公开(公告)号：US20030023113A1

公开(公告)日：2003-01-30

申请号：US10132690

申请日：2002-04-26

Applicant: ATOFINA

Inventor： Thierry Druzkowski ,  Gilles Herbst ,  Serge Tretjak ,  Alain Riondel

IPC: C07C229/30

CPC classification number: C07C213/08 ,  C07C219/08

Abstract: This process for the manufacture of an aqueous solution of the unsaturated quaternary ammonium salt corresponding to the formula (I), by reaction, in the presence of water, of N,N-dimethylaminoethyl acrylate (DAMEA) with a quaternizing agent of formula (II), is characterized in that the said reaction is carried out continuously in a rotating disc agitated column, with introduction of the quaternizing agent in the column bottom and introduction of the DAMEA and the water in the column top, the said reaction being carried out at a temperature of 35 to 60null C. and under a pressure of 10 to 20 bar. 1 nullRnullClnullnull(II)Rnullmethyl or benzyl radical.

Abstract translation: 通过在水存在下，将N，N-二甲基氨基乙基丙烯酸酯（DAMEA）与式（II）的季铵化剂反应制备对应于式（I）的不饱和季铵盐的水溶液的该方法 ），其特征在于所述反应在旋转圆盘搅拌柱中连续进行，并将季铵化合物引入塔底并将DAMEA和水引入塔顶，所述反应在 温度为35〜60℃，压力为10〜20巴。 R-Cl（II）R =甲基或苄基。

公开(公告)号：US20020091284A1

公开(公告)日：2002-07-11

申请号：US09984628

申请日：2001-10-30

Applicant: ATOFINA

Inventor： Alain Riondel ,  Vladimir Chaplinski

IPC: C07C229/34

CPC classification number: C08F20/34 ,  C07C211/63 ,  C07C219/08 ,  Y10S526/932

Abstract: These compounds are represented by the formulae (Ia) and (Ib). To prepare them, in a first stage, p-xylylene dichloride is reacted with a compound (II) to produce a compound (III) and, in a second stage, the compound (III) thus obtained is reacted with a compound of formula (IVa) or (IVb), resulting in an aqueous solution of the compound (Ia) or (Ib) respectively, the water of which is removed, if appropriate. 1 R1 hydrogen or methyl; R2nullethyl or isopropyl.

Abstract translation: 这些化合物由式（Ia）和（Ib）表示。 为了制备它们，在第一阶段中，将对二甲苯二氯与化合物（II）反应以产生化合物（III），并且在第二阶段中使由此获得的化合物（III）与式（III）化合物 IVa）或（IVb），如果合适，分别得到其水被除去的化合物（Ia）或（Ib）的水溶液。 R1氢或甲基; R2 =乙基或异丙基。

公开(公告)号：US20030220519A1

公开(公告)日：2003-11-27

申请号：US10411379

申请日：2003-04-11

Applicant: ATOFINA

Inventor： Alain Riondel ,  Jacqueline Bessalem

IPC: C07C069/52

CPC classification number: C07C67/08 ,  C07C69/54

Abstract: Butyl acrylate is prepared by reacting acrylic acid and butanol in a reactor in the presence of an esterification catalyst the water formed being entrained by distillation in a column (2) in the form of a heteroazeotropic mixture with butanol mixture following condensation, being separated in a decanter (3) to give an upper, organic phase which is recycled to the top of the distillation column (2) and a lower, aqueous phase which is drawn off. The reaction is conducted with deferred introduction of part of the butanol at the top of the distillation column (2) or to the decanter (3) or to the reactor (1), the butanol/acrylic acid molar ratio being initially between 0.5 and 1 before rising to between 1 and 1.5 following the completion of the deferred introduction of the butanol.

Abstract translation: 丙烯酸丁酯通过在反应器中在酯化催化剂存在下使反应器中的丙烯酸和丁醇反应来制备，所形成的水通过蒸馏在柱（2）中以与冷凝后的丁醇混合物的混合物形式的蒸馏夹带，在 滗析器（3），得到上部有机相，再循环到蒸馏塔（2）的顶部，并将较低的水相排出。 反应是在蒸馏塔（2）的顶部或蒸馏塔（3）或反应器（1）中延迟引入部分丁醇进行的，丁醇/丙烯酸摩尔比最初在0.5和1之间 在丁醇延迟引入完成后升至1至1.5之间。

公开(公告)号：US20020193545A1

公开(公告)日：2002-12-19

申请号：US10132691

申请日：2002-04-26

Applicant: ATOFINA

Inventor： Alain Riondel

IPC: C07C229/30

CPC classification number: C07C213/08 ,  C08F20/34 ,  C07C219/08

Abstract: A compound of formula (I) is prepared alone or in combination with at least one monomer of formula (II): the quaternizing agents benzyl chloride is introduced into a solution, in a solvent selected from compounds of the formulae (I) and (II) and mixtures of these, of the compound of formula (III) at a temperature of from 35 to 60null C., and then water is added and the reaction is allowed to proceed to complete or substantially complete conversion of the compound (III), an aqueous solution of desired compound (I) is isolated where appropriate with at least one compound (II), if this or these have/has been used as solvent, and the water is removed where appropriate. 1

Abstract translation: 式（I）化合物单独或与至少一种式（II）单体组合制备：将季铵化剂苄基氯引入溶液中，在选自式（I）和（II）的化合物的溶剂中 ）和这些的混合物，式（III）的化合物在35至60℃的温度下，然后加入水，并使反应进行以完成或基本上完全转化化合物（III） 如果这些或这些已经/已经被用作溶剂，则在适当的时候用至少一种化合物（II）分离所需化合物（I）的水溶液，并在适当的情况下除去水。

公开(公告)号：US20020183543A1

公开(公告)日：2002-12-05

申请号：US10132739

申请日：2002-04-26

Applicant: ATOFINA

Inventor： Alain Riondel ,  Fabrice Castellani

IPC: C07C067/02 ,  C07C229/32

CPC classification number: C07C213/06 ,  C07C219/08

Abstract: Process for preparing a compound (I) by reacting a compound of formula (II) with the alcohol (III). The reaction is carried out using dibutyltin oxide as transesterification catalyst. 1 R1nullH or CH3 R2nulllinear C1-C4 alkyl radical.

Abstract translation: 通过使式（II）的化合物与醇（III）反应制备化合物（I）的方法。 反应使用二丁基氧化锡作为酯交换催化剂进行。 R1 = H或CH3R2 =线性C1-C4烷基。

公开(公告)号：US20020183542A1

公开(公告)日：2002-12-05

申请号：US10113936

申请日：2002-04-02

Applicant: ATOFINA

Inventor： Alain Riondel ,  Jacqueline Bessalem

IPC: C07C067/08 ,  C07C069/54

CPC classification number: C07C67/08 ,  C07C67/62 ,  C07C69/54

Abstract: 2-Ethylhexyl acrylate is manufactured according to a process for the direct esterification of acrylic acid with 2-ethylhexanol catalysed by sulphuric acid, the acrylic acid subjected to the esterification being stabilized by at least one stabilizing agent, the said esterification being followed by the neutralization by a base of the crude reaction mixture (B1) obtained, the resulting salts passing into the aqueous phase (A1) of the said mixture, the organic phase (O1) and the aqueous phase (A1) resulting from this neutralization being separated and the 2-ethylhexyl acrylate being recovered from the organic phase (O1). To suppress the emulsions which appear during the said neutralization, the stabilizer or stabilizers of acrylic acid is/are chosen with the exclusion of hydroquinone, in the absence of which the aqueous phase of the process is stabilized before and/or during the neutralization.

Abstract translation: 丙烯酸2-乙基己酯是根据丙烯酸与硫酸催化的2-乙基己醇进行直接酯化的方法制备的，经过酯化反应的丙烯酸被至少一种稳定剂稳定，所述酯化后进行中和 通过得到的粗反应混合物（B1）的碱，所得到的盐进入所述混合物的水相（A1），由该中和产生的有机相（O1）和水相（A1）分离， 从有机相（O1）中回收丙烯酸2-乙基己酯。 为了抑制在所述中和过程中出现的乳液，除了氢醌之外，选择丙烯酸的稳定剂或稳定剂，在此过程的水相在中和之前和/或中和期间是稳定的。