C. The amino group- containing (meth)acrylic non-tacky polymer (2) is present in an amount of no less than 1 parts by mass and less than 20 parts by mass on a basis of 100 parts by mass of said carboxylic group- containing (meth)acrylic tacky polymer (1).

Abstract translation: 本发明涉及提供具有良好初始粘着性和低温粘合性的压敏粘合剂。 通常，压敏粘合剂组合物包含（1）重均分子量小于800,000，玻璃化转变温度为-100℃至-30℃的含羧基的（甲基）丙烯酸系粘性聚合物，以及 （2）重均分子量为30,000〜100,000，玻璃化转变温度为20〜90℃的含氨基（甲基）丙烯酸系非粘性聚合物。含氨基的（甲基）丙烯酸 基于100质量份所述含羧基的（甲基）丙烯酸系粘性聚合物（1），非粘性聚合物（2）的含量为1质量份以上且小于20质量份， 。

公开(公告)号：WO2004060688A1

公开(公告)日：2004-07-22

申请号：PCT/US2003/039284

申请日：2003-12-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ABE, Hidetoshi

Inventor： ABE, Hidetoshi

IPC: B41M5/00

CPC classification number: B41M5/529 ,  B41M5/504 ,  B41M5/5281 ,  B44C1/105

Abstract: To provide a marking film, which has good resistance to petroleum and moisture and is suitable as a marking film of a vehicle that moves using a petroleum fuel. A marking film comprising a receptor film having a front surface as a colorant-receptive surface, and a back surface, a colorant received on the front surface of the receptor film, and an adhesive layer provided on the back surface of the receptor film and comprising an adhesive which serves to adhere the receptor film to an adherent, wherein the adhesive layer has projections containing the adhesive, which are formed on an adhesion surface, and depressions surrounding the projections, and the depressions define conduits, which communicate with the atmosphere, between the surface of the adherent and the adhesion surface of the adhesive layer when the adhesive layer is being adhered to the adherent, characterized in that the receptor film comprises a receptor layer formed of a thermoplastic resin film having a surface which serves as the colorant-receptive surface, and the thermoplastic resin film comprises a resinous component containing at least one petroleum-resistant resin selected from the group consisting of polyurethane comprising polyol units derived from polycarbonate polyol, polyurethane comprising polyol units derived from polycaprolactone polyol and phenoxy resins, or the receptor film is a petroleum-resistant resin film containing a copolymer comprising a C 1 -C 8 -alkyl acrylate and methyl methacrylate.

Abstract translation: 提供具有良好的耐石油和水分的标记膜，并且适合作为使用石油燃料移动的车辆的标记膜。 一种标记膜，其包括具有作为着色剂接收表面的前表面的接收膜，以及接收在所述接收膜的前表面上的背面，着色剂和设置在所述接收膜的背面上的粘合层， 用于将接收膜粘附到粘合剂上的粘合剂，其中粘合剂层具有形成在粘合表面上的包含粘合剂的突起和围绕突起的凹陷，并且凹陷限定了与大气连通的导管， 当粘合剂层粘附到粘合剂上时粘合剂层的粘附表面和粘合表面的表面，其特征在于，受体膜包括由具有用作着色剂接受性的表面的热塑性树脂膜形成的受体层 表面，并且热塑性树脂膜包括含有至少一种选自耐油树脂的树脂成分 来自由聚碳酸酯多元醇衍生的多羟基化合物单元的聚氨酯组成的组，由聚己内酯多元醇衍生的多羟基化合物单元的聚氨酯和苯氧基树脂构成，或者是受阻膜，是含有丙烯酸C1〜C8烷基酯和甲基 甲基丙烯酸甲酯。

公开(公告)号：WO2019155359A3

公开(公告)日：2019-08-15

申请号：PCT/IB2019/050919

申请日：2019-02-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： ARAKI, Yoshinori ,  ABE, Hidetoshi ,  DOBASHI, Takeshi ,  SAITO, Junichi ,  OKURA, Ken ,  FURUSAWA, Masaaki

IPC: E01F9/512

Abstract: Object: To provide a decorative sheet for a road surface having enhanced surface strength with respect to a large vehicle weight of a vehicle and having enhanced stationary steering resistance against a steering operation performed while a vehicle is stopped. Solution: A decorative sheet for a road surface according to an embodiment of the present invention includes: a graphic construct including an adhesive layer, and a design layer provided on the adhesive layer; and a surface coating layer covering the graphic construct and containing a urethane resin.

公开(公告)号：WO2018189626A1

公开(公告)日：2018-10-18

申请号：PCT/IB2018/052336

申请日：2018-04-04

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： ABE, Hidetoshi ,  IMAMURA, Kengo ,  ONO, Katsuya ,  TAKEDA, Yoshihiko ,  YAMAMOTO, Takeo

IPC: C09J7/38 ,  C09J7/25 ,  C08K7/16 ,  C09J7/29

CPC classification number: C09J7/38 ,  C08K7/16 ,  C09J7/255 ,  C09J7/29 ,  C09J2201/606 ,  C09J2205/102 ,  C09J2205/11 ,  C09J2400/163 ,  C09J2433/00 ,  C09J2467/006

Abstract: An adhesive sheet of an embodiment of the present disclosure is an adhesive sheet including: a rigid resin film having a thickness of 80 micrometers to 500 micrometers, and a first pressure sensitive adhesive layer being disposed on or above a surface of the rigid resin film, wherein the first pressure sensitive adhesive layer includes elastic resin microspheres having a volume average particle diameter of 110 micrometers or greater and a tacky binder, and the first pressure sensitive adhesive layer has an uneven surface due to the presence of the microspheres.

公开(公告)号：WO2011088096A2

公开(公告)日：2011-07-21

申请号：PCT/US2011/020957

申请日：2011-01-12

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ABE, Hidetoshi ,  TAKAMATSU, Yorinobu ,  STEELMAN, Ronald S. ,  TORIUMI, Naoyuki ,  DANIELS, Michael P.

Inventor： ABE, Hidetoshi ,  TAKAMATSU, Yorinobu ,  STEELMAN, Ronald S. ,  TORIUMI, Naoyuki ,  DANIELS, Michael P.

CPC classification number: C09J7/24 ,  C08K5/3412 ,  C08L33/14 ,  C08L33/26 ,  C08L2205/025 ,  C09J2201/622 ,  C09J2433/00 ,  C09J2433/006 ,  Y10T428/28

Abstract: The present application is directed to an acrylic polymer. Specifically, a marking film comprising a film layer which comprises a polymer blend of a first (meth)acrylic polymer having a glass transition temperature of 30 degrees C to 180 degrees C and a second (meth)acrylic polymer having a glass transition temperature of over -80 degrees C less than 30 degrees C. One from the first and second (meth)acrylic polymers comprises a carboxylic group and another comprises an amide group. The marking film additionally comprises an adhesive layer.

Abstract translation: 本申请涉及一种丙烯酸类聚合物。 具体而言，提供一种由玻璃化转变温度为30℃〜180℃的第一（甲基）丙烯酸类聚合物和玻璃化转变点以上的第二（甲基）丙烯酸类聚合物的聚合物混合物构成的膜层 -80摄氏度，小于30摄氏度。第一和第二（甲基）丙烯酸聚合物中的一个包含羧基，另一个包含酰胺基。 标记膜还包括粘合剂层。

公开(公告)号：WO2003076542A1

公开(公告)日：2003-09-18

申请号：PCT/US2003/006476

申请日：2003-03-03

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： ABE, Hidetoshi ,  ENDOH, Hideto

IPC: C09J7/02

CPC classification number: G03G7/0086 ,  B32B27/40 ,  B41M5/504 ,  B41M5/52 ,  B41M5/5272 ,  B41M5/5281 ,  B41M7/0027 ,  C08G18/4277 ,  C08G18/44 ,  C08L61/00 ,  C09D175/06 ,  C09J7/25 ,  C09J7/29 ,  C09J2201/162 ,  C09J2201/28 ,  C09J2461/006 ,  C09J2475/006 ,  Y10T428/24612 ,  Y10T428/24901 ,  Y10T428/2848 ,  C08L2666/14

Abstract: To provide a marking film, which has good resistance to petroleum and moisture and is suitable as a marking film of a vehicle that moves using a petroleum fuel. A marking film comprising a receptor film having a front colorant-receptive surface, and a back surface, and an adhesive layer provided on the back surface of the receptor film and comprising an adhesive which serves to adhere the receptor film to an adherend, wherein the adhesive layer has projections containing the adhesive, which are formed on an adhesion surface to be adhered to the adherend, and depressions surrounding the projections, and the depressions define conduits, which communicate with the atmosphere, between the surface of the adherend and the adhesion surface of the adhesive layer when the adhesive layer is being adhered to the adherend, characterized in that the receptor film comprises a receptor layer formed of a thermoplastic resin film having a surface which serves as the colorant-receptive surface, and the thermoplastic resin film comprises a resinous component containing at least one petroleum-resistant resin selected from the group consisting of polyurethane comprising polyol units derived from polycarbonate polyol, polyurethane comprising polyol units derived from polycaprolactone polyol and phenoxy resins.

Abstract translation: 提供具有良好的耐石油和水分的标记膜，并且适合作为使用石油燃料移动的车辆的标记膜。 一种标记膜，其包括具有前着色剂接收表面的接收膜和背面，以及设置在接收膜的背面上的粘合剂层，并且包括用于将受体膜粘附到被粘物上的粘合剂，其中， 粘合剂层具有包含粘合剂的突起，其形成在粘合表面上以粘合到被粘物上，并且凹陷围绕突起，并且凹陷限定了与被粘附物的表面和粘附表面之间的大气连通的导管 所述粘合剂层粘合到所述被粘物上时，所述粘合剂层的特征在于，所述受体膜包括由具有作为着色剂接受表面的表面的热塑性树脂膜形成的受体层，所述热塑性树脂膜包含 含有至少一种选自聚氨酯组合物的耐油树脂的树脂组分 衍生自聚碳酸酯多元醇的上升多元醇单元，包含衍生自聚己内酯多元醇的多元醇单元的聚氨酯和苯氧树脂。

公开(公告)号：WO2002057387A3

公开(公告)日：2002-07-25

申请号：PCT/US2001/049791

申请日：2001-10-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  ABE, Hidetoshi ,  KOYAMA, Takeshi

Inventor： ABE, Hidetoshi ,  KOYAMA, Takeshi

IPC: C09J175/04

Abstract: To provide an adhesive composition which can effectively improve the thermal-peeling-easy properties and the adhesion properties at low temperature at the same time. An adhesive composition comprising a crystalline polymer which comprises polyol units formed from a crystalline polyol as repeating units in the molecule, and a tackifying polymer compatible with said crystalline polymer at a temperature higher than the melting point of said crystalline polymer, wherein the tackifying polymer has an alkyl group with 4 to 8 carbon atoms and a carboxyl group in the molecule, a content of the monomeric units having the alkyl group with 4 to 8 carbon atoms (repeating units derived from a starting monomer having the alkyl group) is 60 to 99 mole % of the whole monomeric units of the tackifying polymer, and the alkyl group includes a butyl group.