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公开(公告)号:US11577492B2
公开(公告)日:2023-02-14
申请号:US16335537
申请日:2017-09-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Joseph W. Woody, V , David Scott Thompson , Catherine A. Leatherdale , Ryan M. Braun , Michael A. Johnson , Steven D. Solomonson , John J. Stradinger , Lyudmila A. Pekurovsky , Joseph D. Rule , Peter D. Condo
Abstract: A display film includes a transparent glass layer having a thickness of 250 micrometers or less, or in a range from 25 to 100 micrometers. A transparent energy dissipation layer is fixed to the transparent glass layer. The transparent energy dissipation layer has a glass transition temperature of 27 degrees Celsius or less, a Tan Delta peak value of 0.5 or greater, or from 1 to 2 and a Young's Modulus (E′) greater than 0.9 MPa over a temperature range of −40 degrees Celsius to 70 degrees Celsius. In a preferred embodiment, the transparent energy dissipation layer comprises a cross-linked polyurethane layer or a cross-linked polyurethane acrylate layer.
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公开(公告)号:US11440302B2
公开(公告)日:2022-09-13
申请号:US15986912
申请日:2018-05-23
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Catherine A. Leatherdale , David Scott Thompson , Michael A. Johnson , John J. Stradinger , Evan L Breedlove , Steven D. Solomonson , Joseph D. Rule , Peter D. Condo
IPC: B32B27/28 , B32B27/40 , B32B27/30 , B32B7/06 , B32B27/08 , B32B7/12 , H01L51/52 , B32B27/16 , B32B27/34 , B32B27/32 , B32B27/36 , C08J7/04 , C08J7/043 , C08J7/046 , C08J7/048 , H01L51/00
Abstract: A display film includes a transparent polymeric substrate layer having a 0.2% offset yield stress greater than 110 MPa and a transparent aliphatic cross-linked polyurethane layer having a thickness of 100 micrometers or less disposed on the transparent polymeric substrate layer. The transparent aliphatic cross-linked polyurethane layer has a glass transition temperature in a range from 11 to 27 degrees Celsius and a Tan Delta peak value in a range from 0.5 to 2.5. The display film has a haze value of 2% or less.
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公开(公告)号:US10023725B2
公开(公告)日:2018-07-17
申请号:US14911862
申请日:2014-08-12
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , Jeremy O. Swanson , James E. Thorson , William J. Schultz , Kristin L. Thunhorst
IPC: C08K9/04 , C09D7/40 , C08J5/24 , C09D7/12 , C08K9/06 , C08J5/00 , C08K7/00 , C08K7/18 , C08K7/28 , C08L63/00
Abstract: A nanocomposite is provided including nonspherical silica nanoparticles dispersed in a curable resin or a curing agent, where the nanocomposite contains less than 2% by weight solvent. A composite is also provided including from about 4 to 70 weight percent of nonspherical silica nanoparticles dispersed in a cured resin, and a filler embedded in the cured resin. Further, a method of preparing a nanoparticle-containing curable resin system is provided including mixing from 10 to 70 weight percent of aggregated silica nanoparticles with a curable resin and optionally a dispersant, a catalyst, a diluent, a surface treatment agent, and/or a curing agent, to form a mixture. The mixture contains less than 2% by weight solvent. The method also includes milling the mixture in an immersion mill containing milling media to form a milled resin system including nonspherical silica nanoparticles dispersed in the curable resin.
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公开(公告)号:US20140080934A1
公开(公告)日:2014-03-20
申请号:US14086077
申请日:2013-11-21
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jung-Sheng Wu , Jayshree Seth , Michael D. Determan , Peter D. Condo , Lian S. Tan , Neeraj Sharma
IPC: C08G63/00
CPC classification number: C08G63/00 , C01B33/1585
Abstract: Hybrid aerogels that contain a metal oxide precursor and a branched telechelic copolymer are described. Aerogels and aerogel articles, including hydrophobic aerogels and hydrophobic aerogel articles are also described.
Abstract translation: 描述了含有金属氧化物前体和支链遥爪共聚物的混合气凝胶。 还描述了气凝胶和气凝胶制品,包括疏水性气凝胶和疏水性气凝胶制品。
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公开(公告)号:US20210292598A1
公开(公告)日:2021-09-23
申请号:US17264002
申请日:2019-07-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , D. Scott Thompson
Abstract: Nanocomposite blends include metal oxide nanoparticles and at least two (meth)acrylic acid polymers where the nanoparticles are surface modified with a carboxylic acid silane and where the (meth)acrylic acid polymers are at least partially neutralized. The compositions are transparent, with high transmission and low haze up to very high nanoparticle loading. The compositions also exhibit improved mechanical properties of impact resistance and tensile modulus.
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公开(公告)号:US20200377752A1
公开(公告)日:2020-12-03
申请号:US16891903
申请日:2018-12-06
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , D. Scott Thompson , John J. Stradinger , Catherine A. Leatherdale , Richard J. Pokorny , Steven D. Solomonson
IPC: C09D135/02 , C09D7/40 , C09D7/62 , C09D5/00 , C08J7/04 , C08J7/043 , C08J7/046 , C08J5/18 , G02B1/14
Abstract: A hardcoat composition includes one or more multifunctional (meth)acrylate monomers, and a nanoparticle mixture dispersed within the one or more multifunctional (meth)acrylate monomers. The nanoparticle mixture includes a first population of reactive nanoparticles. The first population of reactive nanoparticles have an average particle diameter in a range from 5 nm to 60 nm, and a second population of non-reactive nanoparticles. The second population of non-reactive nanoparticles have an average particle diameter in a range from 5 nm to 60 mn.
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公开(公告)号:US20180265677A1
公开(公告)日:2018-09-20
申请号:US15982169
申请日:2018-05-17
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , James E. Thorson , Jeremy O. Swanson , Kristin L. Thunhorst
IPC: C08K9/04 , C09D7/40 , C08L63/00 , C08K7/28 , C08K7/18 , C08J5/00 , C08K7/00 , C08K9/06 , C08J5/24 , C08L71/00
Abstract: A nanocomposite is provided including spherical pyrogenic silica nanoparticles dispersed in a curable resin or a curing agent. The nanocomposite contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. A composite is also provided including from about 4 to 70 weight percent of spherical pyrogenic silica nanoparticles dispersed in a cured resin, and a filler embedded in the cured resin. Optionally, the composite further contains a curing agent. Further, a method of preparing a nanoparticle-containing curable resin system is provided including mixing from 10 to 70 weight percent of aggregated spherical pyrogenic silica nanoparticles with a curable resin to form a mixture. The mixture contains less than 2% by weight solvent and less than 0.5% by weight dispersant based on the nanoparticle weight. The method also includes milling the mixture in an immersion mill containing milling media to form a milled resin system including silica nanoparticles dispersed in the curable resin.
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公开(公告)号:US12139593B2
公开(公告)日:2024-11-12
申请号:US17263801
申请日:2019-07-24
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , David S. Thompson
IPC: C08K9/06 , B32B7/023 , B82Y30/00 , B82Y40/00 , C08J7/046 , C08K3/22 , C08K3/36 , C08K5/541 , C08K5/544 , C08L23/08 , C08L33/06 , G02B1/04 , G02B1/116 , G02B1/14
Abstract: Nanocomposites include metal oxide nanoparticles and (meth)acrylic acid polymers where the nanoparticles are surface modified with a carboxylic acid silane and where the (meth)acrylic acid polymer is at least partially neutralized. The compositions are transparent, with high transmission and low haze up to very high nanoparticle loading. The compositions also exhibit improved mechanical properties of impact resistance and tensile modulus.
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公开(公告)号:US11987724B2
公开(公告)日:2024-05-21
申请号:US17264002
申请日:2019-07-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , D. Scott Thompson
IPC: C09D183/16 , B82Y30/00 , B82Y40/00 , C07F7/08 , C09D1/04 , C09D7/40 , G02B1/04 , G02B1/14 , G02B5/00
CPC classification number: C09D183/16 , C07F7/081 , C09D1/04 , C09D7/67 , G02B1/04 , G02B1/14 , G02B5/00 , B82Y30/00 , B82Y40/00
Abstract: Nanocomposite blends include metal oxide nanoparticles and at least two (meth)acrylic acid polymers where the nanoparticles are surface modified with a carboxylic acid silane and where the (meth)acrylic acid polymers are at least partially neutralized. The compositions are transparent, with high transmission and low haze up to very high nanoparticle loading. The compositions also exhibit improved mechanical properties of impact resistance and tensile modulus.
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公开(公告)号:US11674003B2
公开(公告)日:2023-06-13
申请号:US17795712
申请日:2021-01-28
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Peter D. Condo , David Scott Thompson
CPC classification number: C08J3/215 , C08J5/18 , C08K3/36 , C08K9/06 , C08L23/0876 , C08J2323/08 , C08K2201/011
Abstract: A nanocomposite includes at least one polymer and metal oxide nanoparticles dispersed in the at least one polymer. Each polymer can have a number average molecular weight of at least 10000 grams/mole. The at least one polymer includes a first polymer including (meth)acrylic acid monomer units. The metal oxide nanoparticles are surface modified with a carboxylic acid silane surface modifying agent. An aqueous dispersion that can be used to make the nanocomposite and a method of making the nanocomposite is described.
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