公开(公告)号：DE848498C

公开(公告)日：1952-09-04

申请号：DEB0008848

申请日：1950-08-19

Applicant: BASF AG

Inventor： ADAM KARL DR ,  TRIESCHMANN HANS-GEORG DR DR

IPC: B01J23/74 ,  B01J23/86 ,  C07C209/48

公开(公告)号：CH386035A

公开(公告)日：1964-12-31

申请号：CH8158459

申请日：1959-12-08

Applicant: BASF AG

Inventor： MERTENS HEINRICH DR ,  SCHMIDT OSWALD DR ,  ADAM KARL DR

IPC: B66B17/26 ,  C11D3/20 ,  C11D3/33 ,  C11D9/26 ,  C11D9/30

公开(公告)号：DE879916C

公开(公告)日：1953-06-18

申请号：DEB0001923

申请日：1950-02-07

Applicant: BASF AG

Inventor： ADAM KARL DR ,  GAETH RUDOLF DR ,  TRIESCHMANN HANS GEORG DR

IPC: C08J9/12

公开(公告)号：DE848654C

公开(公告)日：1952-09-08

申请号：DEB0008846

申请日：1950-08-19

Applicant: BASF AG

Inventor： ADAM KARL DR ,  WIMMER KARL DR

公开(公告)号：CH540871A

公开(公告)日：1973-08-31

申请号：CH838470

申请日：1970-06-04

Applicant: BASF AG

Inventor： ADAM KARL DR ,  HOFFMANN HERWIG DR ,  MERKEL KARL DR

IPC: C07C45/84 ,  C07C47/058 ,  C07C47/04

公开(公告)号：DE1955827A1

公开(公告)日：1971-05-13

申请号：DE1955827

申请日：1969-11-06

Applicant: BASF AG

Inventor： ADAM KARL DR ,  MERKEL KARL DR

IPC: A63H19/18

Abstract: Aqs. ethylene diamine is distilled in the presence of piperidine as an azeotrope former. The azeotrope may be dehydrated by distillation with a hydrocarbon, partic. benzene. Ethylene diamine is used in complex formation, plant protection agents and as an epoxide resin hardener.

公开(公告)号：CH489461A

公开(公告)日：1970-04-30

申请号：CH1256767

申请日：1967-09-08

Applicant: BASF AG

Inventor： RAFF PAUL DR ,  HANS GEORG DR PEINE ,  SCHUSTER LUDWIG DR ,  ADAM KARL DR

IPC: B01J27/186 ,  B01J27/187 ,  C07C87/40

公开(公告)号：NL138924B

公开(公告)日：1973-05-15

申请号：NL6613268

申请日：1966-09-20

Applicant: BASF AG

Inventor： ADAM KARL DR ,  SCHULZ ALFRED DR ,  HAARER ERICH DR ,  WINDERL SIEGFRIED DR

IPC: B01J21/08 ,  B01J23/50 ,  B01J23/68 ,  B01J23/70 ,  B01J23/89 ,  B01J37/02 ,  C07C121/26 ,  B01J11/16

公开(公告)号：DE2060548A1

公开(公告)日：1972-06-15

申请号：DE2060548

申请日：1970-12-09

Applicant: BASF AG

Inventor： ADAM KARL DR ,  AREND WOLFGANG DR ,  HAUG PETER DR ,  HIMMELHAN EMIL DIPL-ING ,  JOSCHEK HANS-INGO DR ,  WITTWER ARNOLD DR

IPC: C07C29/78 ,  C07C31/20

Abstract: Very pure 1,6-hexanediol is obtd. from a mixt. with other diols by opt. distilling out the light and heavy fractions and partially crystallising out crude alcohol mixt. by cooling to 42-15 degrees C, followed by sepn. of the crystals, washing with 1,6-hexanediol and recycling of the mother liquor obtd. after sepn. of the crystals to the crude alcohol mixt. prior to its distn. Purity is >99% as reqd. in the prepn. of plastics and esp. fibres.

公开(公告)号：DE1954546A1

公开(公告)日：1971-05-06

申请号：DE1954546

申请日：1969-10-30

Applicant: BASF AG

Inventor： ADAM KARL DR ,  MERKEL KARL DR ,  FUERST ERNST DR ,  HOFFMANN HERWIG DR

IPC: C07D295/088

Abstract: High yields of pure N-mono- and N,N'-bis-hydroxyalkylpiperazines for use as pharmaceutical intermediates are obtained by reacting piperazine with alkylene oxides, esp ethylene oxide in inert polar solvents, b.p. 130-170 degrees at ordinary pressure (an alcohol, an ether or ether alcohol e.g. ethylene-glycol-mono-n-propylether, or an ester e.g. isoamylacetate), and dissolving at least 5 w/% piperazine at 50 degrees. Slightly raised pressures and temp. of 80-120 degrees are favoured. No catalysts are required.