公开(公告)号：US09994647B2

公开(公告)日：2018-06-12

申请号：US15114903

申请日：2015-01-27

Applicant: ARLANXEO NETHERLANDS B.V.

Inventor： Van Gerardus Henricus Josephus Doremaele ,  Alexandra Berthoud ,  Victor Quiroga Norambuena ,  Leszek Rupnicki ,  Peter Karbaum

IPC: C08F4/76 ,  C08F4/64 ,  C08F4/6592 ,  C08F210/16 ,  C07F7/28 ,  C08F210/18 ,  C08F4/659

CPC classification number: C08F4/6592 ,  C07F7/28 ,  C08F4/65912 ,  C08F210/16 ,  C08F210/18 ,  C08F2420/04 ,  C08F10/00 ,  C08F210/06 ,  C08F2500/17 ,  C08F236/20 ,  C08F2500/25

Abstract: The present invention relates to a A metal complex of formula 1 CyYMLjXn  (formula 1) wherein Cy is a cyclopentadienyl-type ligand; M is a metal of group 4; L is a neutral Lewis basic ligand wherein the number of said neutral ligands “j” is in the range of 0 to the amount that satisfies the 18-electron rule: X is an anionic ligand; n is an integer denoting the number of anionic ligands X and is 1 or 2, preferably is 2; Y is a cyclic amidine-containing ligand moiety represented by formula 2 wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom N2; S is a —CH2— unit, and t is the integer number denoting the number of S and is in the range of 1-4, more preferably in the range of 1-2, most preferably is 1; Sub1 is an aliphatic cyclic or linear substituent comprising a group 14 atom through which Sub2 is bonded to the amine nitrogen atom N1; Sub2 is an optionally substituted C2 unit in which the 2 carbon atoms may be sp2 or sp3 hybridized.

公开(公告)号：US10472431B2

公开(公告)日：2019-11-12

申请号：US15511358

申请日：2015-09-08

Applicant: ARLANXEO NETHERLANDS B.V.

Inventor： Peter Karbaum ,  Richard Thomas William Scott ,  John Van De Moosdijk

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/02 ,  C08F210/18 ,  C07F7/28 ,  C08F4/659

Abstract: A metal complex of the formula (1) CyLMZp(A)n (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, Cy is a cyclopentadienyl-type ligand substituted with at least one aliphatic C3-C20 hydrocarbyl group, which is bonded to the cyclopentadienyl-type ligand, in particular to its cyclopentadienyl ring, via a secondary, a tertiary or quaternary carbon atom and, L is an amidinate ligand of the formula (2), wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub1 is a substituent comprising a group 14 atom through which Sub1 is bonded to the imine carbon atom and Sub2 is a substituent comprising a heteroatom of group 15, through which Sub2 is bonded to the imine carbon atom and A is a neutral Lewis base ligand selected from the list consisting of ether, thioether, amine, tertiary phosphane, imine, nitrile and isonitrile, wherein the number of said metal ligands “n” is in the range of 0 to the amount that specifies the 18-electron rule.