公开(公告)号：US20020002311A1

公开(公告)日：2002-01-03

申请号：US09775027

申请日：2001-02-01

Applicant: Appleton Papers Inc.

Inventor： Ponnampalam Mathiaparanam ,  Debra Arlene Berggren

IPC: C07C041/00

CPC classification number: C07C41/16 ,  C07C43/2055 ,  C07C43/225

Abstract: The present invention is a novel process, with or without solvent, for manufacture of compounds of the formula 1 wherein P is selected from phenyl and naphthyl; wherein R1 and R2 and R3 are each independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, alkoxyalkoxy, and aralkoxyalkoxy; wherein R5 is selected from substituted or unsubstituted phenyl, and substituted or unsubstituted naphthyl, the substituents being each independently selected from alkyl (C1-C8), alkoxy (C1-C8), aroxy, aralkoxy (C1-C8) and halogen. The process comprises reacting substituted phenols or naphthols of the formula 2 with ethylene carbonate in the presence of a first catalyst selected from metal halide, quarternary ammonium halide and quarternary phosphonium halide thereby forming an intermediate of the formula 3 then reacting the intermediate with a first compound selected from alkyl or aralkylhalide, alkyl or aralkyl sulfate, and alkyl or aralkyl sulfonate together with a metal hydroxide in the presence of a second catalyst, the second catalyst selected from quarternary ammonium salt or quarternary phosphonium salt.

Abstract translation: 本发明是一种具有或不含溶剂的新方法，用于制备下式的化合物其中P选自苯基和萘基; 其中R 1和R 2和R 3各自独立地选自氢，烷基，烷氧基，芳基，芳烷基，芳烷氧基，卤素，烷氧基烷氧基和芳烷氧基烷氧基; 其中R5选自取代或未取代的苯基和取代或未取代的萘基，取代基各自独立地选自烷基（C1-C8），烷氧基（C1-C8），芳氧基，芳烷氧基（C1-C8）和卤素。 该方法包括在选自金属卤化物，季铵卤化物和季铵卤化物的第一种催化剂的存在下使下式的取代酚或萘酚与碳酸亚乙酯反应，从而形成下式的中间体，然后使中间体与选自 烷基或芳烷基卤化物，烷基或芳烷基硫酸盐，和烷基或芳烷基磺酸盐与金属氢氧化物在第二催化剂存在下，第二催化剂选自季铵盐或季鏻盐。

公开(公告)号：US20040234756A1

公开(公告)日：2004-11-25

申请号：US10848148

申请日：2004-05-19

Applicant: Appleton Papers Inc.

Inventor： Ponnampalam Mathiaparanam ,  Mark Robert Fisher ,  Stacey Ann Justa MacNeil

IPC: B32B007/12

CPC classification number: B41M5/327 ,  B41M5/3336 ,  B41M2205/04 ,  B41M2205/36 ,  B41M2205/40 ,  C09J7/29 ,  C09J2203/334 ,  Y10T428/2848

Abstract: A linerless label system comprising pressure adhesive coating, release coating and thermal imaging coating is described. The thermal imaging coating contains as one of its components the compounds of the formula (I) 1 wherein R1 and R2 are selected from methyl, ethyl, aryl, aryl substituted with methyl, ethyl, methoxy, ethoxy or halogen, benzyl or benzyl with phenyl substituted with methyl, ethyl, methoxy, ethoxy or halogen, R3,R4,R5 and R6 are selected from hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, phenyl, R7 and R8 are each independently selected from methyl or ethyl, R9 is selected from hydrogen, methoxy or ethoxy, R10 is selected from hydrogen, dimethylamino or diethylamino, R11 is methyl. The imaged linerless label according to the invention has been a bar reflectance of less than 20 at 670 nanometers, a print control contrast signal of at least 80 and a BNL background of at least 75%.

Abstract translation: 描述了包括压力粘合剂涂层，剥离涂层和热成像涂层的无衬标签系统。 热成像涂层作为其组分之一包含式（I）化合物，其中R 1和R 2选自甲基，乙基，芳基，被甲基，乙基，甲氧基，乙氧基或卤素取代的芳基，苄基或苄基与苯基取代 甲基，乙基，甲氧基，乙氧基或卤素，R3，R4，R5和R6选自氢，卤素，甲基，乙基，甲氧基，乙氧基，苯基，R7和R8各自独立地选自甲基或乙基， 氢，甲氧基或乙氧基，R 10选自氢，二甲氨基或二乙氨基，R 11为甲基。 根据本发明的成像的无衬标签在670纳米处是小于20的条反射率，至少80的印刷控制对比度信号和至少75％的BNL背景。

公开(公告)号：US20030170435A1

公开(公告)日：2003-09-11

申请号：US10389932

申请日：2003-03-18

Applicant: Appleton Papers Inc.

Inventor： Ponnampalam Mathiaparanam ,  Mark Robert Fisher

IPC: B41M005/30

CPC classification number: B41M5/3375 ,  C07C43/202 ,  C07C43/2055 ,  C07C43/225 ,  Y10T428/24917

Abstract: The present invention is a novel thermally-responsive record material comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, an acidic developer material, a compound of the formula 1 wherein R1, R2 and R3 are independently selected from hydrogen, alkyl, alkoxy, aryl, aralkyl, aralkoxy, halogen, and alkoxyalkoxy; wherein R4 is independently selected from alkoxyalkyl, alkoxyalkoxy, and aralkoxyalkoxy, and a suitable binder therefor. In the context of the present invention the alkyl moieties in the alkyl, aralkyl, aralkoxy, alkoxyalkyl, alkoxyalkoxy and aralkoxyalkoxy preferably are eight carbons or less, and more preferably from one through four carbons. Substituents on aryl moieties in aryl, aralkyl, aralkoxy, and aralkoxyalkoxy groups can include hydrogen, alkyl, alkoxy and halogen. The alkyl group in these substituents also is eight carbons or less, and more preferably from one through four carbons. The thermally responsive record material of the invention has the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response.

Abstract translation: 本发明是一种新颖的热响应性记录材料，其包括基本上连续地提供给电子染料前体的基底，酸性显影剂材料，下式化合物其中R 1，R 2和R 3独立地选自氢，烷基 烷氧基，芳基，芳烷基，芳烷氧基，卤素和烷氧基烷氧基; 其中R 4独立地选自烷氧基烷基，烷氧基烷氧基和芳烷氧基烷氧基，及其合适的粘合剂。 在本发明的上下文中，烷基，芳烷基，芳烷氧基，烷氧基烷基，烷氧基烷氧基和芳烷氧基烷氧基中的烷基部分优选为8个碳以下，更优选为1〜4个碳。 芳基，芳烷基，芳烷氧基和芳烷氧基烷氧基中的芳基部分上的取代基可以包括氢，烷基，烷氧基和卤素。 这些取代基中的烷基也为8个以下碳原子，更优选为1〜4个碳原子。 本发明的热响应记录材料具有增强的图像强度或密度和/或改善的热响应的意想不到的和显着的性质。

公开(公告)号：US20020007091A1

公开(公告)日：2002-01-17

申请号：US09754643

申请日：2001-01-04

Applicant: Appleton Papers Inc.

Inventor： Ponnampalam Mathiaparanam

IPC: C07C043/225 ,  C07C043/20

CPC classification number: B41M5/3375 ,  C07C43/202 ,  C07C43/2055 ,  C07C43/225

Abstract: The present invention is a novel class of compounds useful in useful in thermally-responsive record material of the type comprising a substrate having provided thereon in substantially contiguous relationship an electron donating dye precursor, and an acidic developer material. The novel compound of the invention is a compound of the formula 1 wherein P is selected from 2 wherein R1, is selected from hydrogen, alkoxy, and aralkoxy; wherein R2 is aralkoxyalkoxy when P is phenyl, and R2 is selected from aralkoxyalkoxy or alkoxyalkoxy when P is naphthyl. Said alkyl moieties are each independently from one to eight carbons, said aryl moieties each independently being unsubstituted or substituted by alkyl (C1-C8), alkoxy (C1-C8) or halogen. The compounds of the invention enable manufacture of thermally responsive record material of the invention having the unexpected and remarkable properties of enhanced image intensity or density, and/or improved thermal response. The compounds of the invention also find use in diverse applications such as emolients and softening agents for creams, lots and cosmetics.

Abstract translation: 本发明是一类新颖的化合物，它们可用于热响应性记录材料，其类型包括基本上连续地提供给电子染料前体的基底和酸性显影剂材料。 本发明的新化合物是下式的化合物，其中P选自其中R 1选自氢，烷氧基和芳烷氧基; 其中当P是苯基时，R 2是芳烷氧基烷氧基，当P是萘基时，R 2选自芳烷氧基烷氧基或烷氧基烷氧基。 所述烷基部分各自为1至8个碳原子，所述芳基部分各自独立地为未取代的或被烷基（C1-C8），烷氧基（C1-C8）或卤素取代。 本发明的化合物使得能够制造本发明的热响应性记录材料，其具有增强的图像强度或密度和/或改善的热响应的意想不到的和显着的性质。 本发明的化合物还可用于各种应用，例如用于霜剂，批次和化妆品的固化剂和软化剂。