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公开(公告)号:CA2551017A1
公开(公告)日:2005-03-03
申请号:CA2551017
申请日:2004-07-19
Applicant: BASELL POLIOLEFINE SPA
Inventor: MEI GABRIELE , BAITA PIETRO , MEIER GERBEN , COVEZZI MASSIMO
IPC: C08F10/02 , B01J8/00 , B01J8/18 , B01J8/24 , B01J19/24 , C08F2/00 , C08F2/34 , C08F210/16 , C08L23/04 , C08L23/06 , C08L23/08
Abstract: Process for preparing a broad molecular weight polyethylene by polymerizing ethylene in the presence of a polymerization catalyst, the process comprisin g the following steps, in any mutual order: a) polymerizing ethylene, optional ly together with one or more a-olefinic comono~mers having from 3 to 12 carbon atoms, in a gas-phase reactor in the presence of hydrogen, b) copolymerizing ethylene with one or more a-olefinic comonomers having from 3 to 12 carbon atoms in another gas-phase reactor in the presence of an amount of hydrogen less than step a), where in at least one of said gas-phase reactors the growing polymer particles flow upward through a first polymerization zone under fast fluidization or transport conditions, leave said first polymerization zone and enter a second polymerization zone through which the y flow downward under the action of gravity.
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公开(公告)号:AU2003271648A1
公开(公告)日:2004-05-04
申请号:AU2003271648
申请日:2003-09-25
Applicant: BASELL POLIOLEFINE SPA
Inventor: COVEZZI MASSIMO , MEIER GERBEN , MEI GABRIELE
IPC: B01J8/18 , B01J8/24 , B01J8/26 , B01J8/38 , B01J19/24 , C08F2/00 , C08F2/34 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18
Abstract: Process for the gas-phase catalytic polymerization of olefins carried out in a plurality of interconnected polymerization zones, the process comprising feeding one or more monomers to said polymerization zones in the presence of a catalyst under reaction conditions and collecting the polymer product from said polymerization zones, in which process the polymer particles grow within a first polymerization zone where a fluidized bed is formed, at least a part of said polymer particles leave said first polymerization zone to enter a second polymerization zone through which they flow downward, leave said second polymerization zone and enter a third polymerization zone through which they flow upward under fast fluidization or transport conditions, leave said third polymerization zone and are reintroduced into the first polymerization zone, thus establishing a circulation of polymer between the different polymerization zones.
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