Abstract:
A monomer with a chromophore group represented by Formula (I) wherein, AR1 represent a substituted or unsubstituted aromatic group; AR2 represent a substituted or unsubstituted aromatic group or a substituted or unsubstituted alkyl group; and R represents a substituted or unsubstituted alkyl group, with the proviso that one of R, AR1 and AR2 has a substituent with a polymerizable functional group. The monomer can be advantageously used to prepare polymeric dispersants for pigment dispersion, especially inkjet inks.
Abstract:
A pigment dispersion comprising a colour pigment represented by formula (I) wherein, R1 to R10 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, - CF3 , -COOH, -COOCH3; -SO2NH-C6H5, -CONH-C6H5, -CONH-C6H5-CONH2 and -CONH2; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said colour pigment. The pigment dispersion can be advantageously used in inkjet inks.
Abstract translation:一种颜料分散体,其包含由式(I)表示的彩色颜料,其中,R 1至R 10独立地选自氢,卤素原子,甲基,乙基,甲氧基,乙氧基,-CF 3 ,-COOH,-COOCH 3; -SO 2 NH-C 6 H 5,-CONH-C 6 H 5,-CONH-C 6 H 5 -CONH 2和-CONH 2; 以及一种聚合物分散剂,其通过与其聚合物主链共价连接的连接基团具有至少一个分子量小于所述彩色颜料分子量95%的未决发色团。 颜料分散体可以有利地用于喷墨油墨。
Abstract:
A radiation curable composition having a viscosity of no more than 50 mPa.s at 25° C and a shear rate of 90 s -1 contains: a) at least one non-polymerizable, non-polymeric bisacylphosphine oxide present in a concentration of no more than 4.0 wt% based on the total weight of the radiation curable composition; b) at least one monomer comprising at least one vinyl ether group and at least one polymerizable group selected from the group consisting of an acrylate group and a methacrylate group; and c) at least one polymerizable or polymeric thioxanthone, with the proviso that if the at least one polymerizable or polymeric thioxanthone contains no tertiary amine group that the radiation curable composition further includes at least one tertiary amine co-initiator selected from the group consisting of ethylhexyl-4-dimethylaminobenzoate, a polymerizable co-initiator containing a tertiary amine and a polymeric co-initiator containing a tertiary amine.
Abstract:
A method for making a negative-working heat-sensitive lithographic printing plate precursor is provided which comprises the steps of (i) providing a support having a hydrophilic surface or which is provided with a hydrophilic layer, and (ii) applying on said support a coating which comprises a product DQ, wherein DQ is obtained by - the step of coating a solution or dispersion comprising a nucleophilic compound Q and a dye D selected from the list consisting of di- or tri-arylmethane dyes, cyanine dyes, styryl dyes and merostyryl dyes; or by - the step of coating a solution or dispersion comprising said compound Q and coating another solution or dispersion comprising said dye D; wherein D and Q interact to form interaction product DQ, having a white light optical density which is lower than the white light optical density of dye D, and wherein said interaction product DQ is capable of at least partially releasing a dye directly after exposure to infrared light or heat, thereby forming a visible image in said coating.
Abstract:
A pigment dispersion comprising a colour pigment and a polymeric dispersant having at least one pending chromophore group covalently bound to the polymeric backbone of the polymeric dispersant through a linking group wherein the colour pigment is selected from the group consisting of monoazo pigments, disazo pigments, β-naphtol pigments, naphtol AS pigments, azo pigment lakes, benzimidazolone pigments, disazo condensation pigments, metal complex pigments, isoindolinone pigments, isoindolinine pigments, phthalocyanine pigments, quinacridone pigments, diketopyrrolo-pyrrole pigments, thioindigo pigments, anthraquinone pigments, anthrapyrimidine pigments, indanthrone pigments, flavanthrone pigments, pyranthrone pigments, anthanthrone pigments, isoviolanthrone pigments, aluminium pigment lakes, dioxazine pigments, triarylcarbonium pigments and quinophthalone pigments; the at least one pending chromophore group has a molecular weight which is smaller than 85 % of the molecular weight of the colour pigment; the at least one pending chromophore group occurs as a side group on the polymeric backbone and not as a group in the polymeric backbone itself or occurring solely as an end group of the polymeric backbone; the linking group consists of all the atoms between the polymeric backbone and the first atom of the aromatic group by which the pending chromophore group is linked to the polymeric backbone; and the at least one pending chromophore group has a similarity coefficient SIM of at least 0.75, with the similarity coefficient defined by (I) wherein, M represents the number of atoms in the at least one pending chromophore group; P represents the number of atoms in the colour pigment; C represents the largest number of atoms in common between the at least one pending chromophore group and the colour pigment as one continuous structure; and t is an integer representing the number of times that the largest number of atoms in common C fits into the organic colour pigment, without using atoms of the colour pigment twice. A method for preparing the pigment dispersion wherein the polymeric dispersant is prepared by copolymerizing a monomer already containing the pending chromophore group is also disclosed.
Abstract:
A negative-working lithographic printing plate precursor is disclosed which includes a support and a coating containing a photopolymerisable layer comprising a polymerisable compound including: - A free radical polymerisable group, and - at least one moiety having a structure according to Formula (I) wherein n represents an integer equal to 0 or 1; L 1 represents a divalent linking group and * denotes the linking positions to the rest of the structure, with the proviso that the carbonyl groups in Formula (I) are bonded to a carbon atom.
Abstract:
A method for making a lithographic printing plate is disclosed which comprises the steps of: (1) providing a heat-sensitive lithographic printing plate precursor comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a heat-sensitive coating, (2) image-wise exposing said precursor with IR-radiation or heat, and (3) developing said image-wise exposed precursor with an alkaline developing solution, characterised in that an antisludge agent is present in said precursor or in said developing solution or in said precursor and said developing solution, and wherein said antisludge agent is a 5-membered heteroaromatic compound, comprising a -NH-group wherein said hydrogen is capable of being deprotonated in said alkaline developing solution, selected from the group consisting of an optionally substituted benztriazole, 1, 2 , 3-triazole, tetrazole or indazole compound. According to the above method, the formation of sludge is inhibited or reduced.
Abstract:
A pigment dispersion comprising a colour pigment represented by formula (I) wherein, R1 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group, -CF3 , -COOH, -COOCH3 and; R2, R4 and R5 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,-CF3 , -COOH and -COOCH3; R3 is selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,-CF3, -COOH, -COOCH3, -SO2NH-C6H5, -CONH-C6H5, -CONH-C6H5-CONH2 and -CONH2 ; R6 and R7 are independently selected from the group consisting of hydrogen, a halogen atom, a methyl group, an ethyl group, a methoxy group, an ethoxy group,- CF3 , -COOH and -COOCH3, or R6 and R7 represent the necessary atoms to form an imidazolone ring; and a polymeric dispersant having via a linking group covalently linked to its polymeric backbone at least one pending chromophore group which has a molecular weight smaller than 95% of the molecular weight of said colour pigment. The pigment dispersion can be advantageously used in inkjet inks.