公开(公告)号：EP2524914A4

公开(公告)日：2014-02-19

申请号：EP11732881

申请日：2011-01-12

Applicant: ADEKA CORP

Inventor： MURAI TOSHIHIKO ,  MAKABE YOSHIE ,  FUJITA SHOHEI

IPC: C07D221/14 ,  C07D311/92 ,  C07D405/12 ,  G03F7/004 ,  G03F7/038 ,  G03F7/039

CPC classification number: C07D221/14 ,  C07D311/92 ,  C07D405/12 ,  C09B57/08 ,  G03F7/0045 ,  G03F7/0046 ,  G03F7/038 ,  G03F7/0382 ,  G03F7/0397

Abstract: Disclosed are a novel sulfonic acid derivative compound and a novel naphthalic acid derivative compound with high solubility in organic solvents, good photosensitivity, and suitability as a photoacid generator and a polymerization initiator. The sulfonic acid derivative compound is represented by the formula (I) (wherein R 01 , R 04 , R 05 , and R 06 represent a hydrogen atom; any one of R 02 and R 03 represents an alkoxy group having a carbon number of 4 to 18 which may be substituted with an alicyclic hydrocarbon group, a heterocyclic group, or a halogen atom and which may have a branch, or the like; and R 07 represents an aliphatic hydrocarbon group having a carbon number of 1 to 18 which may be substituted with a halogen atom and/or an alkylthio group, or the like).

公开(公告)号：EP2502915A4

公开(公告)日：2013-03-20

申请号：EP10831576

申请日：2010-11-17

Applicant: ADEKA CORP

Inventor： MAKABE YOSHIE ,  OKUYAMA YUTA

IPC: C07D219/06 ,  C01G30/00 ,  C07C309/06 ,  C08F2/50 ,  C08G59/68 ,  C09K3/00 ,  G03F7/004

CPC classification number: C07D219/06 ,  C08F2/50 ,  C08G59/68 ,  C08L63/00 ,  G03F7/0045

公开(公告)号：EP2495234A4

公开(公告)日：2015-06-24

申请号：EP10826461

申请日：2010-09-28

Applicant: ADEKA CORP

Inventor： MAKABE YOSHIE ,  OKUYAMA YUTA

IPC: C07C381/12 ,  C07C309/06 ,  C08K5/375 ,  G03F7/004

CPC classification number: C07C381/12 ,  C07C309/06 ,  C08K5/375 ,  C09B69/004 ,  G03F7/0045

Abstract: The invention provides a photo-acid generator having high developing properties, a cationic polymerization initiator having high curing properties, and a resist composition and a cationically polymerizable composition containing the photo-acid generator and the cationic polymerization initiator, respectively. Specifically, the invention provides an aromatic sulfonium salt compound of general formula (I) and a photo-acid generator, a cationic polymerization initiator, a resist composition, and a cationically polymerizable composition containing the compound. In formula (I), R 1 to R 19 are each hydrogen, halogen, hydroxyl, optionally hydroxyl-substituted C1-C18 alkyl, optionally hydroxyl-substituted C1-C18 alkoxy, optionally hydroxyl-substituted C1-C18 thioalkoxy, etc.; An - is a monovalent anion; at least one of R 1 to R 19 is a substituent selected from the group consisting of hydroxyl, hydroxyl-substituted C1-C12 ester group, hydroxyl-substituted C1-C18 alkoxy, and hydroxyl-substituted C1-C18 thioalkoxy.

Abstract translation: 本发明提供具有高显影性的光酸产生剂，具有高固化性质的阳离子聚合引发剂，以及分别含有光酸产生剂和阳离子聚合引发剂的抗蚀剂组合物和阳离子聚合性组合物。 具体而言，本发明提供了通式（I）的芳族锍盐化合物和光酸产生剂，阳离子聚合引发剂，抗蚀剂组合物和含有该化合物的阳离子聚合性组合物。 在式（I）中，R 1至R 19各自为氢，卤素，羟基，任选羟基取代的C 1 -C 18烷基，任选羟基取代的C 1 -C 18烷氧基，任选羟基取代的C 1 -C 18硫代烷氧基等; An - 是一价阴离子; R 1至R 19中的至少一个是选自羟基，羟基取代的C 1 -C 12酯基，羟基取代的C 1 -C 18烷氧基和羟基取代的C 1 -C 18硫代烷氧基的取代基。

公开(公告)号：JP2009161682A

公开(公告)日：2009-07-23

申请号：JP2008001977

申请日：2008-01-09

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： MAKABE YOSHIE

IPC: C08G63/91 ,  C08F4/34 ,  C08F8/00 ,  C08G65/332 ,  C08G77/14 ,  C09C1/00 ,  C09C3/10

Abstract: PROBLEM TO BE SOLVED: To provide a novel polymer peroxide with excellent solubility and useful as a polymerization initiator and a pigment, a polymerization initiator containing the polymer peroxide, a pigment wherein a polymer radical obtained from the polymer peroxide is grafted to the surface of the pigment, and a pigment composition containing the pigment. SOLUTION: This polymer peroxide is represented by general formula (I) (In the formula, A 1 is a polymeric chain; X 1 is a direct bond, -CO- or -O-CO-; X 2 is a direct bond, -CO- or -CO-O-; X 3 is a direct bond, -NH-, -O-CO-R 6 -, -S-CO-R 6 - or -NH-CO-R 6 -; X 4 is a direct bond, -NH-, -R 7 -CO-O-, -R 7 -CO-S- or -R 7 -CO-NH-; R 6 and R 7 are each independently an alkylene group having 1 to 18 carbon atoms, an arylene group having 6 to 30 carbon atoms, an arylene alkylene group having 7 to 30 carbon atoms or an alkylene arylene alkylene group having 8 to 30 carbon atoms, the methylene group of R 6 and R 7 may be interrupted with -O- or -S-, and the hydrogen atom in the methylene group may be substituted with an alkyl group having 1 to 10 carbon atoms, an aryl group having 6 to 20 carbon atoms, an arylalkyl group having 7 to 20 carbon atoms, a hydroxyl group or a cyano group; and Y 1 a polymeric chain, a hydrogen atom, an alkyl group having 1 to 24 carbon atoms, an aryl group having 6 to 30 carbon atoms, an arylalkyl group having 7 to 30 carbon atoms, a heterocyclic group having 2 to 30 carbon atoms or a group represented by the general formula (II)). This polymerization initiator contains the polymer peroxide. COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：为了提供具有优异溶解性并可用作聚合引发剂和颜料的新型聚合物过氧化物，含有聚合物过氧化物的聚合引发剂，其中将由聚合物过氧化物获得的聚合物基团接枝到 颜料的表面和含有颜料的颜料组合物。 解决方案：该聚合物过氧化物由通式（I）表示（在该式中，A 1 是聚合物链; X 1 是直接键， CO-或-O-CO-; X 2 是直接键，-CO-或-CO-O-; X 3 是直接键，-NH- ，-O-CO-R 6，-S-CO-R 6，或-NH-CO-R 6， - X -NH-，-R SP 3，-CO-O-，-R SP 7，-CO-S-或 - R SP 3，-CO-NH-，R SP 6和R SP 7各自独立地为具有1至18个碳原子的亚烷基，亚芳基 具有6至30个碳原子，具有7至30个碳原子的亚芳基亚烷基或具有8至30个碳原子的亚烷基亚芳基亚烷基，R SP 6和R 7的亚甲基， / SP>可以被-O-或-S-中断，亚甲基中的氢原子可以被碳原子数1〜10的烷基，碳原子数6〜20的芳基，芳基烷基 具有7至20个碳原子，羟基或氰基;以及 聚合链，氢原子，碳原子数1〜24的烷基，碳原子数6〜30的芳基，碳原子数7〜30的芳基烷基，杂环基 具有2〜30个碳原子的基团或由通式（II）表示的基团）。 该聚合引发剂含有聚合物过氧化物。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2011105645A

公开(公告)日：2011-06-02

申请号：JP2009262367

申请日：2009-11-17

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： MAKABE YOSHIE ,  OKUYAMA YUTA

IPC: C07D219/06 ,  C01G30/00 ,  C07C309/06 ,  C08F4/00 ,  C08G59/68 ,  C09K3/00 ,  G03F7/004

CPC classification number: C07D219/06 ,  C08F2/50 ,  C08G59/68 ,  C08L63/00 ,  G03F7/0045

Abstract: PROBLEM TO BE SOLVED: To provide a photoacid generator having high developability, a cationic polymerization initiator having high curability, a resist composition and a cationically polymerizable composition using them.
SOLUTION: An aromatic sulfonium salt compound represented by general formula (I) (wherein R
1 -R
10 are each 1-18C alkyl which is unsubstituted or contains a substituent, or the like; R
11 -R
17 are each 1-18C alkyl which is unsubstituted or contains a substituent, or the like; R
18 is 1-18C alkyl which is unsubstituted or contains a substituent, or the like; and X
1
- is a monovalent anion) is used as a photoacid generator or a cationic polymerization initiator.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供具有高显影性的光致酸产生剂，具有高固化性的阳离子聚合引发剂，抗蚀剂组合物和使用它们的可阳离子聚合的组合物。 解决方案：由通式（I）表示的芳香族锍盐化合物（其中R 1 = X-SP 10 -R 16）是未被取代的或含有 取代基等; R 11和R 16各自为未取代的或含有取代基的1-18C烷基等; R 16， SP>是未取代的或含有取代基的1-18C烷基，等等;作为光酸产生剂，可以使用X 1 S 1 - 阳离子聚合引发剂。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2007034279A

公开(公告)日：2007-02-08

申请号：JP2006155876

申请日：2006-06-05

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： MAKABE YOSHIE ,  SATO NAOMI ,  MAEDA NAOKI ,  FUCHIGAMI KAZUYUKI

IPC: G03F7/027 ,  C08F290/14 ,  C08G59/14

Abstract: PROBLEM TO BE SOLVED: To provide an alkaline-developable photosensitive resin composition that is superior in sensitivity, resolution, transparency, adhesion and alkali resistance and is capable of accurately forming fine patterns. SOLUTION: The alkaline-developable photosensitive resin composition contains a reaction product, obtained by sequentially esterifying a polybasic acid anhydride (C) and a polyfunctional epoxy compound (D) with an epoxy adduct, having a structure formed by adding an unsaturated monobasic acid (B) to an epoxy resin (A), wherein the epoxy adduct has the structure formed by adding 0.1-1.0 piece of carboxyl group of the unsaturated monobasic acid (B) to 1 epoxy group of the epoxy resin (A), and esterification is performed in a ratio of 0.1-1.0 acid anhydride structure of the polybasic acid anhydride (C) and in a ratio of 0.1-1.0 epoxy group of the polyfunctional epoxy compound (D) to 1 hydroxyl group of the epoxy adduct. COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 要解决的问题：提供灵敏度，分辨率，透明性，粘合性和耐碱性优异的能够精确地形成精细图案的碱显影性感光性树脂组合物。 解决方案：碱显影感光性树脂组合物含有通过用环氧加成物连续酯化多元酸酐（C）和多官能环氧化合物（D）而获得的反应产物，其具有通过将不饱和一元酸 酸（B）与环氧树脂（A）反应，其中环氧加合物具有通过将不饱和一元酸（B）的0.1-1.0个羧基与环氧树脂（A）的1个环氧基相加而形成的结构，以及 以多元酸酐（C）的0.1-1.0酸酐结构与多官能环氧化合物（D）的0.1-1.0环氧基与环氧加成物的1个羟基的比例进行酯化。 版权所有（C）2007，JPO＆INPIT

公开(公告)号：JP2006251496A

公开(公告)日：2006-09-21

申请号：JP2005069292

申请日：2005-03-11

Applicant: Adeka Corp ,  Toppan Printing Co Ltd ,  凸版印刷株式会社 ,  株式会社Adeka

Inventor： SATO AZUMI ,  DEMACHI YASUYUKI ,  MAEDA TADATOSHI ,  ITO HIROMITSU ,  ISHIGURO TOMOHITO ,  MAKABE YOSHIE ,  SATO NAOMI ,  TAKADA MASAHIRO

IPC: G03F7/027 ,  C08F290/06 ,  C08G59/17 ,  G02B5/20 ,  G02B5/22 ,  G02F1/1335 ,  G03F7/004

Abstract: PROBLEM TO BE SOLVED: To provide an alkali developing type photosensitive coloring composition which is excellent in sensitivity, in adhesion property, and in resistance to alkalis, and with which a fine pattern is accurately formed. SOLUTION: The alkali developing type photosensitive coloring composition is a photosensitive coloring composition which at least contains a binder resin, a photo-polymerization initiator, a color material and a solvent, wherein a photo-polymerizable unsaturated compound, which is obtained by making an unsaturated monobasic acid (B) add to an epoxy resin (A) expressed by a general formula (I) with a ratio of 0.1-1.0 carboxyl group of the unsaturated monobasic acid (B) per 1 epoxy group of the epoxy resin (A) so as to form an epoxy addition product, and making the epoxy addition product and a polybasic acid anhydride (D) react with each other with a ratio of 0.2-0.8 acid anhydride structure of the polybasic acid anhydride (D) per 1 hydroxyl group of the epoxy addition product, is used as the binder resin. COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种敏感性，粘合性和耐碱性优异的精细图案精确形成的碱性显影型感光性着色组合物。 解决方案：碱显影型感光着色组合物是至少含有粘合剂树脂，光聚合引发剂，着色材料和溶剂的感光着色组合物，其中可光聚合的不饱和化合物是通过 使不饱和一元酸（B）添加到由通式（I）表示的环氧树脂（A）中，所述环氧树脂的每1个环氧基的不饱和一元酸（B）的比例为0.1-1.0个羧基（B） A）以形成环氧加成产物，并使环氧加成产物和多元酸酐（D）以每1个羟基的多元酸酐（D）的0.2-0.8酸酐结构的比例彼此反应 环氧加成产物组用作粘合剂树脂。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：JP2010235579A

公开(公告)日：2010-10-21

申请号：JP2009229777

申请日：2009-10-01

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： MAKABE YOSHIE ,  NAKAYASHIKI AKIKAZU

IPC: C07D209/88 ,  C09K3/00 ,  G03F7/004

Abstract: PROBLEM TO BE SOLVED: To provide a photoacid generator in which an acid can be efficiently generated to absorbed energy, which excels in developability, and can form a detailed pattern, and to provide an aromatic sulfonium salt compound which can be used as a cationic polymerization initiator excellent in curability.
SOLUTION: The aromatic sulfonium salt compound, for example is expressed by the formula.
COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种光致酸发生器，其中可以有效地产生酸以吸收能量，显影性优异，并且可以形成详细图案，并提供可用作 可固化性优异的阳离子聚合引发剂。 解决方案：芳族锍盐化合物例如由式表示。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2008050572A

公开(公告)日：2008-03-06

申请号：JP2007173022

申请日：2007-06-29

Applicant: Adeka Corp ,  株式会社Adeka

Inventor： MAKABE YOSHIE

IPC: C08G81/00

Abstract: PROBLEM TO BE SOLVED: To provide a new polymeric azo compound exhibiting excellent solubility which is useful as a polymerization initiator and a pigment, to provide a polymerization initiator containing the polymeric azo compound, to provide a pigment prepared by grafting a polymeric radical derived from the polymeric azo compound onto the pigment surface, and to provide a pigment composition containing the pigment. SOLUTION: The polymeric azo compound is represented by general formula (I). The polymerization initiator comprises the polymeric azo compound. The grafted pigment is prepared by grafting the high-molecular radical produced by thermal decomposition of a radical generator comprising the polymeric azo compound onto the surface of the pigment. The pigment composition comprises the grafted pigment, solvent and a binder resin. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：为了提供可用作聚合引发剂和颜料的具有优异溶解性的新的聚合偶氮化合物，以提供含有聚合偶氮化合物的聚合引发剂，以提供通过接枝聚合基团制备的颜料 衍生自聚合偶氮化合物到颜料表面上，并提供含有该颜料的颜料组合物。 解决方案：聚合偶氮化合物由通式（I）表示。 聚合引发剂包括聚合偶氮化合物。 通过将包含聚合偶氮化合物的自由基发生剂的热分解产生的高分子量接枝到颜料的表面上来制备接枝颜料。 颜料组合物包含接枝颜料，溶剂和粘合剂树脂。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007206369A

公开(公告)日：2007-08-16

申请号：JP2006025026

申请日：2006-02-01

Applicant: Adeka Corp ,  Toppan Printing Co Ltd ,  凸版印刷株式会社 ,  株式会社Adeka

Inventor： NAWA NOZOMI ,  DEMACHI YASUYUKI ,  SATO AZUMI ,  SATO NAOMI ,  MAKABE YOSHIE ,  FUJIGAMI WAKIFUMI ,  FUCHIGAMI KAZUYUKI

IPC: G03F7/027 ,  G02B5/20 ,  G03F7/004

Abstract: PROBLEM TO BE SOLVED: To provide a colored alkali developable resin composition that is superior in resolution and developability. SOLUTION: The colored alkali developable photosensitive resin composition contains a color material (G) and a photopolymerizable unsaturated compound (X), obtained by adding an unsaturated monobasic acid (B) to an epoxy compound (A) represented by Formula (I), further, adding a polybasic acid anhydride (C) and an epoxy compound (D), and further subjecting a polybasic acid anhydride (E) to esterification, where Cy is a 3-10C cycloalkyl group in the Formula (I). COPYRIGHT: (C)2007,JPO&INPIT

Abstract translation: 待解决的问题：提供分辨率和显影性优异的着色碱显影树脂组合物。 着色碱显影性感光性树脂组合物含有将不饱和一元酸（B）添加到式（I）表示的环氧化合物（A）中而得到的着色材料（G）和光聚合性不饱和化合物（X） ），进一步加入多元酸酐（C）和环氧化合物（D），进一步对多元酸酐（E）进行酯化反应，其中Cy是式（I）中的3-10C环烷基。 版权所有（C）2007，JPO＆INPIT