公开(公告)号：WO2017030773A1

公开(公告)日：2017-02-23

申请号：PCT/US2016/044973

申请日：2016-08-01

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YIN, Long ,  JIN, Zhou

IPC: C09D183/08

CPC classification number: C09D183/08 ,  C08G77/14 ,  C08G77/26 ,  C08K3/36 ,  C08K9/06 ,  C08K9/08 ,  C08K2201/005 ,  C09D5/00 ,  C09D7/62 ,  C09D183/06 ,  C08L83/00

Abstract: The present invention provides a slip resistant liquid, comprising a reaction product of the following reaction components, based on the total weight of the slip resistant liquid as 100 wt.%: 1) a first reaction solution comprising a reaction product of the following reaction components: 3-75 wt.% of a first silane represented by a general formula of R 1 a Si (OR) 4-a-b R 2 b , wherein the value of a is 1 to 3; when the value of a is 1, the value of b is 0 to 2; when the value of a is 2, the value of b is 0 to 1; when the value of a is 3, the value of b is 0; R represents an alkyl group having 1 to 4 carbon atoms, R 1 represents an organic group with at least one epoxy functional group, and R 2 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; 20-96 wt.% of water; and an acid; 2) 0.5-4 wt.% of a second silane represented by a general formula of R 3 c Si (OR) 4-c-d R 4 d , wherein the value of c is 1 to 3; when the value of c is 1, the value of d is 0 to 2; when the value of c is 2, the value of d is 0 to 1; when the value of c is 3, the value of d is 0; R represents an alkyl group having 1 to 4 carbon atoms, R 3 represents an organic group with at least one primary amino functional group, secondary amino functional group or tertiary amino functional group, and R 4 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; and 3) 0.5-11 wt.% of surface epoxy-modified silica particles.

Abstract translation: 本发明提供一种防滑液体，其包含以下反应组分的反应产物：基于防滑液体的总重量为100重量％：1）第一反应溶液，其包含以下反应组分的反应产物 ：3-75重量％的由通式R1 aSi（OR）4-a-bR2 b表示的第一硅烷，其中a的值为1至3; 当a的值为1时，b的值为0〜2; 当a的值为2时，b的值为0〜1; 当a的值为3时，b的值为0; R表示碳原子数1〜4的烷基，R 1表示具有至少一个环氧官能团的有机基团，R 2表示氢原子或碳原子数1〜20的烷基。 20-96重量％的水; 和酸; 2）0.5-4重量％的由通式R3cSi（OR）4-c-dR4d表示的第二硅烷，其中c的值为1至3; 当c值为1时，d值为0〜2; 当c值为2时，d值为0〜1; 当c的值为3时，d的值为0; R表示碳原子数1〜4的烷基，R 3表示具有至少一个伯氨基官能团，仲氨基官能团或叔氨基官能团的有机基团，R 4表示氢原子或具有1〜20个碳原子的烷基 碳原子 和3）0.5-11重量％的表面环氧改性二氧化硅颗粒。

公开(公告)号：WO2015026652A1

公开(公告)日：2015-02-26

申请号：PCT/US2014/051255

申请日：2014-08-15

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YIN, Long ,  CHEN, Xue-hua ,  YU, Zhigang ,  SUN, Duyinzi ,  LIU, Wenbin ,  JING, Naiyong

IPC: B32B15/04 ,  B05D7/14 ,  C09D5/08

CPC classification number: C09D5/086 ,  B05D3/007 ,  C09D5/08 ,  C09D7/61

Abstract: The present invention provides an anti-corrosion solution comprising reaction products of the following reaction components: 1-30 wt% of a tetraalkyl orthosilicate, with the total weight of said anti-corrosion solution being 100 wt%; 0.2-6.0 wt% of a metal salt, with the total weight of said anti-corrosion solution being 100 wt%, said metal salt comprising one or more selected from the group consisting of: an aluminum salt, a strontium salt, a chromium salt, a zirconium salt and a cerium salt; an acid; 3-90 wt% of water, with the total weight of said anti-corrosion solution being 100 wt%; 4-95 wt% of an alcohol, with the total weight of said anti-corrosion solution being 100 wt%; said anti-corrosion solution having a pH value less than or equal to 4. The anti-corrosion solution provided by the present invention can form a dense transparent anti-corrosion coating layer on a substrate surface, the anti-corrosion coating layer having a good corrosion resistance performance.

Abstract translation: 本发明提供了包含以下反应组分的反应产物的防腐蚀溶液：1-30重量％的原硅酸四烷基酯，所述防腐蚀溶液的总重量为100重量％; 0.2-6.0重量％的金属盐，所述防腐蚀溶液的总重量为100重量％，所述金属盐包含选自以下的一种或多种：铝盐，锶盐，铬盐 ，锆盐和铈盐; 酸; 3-90重量％的水，所述防腐蚀溶液的总重量为100重量％; 4-95重量％的醇，所述防腐蚀溶液的总重量为100重量％; 所述防腐蚀溶液的pH值小于或等于4.本发明提供的防腐蚀溶液可在基材表面上形成致密的透明防腐蚀涂层，防腐蚀涂层具有良好的 耐腐蚀性能。

公开(公告)号：WO2017015885A1

公开(公告)日：2017-02-02

申请号：PCT/CN2015/085383

申请日：2015-07-29

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  YIN, Long

Inventor： YIN, Long ,  YU, Zhigang ,  JING, Naiyong

IPC: C09D5/16 ,  C03C17/00 ,  C03C17/22

CPC classification number: C03C17/008 ,  C03C17/007 ,  C03C2217/445 ,  C03C2217/478 ,  C03C2217/75 ,  C09D1/00 ,  C09D5/16

Abstract: Provided is a coated article comprising a substrate and a dried coating which comprises a first set of spherical silica nanoparticles having an average diameter of less than 20 nm and a second set of spherical silica nanoparticles having an average diameter of 20 nm to 120 nm. The alkoxy silane compound comprises an epoxy functional group or a carboxylic acid functional group. Also provided is a coating composition comprising an acidic aqueous dispersion which comprises the described first and second set of spherical silica nanoparticles and silane compound.

Abstract translation: 本发明提供一种包含基材和干燥涂层的涂层制品，其包括平均直径小于20nm的第一组球形二氧化硅纳米颗粒和平均直径为20nm至120nm的第二组球形二氧化硅纳米颗粒。 烷氧基硅烷化合物包含环氧官能团或羧酸官能团。 还提供了包含酸性水分散体的涂料组合物，其包含所述第一和第二组球形二氧化硅纳米颗粒和硅烷化合物。

公开(公告)号：WO2018125842A1

公开(公告)日：2018-07-05

申请号：PCT/US2017/068332

申请日：2017-12-22

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YIN, Long ,  SONG, Tao ,  LI, Yu

IPC: C09D5/14 ,  C09D183/02 ,  C09D183/04 ,  B05D7/24 ,  C11D11/00 ,  C11D3/04 ,  C11D3/20 ,  C11D3/48 ,  C11D3/24 ,  C11D3/50

CPC classification number: C09D5/14 ,  C08G77/02 ,  C08G77/24 ,  C09D1/00 ,  C09D183/02 ,  C09D183/04 ,  C11D3/04 ,  C11D3/1246 ,  C11D3/20 ,  C11D3/24 ,  C11D3/245 ,  C11D3/48 ,  C11D3/50 ,  C11D11/00 ,  C11D11/0023

Abstract: Described herein is a preparation method of a durable easy-cleaning and antimicrobial coating composition, the method comprising steps of: 1) adding an acid into an alcohol-water solution comprising at least one orthosilicate and fluorinated polyether silane compound to perform hydrolysis and co-condensation at 20 to 80°, so as to form a reaction mixture i; 2) placing the reaction mixture i at room temperature to perform aging for 12 to 72 h, so as to form a reaction mixture ii; 3) adding an acid into an aqueous solution comprising at least one high-valence metal salt to adjust pH of the solution to 1-4, and then mixing the solution with the reaction mixture ii, so as to form a reaction mixture iii, wherein the high-valence metal salt is one or more selected from the group consisting of aluminum salts (in an oxidation state of 3+), chromium salts (in an oxidation state of 3+), cerium salts (in an oxidation state of 3+ or 4+), zirconium salts (in an oxidation state of 4+), and vanadium salts (in an oxidation state of 5+); and 4) adding at least one inorganic antimicrobial agent into the reaction mixture iii to form a coating composition, wherein the inorganic antimicrobial agent is a silver salt (in an oxidation state of 1+), a copper salt (in an oxidation state of 2+), or a zinc salt (in an oxidation state of 2+).

公开(公告)号：WO2015142689A1

公开(公告)日：2015-09-24

申请号：PCT/US2015/020651

申请日：2015-03-16

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YIN, Long ,  YU, Xin ,  YU, Zhigang ,  YANG, Lin ,  LI, Wenyan ,  JING, Naiyong

IPC: B05D5/02 ,  C04B41/48 ,  C04B41/49 ,  C04B111/00

CPC classification number: C04B41/009 ,  C04B41/4922 ,  C04B41/84 ,  C04B2111/00112 ,  C04B2111/00362 ,  C04B33/00 ,  C04B14/048 ,  C04B14/285 ,  C04B41/4944 ,  C04B41/5016

Abstract: The present invention provides a slip resistant article comprising a substrate and a slip resistant coating applied on the surface of the substrate. The substrate is a ceramic tile substrate. The slip resistant coating is further prepared from a slip resistant solution, and the slip resistant solution comprises the reaction product of the following reaction components: 1-83.5 wt.% of a first silane, based on the total weight of the slip resistant solution as 100 wt.%, the general formula of the first silane being R 1 a Si (OR) 4-a-b R 2 b , wherein the value of a is 0 to 3; when the value of a is 0, the value of b is 0; when the value of a is 1, the value of b is 0 to 2; when the value of a is 2, the value of b is 0 to 1; when a value of a is 3, the value of b is 0; R represents alkyl group having 1 to 4 carbon atoms; R 1 represents hydrocarbyl group with epoxy functional group; and R 2 represents alkyl group having 1 to 2 carbon atoms; and 16.5-99 wt.% of a first solvent, based on the total weight of the slip resistant solution as 100 wt.%, the first solvent being water and/or alcohol.

Abstract translation: 本发明提供一种防滑制品，其包括施加在基材表面上的基材和防滑涂层。 衬底是瓷砖衬底。 防滑涂层由防滑溶液进一步制备，防滑溶液包含以下反应组分的反应产物：1-83.5重量％的第一硅烷，基于防滑溶液的总重量为 100重量％，第一硅烷的通式为R a a Si（OR）4-a-b R b b，其中a的值为0至3; 当a的值为0时，b的值为0; 当a的值为1时，b的值为0〜2; 当a的值为2时，b的值为0〜1; 当a的值为3时，b的值为0; R表示具有1至4个碳原子的烷基; R1表示具有环氧官能团的烃基; 并且R 2表示具有1至2个碳原子的烷基; 和16.5-99重量％的第一溶剂，基于防滑溶液的总重量为100重量％，第一溶剂为水和/或醇。

公开(公告)号：WO2017101105A1

公开(公告)日：2017-06-22

申请号：PCT/CN2015/097870

申请日：2015-12-18

Applicant: 3M INNOVATIVE PROPERTIES COMPANY ,  CUI, Wei

Inventor： CUI, Wei ,  LIU, Hongbo ,  LIN, Weigang ,  YIN, Long ,  WU, Qing ,  JIN, Zhou

IPC: C09J133/08 ,  C09J183/04 ,  C08L83/04 ,  C08G77/42

CPC classification number: C08G77/42 ,  C08L83/04 ,  C09J133/068 ,  C09J183/04 ,  C08F220/14 ,  C08F2220/1825 ,  C08F220/06 ,  C08F2220/325

Abstract: UV curable adhesive compositions are provided that include 1) a UV curable poly(meth)acrylate copolymer containing monomeric units having an epoxy group wherein the poly(meth)acrylate copolymer has a glass transition temperature between -30°C and -10°C, 2) a silsesquioxane polymer having epoxy-containing groups, and 3) a photocatalyst. UV cured adhesive compositions and adhesive tapes containing the cured adhesive compositions are also provided. The cured adhesive compositions are pressure sensitive adhesives.

Abstract translation: 提供了可UV固化的粘合剂组合物，其包括1）含有具有环氧基团的单体单元的UV可固化聚（甲基）丙烯酸酯共聚物，其中所述聚（甲基）丙烯酸酯共聚物具有-30℃至-80℃的玻璃化转变温度 ;和-10℃，2）具有含环氧基团的倍半硅氧烷聚合物，和3）光催化剂。 还提供了UV固化的粘合剂组合物和含有固化的粘合剂组合物的胶带。 固化的粘合剂组合物是压敏粘合剂。

公开(公告)号：WO2015171360A1

公开(公告)日：2015-11-12

申请号：PCT/US2015/027970

申请日：2015-04-28

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： YIN, Long ,  YU, Zhigang ,  WU, Shupeng ,  JING, Naiyong

IPC: C09D1/00 ,  C09D7/12 ,  C09D5/02 ,  C09D201/00 ,  B05D5/00 ,  C08K7/26 ,  C08K5/54

CPC classification number: C09D5/02 ,  C08K3/36 ,  C09D1/00 ,  C09D7/67 ,  C09D201/00 ,  C09K3/149

Abstract: The present invention provides a slip resistant liquid comprising a reaction product of a reaction mixture comprising: 0.2-5 wt.% of a polymer; 0.5-10 wt.% of silica particles with an average particle size of less than or equal to 60 nm; 1-10 wt.% of a first silane represented by the general formula of R 1 a Si(OR) 4-a-b R 2 b , wherein the value of a is 0 to 3; when the value of a is 0, the value of b is 0; when the value of a is 1, the value of b is 0 to 2; when the value of a is 2, the value of b is 0 to 1; when the value of a is 3, the value of b is 0; R represents alkyl group having 1 to 4 carbon atoms, R 1 represents hydrocarbyl group with epoxy functional group, and R 2 represents alkyl group having 1 to 2 carbon atoms; 80-97 wt.% of water; and an acid, wherein the slip resistant liquid has a pH value of less than or equal to 5, the above percentages by weight are all based on the total weight of the slip resistant liquid as 100 wt.%. The slip resistant liquid provided by the present invention can form a slip resistant coating on the surface of the substrate to obtain a slip resistant article having good slip resistance performance.

Abstract translation: 本发明提供一种防滑液体，其包含反应混合物的反应产物，其包含：0.2-5重量％的聚合物; 平均粒度小于或等于60nm的二氧化硅颗粒为0.5-10重量％; 1-10重量％的由通式R1 aSi（OR）4-a-bR2 b表示的第一硅烷，其中a的值为0至3; 当a的值为0时，b的值为0; 当a的值为1时，b的值为0〜2; 当a的值为2时，b的值为0〜1; 当a的值为3时，b的值为0; R表示碳原子数为1〜4的烷基，R 1表示具有环氧官能团的烃基，R 2表示碳原子数1〜2的烷基。 80-97重量％的水; 和酸，其中防滑液体的pH值小于或等于5，上述重量百分比均基于防滑液体的总重量为100重量％。 本发明提供的防滑液体可以在基材的表面上形成防滑涂层，以获得具有良好防滑性能的防滑物品。

公开(公告)号：EP3036101A1

公开(公告)日：2016-06-29

申请号：EP14838449.8

申请日：2014-08-15

Applicant: 3M Innovative Properties Company

Inventor： YIN, Long ,  CHEN, Xue-hua ,  YU, Zhigang ,  SUN, Duyinzi ,  LIU, Wenbin ,  JING, Naiyong

IPC: B32B15/04 ,  B05D7/14 ,  C09D5/08

CPC classification number: C09D5/086 ,  B05D3/007 ,  C09D5/08 ,  C09D7/61

Abstract: The present invention provides an anti-corrosion solution comprising reaction products of the following reaction components: 1-30 wt % of a tetraalkyl orthosilicate, with the total weight of said anti-corrosion solution being 100 wt %; 0.2-6.0 wt % of a metal salt, with the total weight of said anti-corrosion solution being 100 wt %, said metal salt comprising one or more selected from the group consisting of: an aluminum salt, a strontium salt, a chromium salt, a zirconium salt and a cerium salt; an acid; 3-90 wt % of water, with the total weight of said anti-corrosion solution being 100 wt %; 4-95 wt % of an alcohol, with the total weight of said anti-corrosion solution being 100 wt %; said anti-corrosion solution having a pH value less than or equal to 4. The anti-corrosion solution provided by the present invention can form a dense transparent anti-corrosion coating layer on a substrate surface, the anti-corrosion coating layer having a good corrosion resistance performance.

公开(公告)号：EP3328946A1

公开(公告)日：2018-06-06

申请号：EP15899237.0

申请日：2015-07-29

Applicant: 3M Innovative Properties Company

Inventor： YIN, Long ,  YU, Zhigang ,  JING, Naiyong

IPC: C09D5/16 ,  C03C17/00 ,  C03C17/22

CPC classification number: C09D7/61 ,  C03C17/007 ,  C03C17/008 ,  C03C2217/445 ,  C03C2217/478 ,  C03C2217/75 ,  C08G59/20 ,  C08K3/36 ,  C08K5/5419 ,  C09D1/00 ,  C09D5/16 ,  C09D7/65

Abstract: Provided is a coated article comprising a substrate and a dried coating which comprises a first set of spherical silica nanoparticles having an average diameter of less than 20 nm and a second set of spherical silica nanoparticles having an average diameter of 20 nm to 120 nm. The alkoxy silane compound comprises an epoxy functional group or a carboxylic acid functional group. Also provided is a coating composition comprising an acidic aqueous dispersion which comprises the described first and second set of spherical silica nanoparticles and silane compound.

公开(公告)号：EP3390564A1

公开(公告)日：2018-10-24

申请号：EP15910576.6

申请日：2015-12-18

Applicant: 3M Innovative Properties Company

Inventor： CUI, Wei ,  LIU, Hongbo ,  LIN, Weigang ,  YIN, Long ,  WU, Qing ,  JIN, Zhou

IPC: C09J133/08 ,  C09J183/04 ,  C08L83/04 ,  C08G77/42

CPC classification number: C09J133/068 ,  C08G77/42 ,  C09J183/06 ,  C09J183/10 ,  C08F220/14 ,  C08F2220/1825 ,  C08F220/06 ,  C08F2220/325 ,  C08L83/06 ,  C08L33/068

Abstract: UV curable adhesive compositions are provided that include 1) a UV curable poly(meth)acrylate copolymer containing monomeric units having an epoxy group wherein the poly(meth)acrylate copolymer has a glass transition temperature between -30°C and -10°C, 2) a silsesquioxane polymer having epoxy-containing groups, and 3) a photocatalyst. UV cured adhesive compositions and adhesive tapes containing the cured adhesive compositions are also provided. The cured adhesive compositions are pressure sensitive adhesives.