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    HYDROFLUOROOLEFINS AND METHODS OF USING SAME
    1.
    发明申请
    HYDROFLUOROOLEFINS AND METHODS OF USING SAME 审中-公开

    公开(公告)号：WO2020170080A1

    公开(公告)日：2020-08-27

    申请号：PCT/IB2020/051153

    申请日：2020-02-12

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： TOSO, Nicholas A. ,  BULINSKI, Michael J.

    IPC: C07C211/24 ,  C07D207/10 ,  C07D265/30

    Abstract: A hydrofluoroolefin compound is represented by the following general formula (I): where R F 1 is a hydrogen atom or CH 3 , and (iii) R F 1 is a linear or branched perfluorinated alkyl group having 1 to 10 carbon atoms and optionally including one or more catenated heteroatoms; and R F 2 is a fluorine atom or a linear or branched perfluorinated alkyl group having 1 to 8 carbon atoms and optionally including one or more catenated heteroatoms; with the proviso that when RF2 is a fluorine atom, then RF1 includes at least 2 carbon atoms; or (iv) R F 1 and R F 2 are bonded together to form a ring structure having 4 to 8 carbon atoms and optionally including one or more catenated heteroatoms.

    NITROGEN AND/OR OXYGEN-CONTAINING HYDROFLUOROOLEFINS AND METHODS OF MAKING AND USING THE SAME
    3.
    发明申请
    NITROGEN AND/OR OXYGEN-CONTAINING HYDROFLUOROOLEFINS AND METHODS OF MAKING AND USING THE SAME 审中-公开
    含氮和/或含氧的氢氟烯烃及其制备和使用方法

    公开(公告)号：WO2018057134A1

    公开(公告)日：2018-03-29

    申请号：PCT/US2017/045834

    申请日：2017-08-08

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： SMITH, Sean M. ,  BULINSKI, Michael J. ,  COSTELLO, Michael G. ,  LAMANNA, William M. ,  TOSO, Nicholas A.

    IPC: C07D207/10 ,  C07D265/30 ,  C07C43/17 ,  C07C211/21 ,  C07C2/56 ,  C11D7/50 ,  C11D3/24 ,  D06L1/02 ,  C09K5/00 ,  C23G5/028 ,  B23K1/015

    Abstract: The present invention relates to an unsaturated fluorinated ether or amine compound of formula (I) with low global warming potential and method of making the compound (I), where R H 1 is and R H 2 are independently selected from H or CH 3 , wherein when R H 1 is CH 3 then R H 2 is H and when R H 2 is CH 3 , then R H 1 is H; X is O or N and when X is O, then n is 1 and R f is a linear or branched perfluorinated alkyl group comprising 1-10 carbon atoms and optionally comprising at least one catenated O or N atom; X is N, then n is 2 and (i) each R f is independently selected from a linear or branched perfluorinated alkyl group comprising 1 -8 carbon atoms and optionally comprising at least one catenated O or N atom, or (ii) the two R f 's are bonded together to form a ring structure optionally comprising at least one catenated O or N atom, wherein the ring of the ring structure consists of 5-7 atoms, no more than 10 carbon atoms, and is perfluorinated. The applications of the compound include solvent cleaning, electrolyte solvents or additives, heat transfer, and vapour phase soldering.

    Abstract translation: 本发明涉及具有低全球变暖潜能值的式（I）的不饱和氟化醚或胺化合物和制备化合物（I）的方法，其中R H， 1和R 2独立地选自H或CH 3，其中当R H 1是CH 3，则R 2 H 2是H，并且当R H 2是H时， 2是CH 3，则R H = 1是H; X是O或N，并且当X是O时，则n是1且R f是包含1-10个碳原子的直链或支链全氟化烷基，并且任选地包含至少一个连接的O或N原子 ; X是N，则n是2并且（i）每个R f独立地选自包含1-8个碳原子的直链或支链全氟化烷基并且任选地包含至少一个连接的O或N原子 ，或（ii）两个R f'结合在一起形成任选地包含至少一个连接的O或N原子的环结构，其中环结构的环由5-7个原子 ，不超过10个碳原子，并且是全氟化的。 该化合物的应用包括溶剂清洗，电解质溶剂或添加剂，传热和气相焊接。

    AMINE-CONTAINING CYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME
    4.
    发明申请
    AMINE-CONTAINING CYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME 审中-公开
    含胺的环状氢氟烯烃及其使用方法

    公开(公告)号：WO2017155735A1

    公开(公告)日：2017-09-14

    申请号：PCT/US2017/019842

    申请日：2017-02-28

    Applicant: 3M INNOVATIVE PROPERTIES COMPANY

    Inventor： SMITH, Sean M. ,  BULINSKI, Michael J. ,  COSTELLO, Michael G. ,  LAMANNA, William M. ,  TOSO, Nicholas A.

    IPC: C07D413/06 ,  C07D405/06 ,  C07D413/14

    Abstract: Described herein is a cyclic fluorinated compound of formula (I) where: L is O, CH 2 , or a covalent bond; X is selected from F or CF 3 , and Y is selected from H, F, or CF 3 , wherein when X is CF 3 then Y is F and when Y is CF 3 then X is F„ each R f 1 is independently selected from a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; or the two R f 1 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; the -CFZ-CHAQ group is bonded to a ring carbon that is alpha to at least one O atom of the ring; A is selected from F, or CF 3 ; Z is selected from H, F, or CF 3 ; and Q is selected from (i) a F atom, (ii) a Cl atom, (iii) a linear, cyclic, or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, or (iv) a G(R f 2 ) e group, where G is an O atom or a N atom wherein: when Q is a Cl atom, then Z and A are F atoms; when G is O then e is 1, Z is H, F, or CF 3 ; A is F; and R f 2 is a linear or branched perfluorinated alkyl group comprising 1-10 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; when G is N then e is 2, and each R f 2 group is independently a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof or the two R f 2 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, with the proviso that when A is CF 3 then Z is F, and when Z is CF 3 then A is F.

    Abstract translation: 本文描述了式（I）的环状氟化化合物，其中：L是O，CH 2 2或共价键; X选自F或CF 3，并且Y选自H，F或CF 3，其中当X是CF 3时，则 Y是F，并且当Y是CF 3时，则X是F“，每个R f 1独立地选自直链或支链的全氟化烷基 其包含1-8个碳原子且任选地包含至少一个选自O，N或其组合的连接原子; 或两个R f1基团结合在一起形成包含4-8个碳原子的氟化的环结构，并且任选地包含至少一个选自O，N， 或其组合; -CFZ-CHAQ基团键合到环上至少一个O原子的α位的环碳; A选自F或CF 3; Z选自H，F或CF 3; （i）F原子，（ii）Cl原子，（iii）包含1-8个碳原子的直链，环状或支链的全氟化烷基，并且任选地包含至少一个选自O， N或它们的组合，或（iv）G（R 2）2基团，其中G是O原子或N 原子，其中：当Q是Cl原子时，则Z和A是F原子; 当G为O时，e为1，Z为H，F或CF 3; A是F; R 2和R 2是直链或支链全氟烷基，其包含1-10个碳原子并任选地包含至少一个选自O，N或其组合的连接原子; 当G为N时，e为2，并且每个R f 2基团独立地为包含1-8个碳原子的直链或支链全氟化烷基，并且任选地包含至少一个 选自O，N或它们的组合的连接原子或两个R f 2基团键合在一起形成包含4-8个碳原子的氟化的环结构，并且任选地包含 至少一个选自O，N或其组合的连接原子，条件是当A是CF 3时，则Z是F，并且当Z是CF 3时，则 A是F.

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