公开(公告)号：CH638780A5

公开(公告)日：1983-10-14

申请号：CH403478

申请日：1978-04-14

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: C07C403/14 ,  C07C20060101 ,  C07C43/30 ,  C07C43/303 ,  C07C67/00 ,  C07C401/00 ,  C07C403/00 ,  C07C403/10 ,  C07C175/00

公开(公告)号：CH636094A5

公开(公告)日：1983-05-13

申请号：CH623881

申请日：1981-09-28

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: C07D307/32

公开(公告)号：CH624918A5

公开(公告)日：1981-08-31

申请号：CH141376

申请日：1976-02-05

Applicant: BASF AG

Inventor： HOFFMANN WERNER DR ,  BAUMANN MANFRED DR

IPC: C07C45/60 ,  C07C45/66 ,  C07D309/30 ,  C07C49/603

Abstract: A process for the manufacture of 2,6,6-trimethyl-cyclo-hex-2-en-1-one by reacting 3-alkoxy-4-methyl-3-pentene or 3-alkoxy-4-methyl-2-pentene or a mixture of these compounds with acrolein, and reacting the resulting 2-alkoxy-2-ethyl-3,3-dimethyl-2,3-dihydro-4H-pyran with acids. The product is an intermediate for numerous syntheses of scents. Furthermore, a number of carotenoid syntheses are based on 2,6,6-trimethyl-cyclohex-2-en-1-one or its hydrogenation product, 2,6,6-trimethyl-cyclohexan-1-one.

公开(公告)号：CH601160A5

公开(公告)日：1978-06-30

申请号：CH1331176

申请日：1976-10-21

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: C07C45/00 ,  C07C45/72 ,  C07C45/74 ,  C07C45/78 ,  C07C45/82 ,  C07C45/85 ,  C07C49/203 ,  C07C49/603 ,  C07C67/00 ,  C07C49/48

Abstract: 2,6,6-Trimethyl-cyclohex-2-en-1-one is manufactured by reacting ethyl isopropyl ketone with acrolein in an organic solvent in the presence of a strong organic acid at from 40 DEG to 150 DEG C.

公开(公告)号：DE3260432D1

公开(公告)日：1984-08-30

申请号：DE3260432

申请日：1982-03-19

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: C07C45/45 ,  C07C49/403 ,  C07C49/427 ,  C07C49/443 ,  C07C49/657

公开(公告)号：CH635317A5

公开(公告)日：1983-03-31

申请号：CH403578

申请日：1978-04-14

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: A61K31/07 ,  A61K31/23 ,  C07C21/02 ,  C07C22/02 ,  C07C67/00 ,  C07C401/00 ,  C07C403/00 ,  C07C403/02 ,  C07C403/04 ,  C07C403/08 ,  C07C403/12 ,  C07F9/50 ,  C07F9/54 ,  C07C175/00

公开(公告)号：DE2860261D1

公开(公告)日：1981-01-29

申请号：DE2860261

申请日：1978-09-15

Applicant: BASF AG

Inventor： BAUMANN MANFRED DR ,  HOFFMANN WERNER DR

IPC: C07C1/34 ,  C07C13/40 ,  C07C29/14 ,  C07C33/05 ,  C07C33/12 ,  C07C45/60 ,  C07C47/225 ,  C07C47/45 ,  C07C69/74 ,  C07D317/12 ,  C11B9/00 ,  C07C121/48

公开(公告)号：CH613928A5

公开(公告)日：1979-10-31

申请号：CH1204775

申请日：1975-09-17

Applicant: BASF AG

Inventor： HOFFMANN WERNER DR ,  ARNOLD LOTHAR DR ,  BAUMANN MANFRED DR

IPC: C07C45/62 ,  C07C45/68 ,  C07C49/20 ,  C07C403/00 ,  C07F1/04 ,  C07C49/48 ,  C07C49/61

公开(公告)号：CH602552A5

公开(公告)日：1978-07-31

申请号：CH984576

申请日：1976-08-02

Applicant: BASF AG

Inventor： HOFFMANN WERNER DR ,  BAUMANN MANFRED DR

IPC: C07C69/52 ,  C07C69/587

Abstract: A process for the manufacture of alpha , beta , gamma , delta -unsaturated esters containing a very high proportion of the 4(Z)-isomer, which are valuable perfume and flavor materials. The alpha , beta , gamma , delta -unsaturated esters are manufactured by a Wittig synthesis from phosphoranes and fumaraldehyde-acid esters under specific conditions.

公开(公告)号：DE19533665C2

公开(公告)日：1997-09-18

申请号：DE19533665

申请日：1995-09-12

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  TRUEBENBACH PETER DR ,  BAUMANN MANFRED DR ,  SCHUBERT JUERGEN DR

IPC: C07C37/07 ,  B01J23/44 ,  C07C39/07

Abstract: The prodn. of an alkylphenol of formula (I) comprises reacting corresp. alkyl-cyclohex-2- en-1-one of formula (II) at 200-400 degrees C and 0.01-50 bar in presence of a supported Pd/ alpha -alumina catalyst (III) with a specific surface (BET) of 1-10 m /g, a pore dia. of 5 nm to 300 microns and a pore vol. of 0.1-0.5 cm /g, in which 80-100% of the pores have a dia. of 40-400 nm. R1-R5 = H or 1-8C alkyl. Also claimed are catalysts (III) as such.