公开(公告)号：WO2007106724A2

公开(公告)日：2007-09-20

申请号：PCT/US2007/063636

申请日：2007-03-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： SHERMAN, Audrey A. ,  YARUSSO, David J. ,  SHER, Frank T.

CPC classification number: C08F265/04 ,  B33Y80/00 ,  C08F291/00 ,  C08L51/06 ,  C08L2666/02 ,  C08L2666/24 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J133/02 ,  C09J133/06 ,  C09J151/003 ,  C09J2433/00 ,  C09J2451/00 ,  Y10T428/31663 ,  Y10T428/31855 ,  Y10T428/31928

Abstract: An adhesive composition includes a blend of a pressure sensitive adhesive and an additive. The pressure sensitive adhesive includes a (meth)acrylate polymer. The additive includes a copolymer with a vinyl polymeric backbone that includes at least one free radically polymerizable vinyl monomer A and at least one reinforcing comonomer B, wherein B is present at 0 to about 20% by weight of the copolymer, and a pendant polysiloxane monomer grafted to the backbone. The adhesive composition may optionally be crosslinked. The adhesive composition may be applied to a film to form a graphic article. These graphic articles may be applied to a substrate without liquid application aids.

Abstract translation: 粘合剂组合物包括压敏粘合剂和添加剂的共混物。 压敏粘合剂包括（甲基）丙烯酸酯聚合物。 添加剂包括具有乙烯基聚合物主链的共聚物，其包含至少一种可自由基聚合的乙烯基单体A和至少一种增强共聚单体B，其中B以共聚物的0至约20重量％存在，以及侧链聚硅氧烷单体 嫁接到骨干。 粘合剂组合物可任选地交联。 粘合剂组合物可以施加到膜上以形成图形制品。 这些图形制品可以应用于没有液体施用辅助剂的基材。

公开(公告)号：WO2018080623A1

公开(公告)日：2018-05-03

申请号：PCT/US2017/047893

申请日：2017-08-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： BEVERIDGE, Nicole Morozowich ,  BEHLING, Ross E. ,  KURIAN, Anish ,  ELLIS, Mark F. ,  BENSON, Karl E. ,  CRATON, Michele A. ,  MUNSON, Daniel C. ,  YARUSSO, David J.

IPC: C09J133/14 ,  C09J133/08 ,  C08F220/18

Abstract: Crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions, which include two (meth)acrylate polymers, are used to form the crosslinked compositions upon exposure to ultraviolet radiation. The crosslinkable and crosslinked compositions are free or substantially free of tackifiers. The crosslinked compositions can function as pressure-sensitive adhesives. The crosslinkable compositions are well suited for use with hot melt processing methods.

Abstract translation: 提供了可交联组合物，交联组合物，含有这些组合物的制品以及制造这些制品的方法。 包含两种（甲基）丙烯酸酯聚合物的可交联组合物在暴露于紫外线辐射时用于形成交联组合物。 可交联和交联的组合物不含或基本上不含增粘剂。 交联的组合物可以用作压敏粘合剂。 可交联组合物非常适合用于热熔加工方法。

公开(公告)号：WO2018031604A1

公开(公告)日：2018-02-15

申请号：PCT/US2017/046002

申请日：2017-08-09

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： D'HAESE, Francois C. ,  FUKUSHI, Tatsuo ,  GIBNEY, Katherine A. ,  HINTZER, Klaus ,  OPSTAL, Tom ,  SETH, Jayshree ,  YARUSSO, David J.

IPC: C09J201/04

Abstract: Described herein is a pressure sensitive adhesive comprising a high molecular weight fluorinated polymer having a Tg less than about 0°C and a number average molecular weight greater than about 20 kilograms/mole; and a low molecular weight fluorinated polymer derived from an ethylenically unsaturated fluorinated monomer, wherein the low molecular weight fluorinated polymer has a Tg greater than about -15°C and a number average molecular weight less than about 18 kilograms/mole. Also described herein are articles comprising the pressure sensitive adhesive composition.

Abstract translation: 本文描述了一种压敏粘合剂，其包含具有小于约0℃的Tg和大于约20千克/摩尔的数均分子量的高分子量氟化聚合物; 和衍生自烯属不饱和氟化单体的低分子量氟化聚合物，其中低分子量氟化聚合物具有大于约-15℃的Tg和小于约18千克/摩尔的数均分子量。 本文还描述了包含压敏粘合剂组合物的制品。

公开(公告)号：WO2017116801A1

公开(公告)日：2017-07-06

申请号：PCT/US2016/067540

申请日：2016-12-19

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YARUSSO, David J. ,  TRAN, Thu-Van T. ,  KIM, Soyoung ,  BEHLING, Ross E. ,  BENSON, Karl E.

IPC: C09J7/02 ,  C09J133/08 ,  C09J133/10 ,  C09J133/12 ,  C09J133/26

CPC classification number: C09J133/10 ,  B32B27/306 ,  B32B2307/306 ,  C08F220/18 ,  C08F265/06 ,  C08F290/046 ,  C08L23/02 ,  C08L33/08 ,  C08L33/10 ,  C08L33/26 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/05 ,  C09J133/08 ,  C09J133/26 ,  C09J155/005 ,  C08F2220/1858 ,  C08F220/56

Abstract: An adhesive composition includes a first acrylic polymer preparable from first components and a second acrylic polymer. The first components comprising i) a branched first alkyl (meth)acrylate having from 4 to 22 carbon atoms, and ii) at least one of acrylic acid and methacrylic acid. The second acrylic polymer is preparable from second components comprising iii) at least one second alkyl (meth)acrylate having from 4 to 22 carbon atoms, iv) a (meth)acrylamide represented by formula (I) wherein R 1 is H or methyl, and R 2 and R 3 each independently represents H or an alkyl group having from 1 to 8 carbon atoms, or taken together R 2 and R 3 may form a divalent alkylene group having from 4 to 6 carbon atoms, and v) at least one high T g macromer having a terminal free-radically polymerizable unsaturated group, the high T g macromer having a T g of at least 45°C. Based on the combined total weight of the at least one first acrylic polymer and the at least one second acrylic polymer, the at least one second acrylic polymer is present at a level of from 5 to 40 percent by weight. Methods of making the adhesive composition are also disclosed.

Abstract translation: 粘合剂组合物包含可由第一组分制备的第一丙烯酸类聚合物和第二丙烯酸类聚合物。 第一组分包含i）具有4-22个碳原子的支化的第一（甲基）丙烯酸烷基酯，和ii）丙烯酸和甲基丙烯酸中的至少一种。 第二丙烯酸聚合物可由第二组分制备，所述第二组分包含iii）至少一种具有4-22个碳原子的第二（甲基）丙烯酸烷基酯，iv）式（I）代表的（甲基）丙烯酰胺，其中R 1， R 2是H或甲基，R 2和R 3各自独立地代表H或具有1至8个碳原子的烷基，或一起表示R 1， 2和R 3可以形成具有4至6个碳原子的二价亚烷基，和v）至少一种具有游离末端的高T max大单体 - 可自由基聚合的不饱和基团，所述高Tg大单体的T g至少为45℃。 基于所述至少一种第一丙烯酸类聚合物和所述至少一种第二丙烯酸类聚合物的总重量，所述至少一种第二丙烯酸类聚合物以5至40重量％的含量存在。 还公开了制造粘合剂组合物的方法。

公开(公告)号：WO2016109262A1

公开(公告)日：2016-07-07

申请号：PCT/US2015/066815

申请日：2015-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： PYUN, Eumi ,  GRIESGRABER, George W. ,  TRAN, Thu-Van T. ,  CLEM, Tabitha A. ,  LIN, Haohao ,  MOSER, William H. ,  PLEPYS, Anthony R. ,  ROSS, Richard B. ,  YARUSSO, David J. ,  LIPSCOMB, Corinne E.

IPC: C09J7/02 ,  C09J9/00 ,  C09J133/14 ,  C08F220/18

CPC classification number: C09J9/00 ,  C08F220/18 ,  C08F230/02 ,  C08F2220/1858 ,  C09D143/02 ,  C09J7/0217 ,  C09J7/385 ,  C09J133/14 ,  C09J2201/606 ,  C09J2203/326 ,  C09J2400/163 ,  C09J2433/00 ,  C09K21/14 ,  C08F2220/1875 ,  C08F220/06 ,  C08F2222/1013

Abstract: A halogen-free flame retardant adhesive comprises an acrylic copolymer preparable by polymerization of monomers comprising a first monomer which comprises a low glass transition temperature (Tg) monomer, a second monomer which comprises a high Tg monomer, wherein at least one of the first and second monomers comprises a (meth)acrylate, and a phosphate containing monomer.

Abstract translation: 无卤阻燃粘合剂包括丙烯酸共聚物，所述丙烯酸共聚物可通过包含第一单体的单体的聚合制备，所述第一单体包含低玻璃化转变温度（Tg）单体，包含高Tg单体的第二单体，其中所述第一和/ 第二单体包括（甲基）丙烯酸酯和含磷酸酯的单体。

公开(公告)号：WO2014186169A1

公开(公告)日：2014-11-20

申请号：PCT/US2014/036892

申请日：2014-05-06

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： WANG, Shujun J. ,  CHEN, Zhong ,  JACOBSEN, John R. ,  WILLETT, Peggy S. ,  YARUSSO, David J. ,  KIM, Soyoung

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08F265/06 ,  C08L33/08 ,  C08L33/10 ,  C09J7/385 ,  C09J133/10 ,  C09J151/003 ,  C09J2201/622 ,  C09J2400/243 ,  C09J2433/00 ,  C08F2220/1875 ,  C08F220/06 ,  C08F2220/1858

Abstract: Disclosed is a crosslinked adhesive composition comprising a low T g (meth)acrylate copolymer component, a high T g (meth)acrylate copolymer component, and a hydrogenated hydrocarbon tackifier. This disclosure provides a pressure-sensitive adhesive and pressure-sensitive adhesive articles that are particularly useful in the bonding of low surface energy (LSE) substrates.

Abstract translation: 公开了包含低Tg（甲基）丙烯酸酯共聚物组分，高Tg（甲基）丙烯酸酯共聚物组分和氢化烃增粘剂的交联粘合剂组合物。 本公开提供了在低表面能（LSE）基材的粘合中特别有用的压敏粘合剂和压敏粘合剂制品。

公开(公告)号：WO2011090603A1

公开(公告)日：2011-07-28

申请号：PCT/US2010/060377

申请日：2010-12-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  AUSEN, Ronald W. ,  KOPECKY, William J. ,  FLEMING, Danny L. ,  YARUSSO, David J. ,  BATCH, Gibson L. ,  EMSLANDER, Jeffrey O. ,  JONZA, James M.

Inventor： AUSEN, Ronald W. ,  KOPECKY, William J. ,  FLEMING, Danny L. ,  YARUSSO, David J. ,  BATCH, Gibson L. ,  EMSLANDER, Jeffrey O. ,  JONZA, James M.

IPC: B29C47/06 ,  B29C47/14 ,  B29C47/58 ,  C09J7/02 ,  B29C47/88 ,  B29C47/56

CPC classification number: B29C47/0021 ,  B29C47/0057 ,  B29C47/065 ,  B29C47/067 ,  B29C47/068 ,  B29C47/14 ,  B29C47/145 ,  B29C47/56 ,  B29C47/8845 ,  B29C47/8895 ,  B29K2909/02 ,  B29L2007/008 ,  C09J7/38 ,  C09J7/40 ,  C09J2433/00 ,  C09J2453/00 ,  Y10T428/1476 ,  Y10T428/28

Abstract: An extrusion die (20) and method for co-extruding a first molten polymeric material and a second molten polymeric material. The die includes a first die portion (20), a second die portion and a shim separating the first die portion and the second die portion. The shim has a first side and a second side, the first side of the shim forming a boundary of the first die portion and defining a first die cavity (38), the second side of the shim forming a boundary of the second die portion and defining a second die cavity (40). A dispensing edge (36) is provided having a plurality of first and second extrusion openings, a plurality of first feed channels connecting the first die cavity to the first extrusion openings along the dispensing edge, and a plurality of second feed channels connecting the second die cavity to the second extrusion openings along the dispensing edge. The first and second extrusion openings arranged along the dispensing edge to provide an interfacial zone having portions of the first extrusion openings disposed between portions of the second extrusion openings. The die is used in an extrusion system and a method for making a multilayered article.

Abstract translation: 挤出模具（20）和用于共挤出第一熔融聚合物材料和第二熔融聚合物材料的方法。 模具包括第一模具部分（20），第二模具部分和分隔第一模具部分和第二模具部分的垫片。 垫片具有第一侧和第二侧，垫片的第一侧形成第一模具部分的边界并且限定第一模腔（38），垫片的第二侧形成第二模具部分的边界，并且 限定第二模腔（40）。 提供分配边缘（36），其具有多个第一和第二挤压开口，多个第一进料通道，其沿着分配边缘将第一模腔连接到第一挤出开口;以及多个第二进料通道，其连接第二模具 空腔沿分配边缘移动到第二挤压开口。 所述第一和第二挤压开口沿分配边缘布置，以提供界面区域，其中第一挤出开口的部分设置在第二挤压开口的部分之间。 模具用于挤出系统和制造多层制品的方法。

公开(公告)号：WO2019123180A1

公开(公告)日：2019-06-27

申请号：PCT/IB2018/060125

申请日：2018-12-14

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YARUSSO, David J. ,  BEHLING, Ross E. ,  SIMONE, Peter M. ,  LI, Chaodi ,  CHEN, Zhong ,  WANG, Sharon ,  MA, Jingjing ,  SHOCKEY, Eric D.

IPC: C09J7/38

CPC classification number: C09J7/385 ,  C09J2201/36 ,  C09J2201/606 ,  C09J2433/00

Abstract: An adhesive article including: a flexible backing; a first cushion layer permanently bonded to a first surface of the flexible backing, wherein the first cushion layer: has an average thickness of at least 10 micrometers; and includes an acrylate pressure-sensitive adhesive having a Fox Tg of up to -30°C, wherein the acrylate pressure-sensitive adhesive includes a (meth)acrylate copolymer; and a first continuous shell layer adjacent the first cushion layer, wherein: the first continuous shell layer has an average thickness of up to 25 micrometers; the ratio of the first cushion layer average thickness to the first shell layer average thickness is at least 2:1; the first continuous shell layer includes an adhesive having a Fox Tg of -20°C to +50°C; and the first continuous shell layer adhesive includes a copolymer having a weight average molecular weight of at least 100,000 Daltons.

公开(公告)号：WO2018031554A1

公开(公告)日：2018-02-15

申请号：PCT/US2017/045914

申请日：2017-08-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： D'HAESE, Francois C. ,  FUKUSHI, Tatsuo ,  GIBNEY, Katherine A. ,  HINTZER, Klaus ,  OPSTAL, Tom ,  SETH, Jayshree ,  YARUSSO, David J. ,  YANG, Yu

IPC: C09J133/06 ,  C09J11/08 ,  C08L33/16 ,  C08L33/08 ,  C08L25/18 ,  B32B27/04

Abstract: Described herein is a pressure sensitive adhesive is comprising: (a) a high molecular weight (meth)acrylate polymer wherein the high molecular weight (meth)acrylate polymer is derived from (i) a C4 to C24 (meth)acrylate ester monomer; and (ii) 0 to less than 10 wt % of a polar comonomer based on the weight of the high molecular weight (meth)acrylate polymer; and (b) 10 to 100 parts of a low molecular weight fluorinated polymer per 100 parts of the high molecular weight (meth)acrylate polymer, wherein the low molecular weight fluorinated polymer has a glass transition temperature (Tg) of less than 40°C. The low molecular weight fluorinated polymer is preferably derived from fluorinated (meth)acrylate, fluorinated (meth)acrylate comprising a sulfonylamide group, fluorinated vinyl monomers, fluorinated vinyl ethers, or fluorinated styrene.

Abstract translation: 本文描述的压敏粘合剂包含：（a）高分子量（甲基）丙烯酸酯聚合物，其中高分子量（甲基）丙烯酸酯聚合物衍生自（i）C 4至C 24 （甲基）丙烯酸酯单体; 和（ii）基于高分子量（甲基）丙烯酸酯聚合物的重量，0至小于10重量％的极性共聚单体; 和（b）每100份高分子量（甲基）丙烯酸酯聚合物10至100份低分子量氟化聚合物，其中低分子量氟化聚合物的玻璃化转变温度（Tg）低于40℃ 。 低分子量氟化聚合物优选衍生自氟化（甲基）丙烯酸酯，包含磺酰胺基团的氟化（甲基）丙烯酸酯，氟化乙烯基单体，氟化乙烯基醚或氟化苯乙烯。

公开(公告)号：WO2018031512A1

公开(公告)日：2018-02-15

申请号：PCT/US2017/045832

申请日：2017-08-08

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： SETH, Jayshree ,  D'HAESE, Francois C. ,  FUKUSHI, Tatsuo ,  OPSTAL, Tom ,  YARUSSO, David J.

IPC: C09J11/08 ,  C09J133/16 ,  C08L33/16

Abstract: Described herein is a low molecular weight fluorinated (meth)acrylate polymer comprising a plurality of pendent sulfonylamide groups, which is used as a tackifier in a pressure sensitive adhesive composition. Also described herein is a pressure sensitive adhesive composition comprising the low molecular weight fluorinated (meth)acrylate polymer, and articles comprising the pressure sensitive adhesive composition. The pressure sensitive adhesive preferably also comprises a high molecular weight polymer, which is derived from a (meth)acrylate monomer or is a fluoropolymer.

Abstract translation: 本文描述了包含多个侧链磺酰胺基团的低分子量氟化（甲基）丙烯酸酯聚合物，其用作压敏粘合剂组合物中的增粘剂。 本文还描述了包含低分子量氟化（甲基）丙烯酸酯聚合物的压敏粘合剂组合物，以及包含压敏粘合剂组合物的制品。 压敏粘合剂优选还包含衍生自（甲基）丙烯酸酯单体或为含氟聚合物的高分子量聚合物。