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公开(公告)号:WO2020191579A1
公开(公告)日:2020-10-01
申请号:PCT/CN2019/079523
申请日:2019-03-25
Applicant: 3M INNOVATIVE PROPERTIES COMPANY , YAO, Li
Inventor: YAO, Li , KROPP, Michael A. , KRYGER, Matthew J. , MAHONEY, Wayne S. , PEREZ, Mario A. , WU, Shuang , TONG, Lingjie , SHAABAN, Ahmad , JUNG, Adrian T. , HIGGINS, Jeremy M. , LIN, Ying
IPC: C08L63/00 , C08G59/66 , C08K3/36 , C09J163/00 , H01M8/10
Abstract: A curable composition includes a first part comprising an epoxy resin; and a second part comprising a multifunctional, functional thiol containing compound. The curable composition further includes an inorganic filler present in an amount of at least 20 weight %, based on the total weight of the curable composition. The multifunctional, functional thiol containing compound comprises an ether in the backbone thereof.
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公开(公告)号:WO2019202453A1
公开(公告)日:2019-10-24
申请号:PCT/IB2019/053047
申请日:2019-04-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: GALUSH, Thomas B. , FRONEK, Daniel R. , KRYGER, Matthew J.
IPC: C09J7/38
Abstract: Method of applying an high velocity oxygen fuel (HVOF)-resistant masking tape to the surface of a workpiece (112) such that multiple lengths of tape (116, 118) are abutted to one another to form butt joints (132), the butt joint (132) is then covered with additional lengths of tape (120).
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公开(公告)号:WO2018229583A1
公开(公告)日:2018-12-20
申请号:PCT/IB2018/053856
申请日:2018-05-30
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: KRYGER, Matthew J. , KROPP, Michael A. , GALUSH, Thomas B. , FRONEK, Daniel R.
IPC: C08G59/00 , C09J163/00 , C09J163/04 , C08L63/00
Abstract: Curable epoxy/thiol resin compositions, methods of curing, methods of bonding substrates, and tapes including the cured polymeric material, wherein the curable epoxy/thiol resin composition includes: an epoxy resin component comprising an epoxy resin having at least two epoxide groups per molecule; a thiol component comprising a polythiol compound having at least two primary thiol groups; a silane-functionalized adhesion promoter; a nitrogen-containing catalyst for curing the epoxy resin; and optionally a cure inhibitor.
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公开(公告)号:WO2022123498A1
公开(公告)日:2022-06-16
申请号:PCT/IB2021/061535
申请日:2021-12-09
Applicant: 3M INNOVATIVE PROPERTIES COMPANY [US]/[US]
Inventor: SAHOUANI, Hassan , KRYGER, Matthew J.
IPC: C08F220/34 , C08G59/18 , C08L63/00
Abstract: The crosslinked polymer particles include a plurality of pendent tertiary amine groups and at least 20 percent by weight poly(alkyleneoxy) crosslinking segments, based on the total weight of the crosslinked polymer particles. Further particles include cores of crosslinked polymer particles having a plurality of tertiary amine groups and shells of an inorganic salt encapsulating the cores. The inorganic salt includes a multivalent cation and a multivalent anion. Compositions and articles including the particles and processes for making the particles and the crosslinked polymer particles are also described.
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公开(公告)号:WO2021260557A1
公开(公告)日:2021-12-30
申请号:PCT/IB2021/055516
申请日:2021-06-22
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: DENG, Shuanghul , KROPP, Michael A. , KRYGER, Matthew J.
IPC: C08G59/24 , C08G59/50 , C08G59/68 , C08L63/00 , C09J163/00 , C08G59/245 , C08G59/5013 , C08G59/686
Abstract: The present invention relates to an epoxy adhesive composition, comprising: a) 10-50 parts by weight of a bisphenol A epoxy resin, a bisphenol F epoxy resin, or a combination of a bisphenol A epoxy resin and a bisphenol F epoxy resin, wherein the epoxy equivalent weight thereof is 150-250 g/Eq; b) 20-50 parts by weight of a dihydroxy phenol glycidyl ether epoxy resin having an epoxy equivalent weight of 100-150 g/Eq; c) 1-5 parts by weight of a silane coupling agent; d) 20-60 parts by weight of a polyetheramine curing agent; e) 10-40 parts by weight of a filler; and f) 0-10 parts by weight of an imidazole accelerator. The epoxy adhesive composition provided by the present invention has a good workability and curing process operability. In addition, an epoxy adhesive prepared from the epoxy adhesive composition has a good peel strength on a plastic surface and good resistance to water vapor permeation.
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公开(公告)号:WO2021124075A1
公开(公告)日:2021-06-24
申请号:PCT/IB2020/061899
申请日:2020-12-14
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: WHITE, Kolby L. , YAO, Li , RULE, Joseph D. , KRYGER, Matthew J. , KROPP, Michael A.
IPC: C08G18/79
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and an inorganic filler. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:WO2020121124A1
公开(公告)日:2020-06-18
申请号:PCT/IB2019/060434
申请日:2019-12-04
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: WHITE, Kolby L. , RULE, Joseph D. , KRYGER, Matthew J. , KROPP, Michael A. , SCHLECHTE, Jay S. , THOMPSON, Zachary J.
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group, wherein; and an epoxy component. The epoxy component is present in an amount of 35% by weight or greater, based on the total weight of the polymerizable composition. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water, or with performance similar to toughened epoxy systems.
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公开(公告)号:WO2020065466A1
公开(公告)日:2020-04-02
申请号:PCT/IB2019/057938
申请日:2019-09-19
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: WHITE, Kolby L. , KRYGER, Matthew J. , RULE, Joseph D. , KROPP, Michael A. , JUNG, Adrian T.
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components, and a thermally activatable amine curative, and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which a polymeric material is included in the first part and the second part includes at least one liquid amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of curing a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems having a two-step cure with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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9.
公开(公告)号:WO2021124033A
公开(公告)日:2021-06-24
申请号:PCT/IB2020/061764
申请日:2020-12-10
Applicant: 3M INNOVATIVE PROPERTIES COMPANY [US]/[US]
Inventor: WHITE, Kolby L. , YAO, Li , RULE, Joseph D. , KRYGER, Matthew J. , KROPP, Michael A.
IPC: C08G18/79 , C08G18/50 , C08G18/38 , C09J175/00 , C08G18/12 , C08G18/28 , C08G18/32 , C08G18/48 , C09J163/00 , H01M50/20 , C08G59/66 , C08G18/282 , C08G18/3206 , C08G18/3876 , C08G18/4825 , C08G18/4854 , C08G18/5072 , C08G18/798 , C08G2190/00 , C08K2003/2227 , H01M10/653 , H01M10/6554 , H01M50/209 , H01M50/264
Abstract: The present disclosure provides a two-part composition polymeric material including a first part and a second part. The first part includes an inorganic filler and a polymeric material including a polymerized reaction product of a polymerizable composition including components. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; and an optional second hydroxyl-containing compound having a single OH group. The second part includes a polythiol having an average sulfhydryl group functionality of 2 or greater. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymerized product of the two-part composition and a battery module. Advantageously, two-part compositions can be used as coatings and adhesive systems including high loadings of inorganic filler, such as thermally conductive filler, with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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公开(公告)号:WO2020121116A1
公开(公告)日:2020-06-18
申请号:PCT/IB2019/060386
申请日:2019-12-03
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: WHITE, Kolby L. , RULE, Joseph D. , KROPP, Michael A. , KRYGER, Matthew J. , DEMOSS, Susan E. , ZOOK, Jonathan D. , THOMPSON, Zachary J.
Abstract: The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group; an epoxy component; and an accelerator. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which a polymeric material is included in the first part and the second part includes at least one thiol-containing compound. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.
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