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公开(公告)号:US20230235103A1
公开(公告)日:2023-07-27
申请号:US18013369
申请日:2021-06-29
Applicant: ADEKA CORPORATION
Inventor: Tomofumi YOKOMIZO , Hirokatsu SHINANO , Hiromi TAKENOUCHI , Kensaku AKIMOTO , Yohei AOYAMA
IPC: C08F20/44 , C08F8/34 , H01M4/60 , H01M10/0525 , H01M4/04
CPC classification number: C08F20/44 , C08F8/34 , H01M4/604 , H01M10/0525 , H01M4/04 , H01M2004/027
Abstract: The present invention provides a sulfur-modified polyacrylonitrile having a total content of sulfur of from 30 mass % to 55 mass % and having a content of free sulfur of from 0.05 ppm by mass to 4 mass % determined by a solvent extraction method, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.
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公开(公告)号:US20220376257A1
公开(公告)日:2022-11-24
申请号:US17763825
申请日:2020-09-14
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Kenji KAKIAGE , Yuta NOHARA , Yohei AOYAMA
Abstract: The present invention provides a sulfur-modified polyacrylonitrile, which has a content of sulfur of from 30 mass % to 50 mass %, and satisfies the expression: 4,500
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公开(公告)号:US20210194005A1
公开(公告)日:2021-06-24
申请号:US16757934
申请日:2018-10-30
Applicant: ADEKA CORPORATION
Inventor: Kenji KAKIAGE , Hiromi TAKENOUCHI , Yuki HAMASAKI
IPC: H01M4/60 , H01M10/0525 , H01M4/66 , H01M4/13
Abstract: An organosulfur compound-containing slurry composition for making an electrode. The slurry composition forms an electrode mixture layer that exhibits high adhesion to a current collector even when combined with inexpensive aluminum foil current collector and therefore achieves sufficient capacity. The slurry composition contains an organosulfur compound, a binder, an electroconductive agent, and a solvent and has a pH of 4.0 to 9.0. The slurry composition preferably contains a basic compound. The organosulfur compound is preferably at least one of sulfur-modified elastomer compounds, sulfur-modified polynuclear aromatic compounds, sulfur-modified pitch compounds, sulfur-modified aliphatic hydrocarbon oxides, sulfur-modified polyether compounds, polythienoacene compounds, carbon polysulfide compounds, sulfur-modified polyamide compounds, and sulfur-modified polyacrylonitrile compounds.
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公开(公告)号:US20200350587A1
公开(公告)日:2020-11-05
申请号:US16960782
申请日:2019-02-25
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Tomofumi YOKOMIZO , Hirokatsu SHINANO , Kenji KAKIAGE , Yuta NOHARA , Yohei AOYAMA
Abstract: Disclosed is an electrode active material that has a large charge discharge capacity, a high initial efficiency, as well as excellent cycle characteristics and rate characteristics and is favorably used in a non-aqueous electrolyte secondary battery. An organo sulfur-based electrode active material contains sodium and potassium in a total amount of 100 ppm by mass to 1000 ppm by mass; an electrode for use in a secondary battery, the electrode containing the organo sulfur-based electrode active material as an electrode active material; and a non-aqueous electrolyte secondary battery including the electrode. Preferably, the organo sulfur-based electrode active material further contains iron in an amount of 1 ppm by mass to 20 ppm by mass. Preferably, the organo sulfur-based electrode active material is sulfur-modified polyacrylonitrile, and the amount of sulfur in the organo sulfur-based electrode active material is 25 mass % to 60 mass %.
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公开(公告)号:US20230261193A1
公开(公告)日:2023-08-17
申请号:US18013378
申请日:2021-06-29
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Tomofumi YOKOMIZO
IPC: H01M4/60 , C08F220/44 , C08F8/36
CPC classification number: H01M4/604 , C08F220/44 , C08F8/36 , H01M2004/028
Abstract: The present invention provides a sulfur-modified polyacrylonitrile, which has a total content of sulfur of from 30 mass % to 55 mass %, and has a value for the calculation formula (1) defined in Description of less than 0.08, an electrode active material containing the same, an electrode for a secondary battery including the electrode active material, a method of manufacturing the electrode, and a non-aqueous electrolyte secondary battery using the electrode.
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公开(公告)号:US20220340693A1
公开(公告)日:2022-10-27
申请号:US17763839
申请日:2020-09-14
Applicant: ADEKA CORPORATION
Inventor: Hiromi TAKENOUCHI , Kensaku AKIMOTO , Kenji KAKIAGE , Hirokatsu SHINANO , Tomofumi YOKOMIZO
Abstract: The present invention provides a method of producing sulfur-modified polyacrylonitrile, including: a step (1) of heating polyacrylonitrile and elemental sulfur in a rotating-type heating container including a discharge pipe and a sulfur vapor recovery unit while rotating the rotating-type heating container; a step (2) of liquefying a sulfur vapor by the sulfur vapor recovery unit while discharging hydrogen sulfide generated in the heating step; and a step (3) of returning the liquefied sulfur to a mixture of the sulfur and the polyacrylonitrile of the step (1).
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公开(公告)号:US20180375445A1
公开(公告)日:2018-12-27
申请号:US16062326
申请日:2017-01-06
Applicant: Seiki CHIBA , Mikio WAKI , KCM CORPORATION , ADEKA CORPORATION
Inventor: Noriyuki OYA , Hideyuki YOKOTA , Masatoshi HOMMA , Keiichi ODAGIRI , Hiromi TAKENOUCHI , Tomoaki SAIKI , Seiki CHIBA , Mikio WAKI
IPC: H02N11/00 , H02N2/18 , H01L41/113 , H01L41/193 , H01L41/09 , H01L41/187
Abstract: A converter includes a first electrode, a second electrode, a dielectric elastomer film, and a high-dielectric-constant film. The dielectric elastomer film is disposed between the first electrode and the second electrode, and has relative dielectric constant ε1. The high-dielectric-constant film is disposed at one or both of: a location between the first electrode and the dielectric elastomer film; and a location between the second electrode and the dielectric elastomer film. The high-dielectric-constant film has relative dielectric constant ε2 that is higher than the relative dielectric constant ε1.
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