公开(公告)号：JPH09194213A

公开(公告)日：1997-07-29

申请号：JP30644296

申请日：1996-11-18

Applicant: BASF AG

Inventor： HARUTOMUUTO HIPUSUTO ,  ANDOREASU TEENTEN ,  RASHIYURO MAROJI

IPC: C01G1/00 ,  B01J23/00 ,  B01J23/20 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C01G41/00 ,  C07B61/00 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055

公开(公告)号：JPH09131532A

公开(公告)日：1997-05-20

申请号：JP20593796

申请日：1996-08-05

Applicant: BASF AG

Inventor： HARUTOMUUTO HIBUSUTO ,  ANDOREASU TEENTEN ,  RASHIYURO MAROJI

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/887 ,  B01J23/888 ,  B01J35/00 ,  C01G31/00 ,  C01G39/00 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055

Abstract: PROBLEM TO BE SOLVED: To make the efficient contact gaseous phase oxidation of a low mol.wt. org. compd. possible by using a multiple metal oxide material which has a multiphase structure expressed by the specific formula and contains molybdenum, vanadium and >=1 kinds of tungsten, niobium, tantalum, chromium and cerium. SOLUTION: This multiple metal oxide material is expressed by the formula [A]p [B]q (where, A denotes Mo12 Va X b X c X d X e X f X g Ox (active phase); B denotes X 12 Cub Hi Oy (promoter phase); X denotes W, Nb, Cr, etc.; X denotes Cu, Ni, Co, etc.; X denotes Sb, etc.; X denotes Na, K, etc.; X denotes Ca, Sr, Ba, etc.; X denotes Si, Al, Ti, etc.; X denotes Mo, W, etc.; (x), (y) are each the number determined by the valency and frequency of the elements exclusive of oxygen]. The three-dimensionally spread ranges A, B of the components [A]p , [B]q are distributed relatively and similarly like in the mixture composed of the fine A and the fine B with each other.