公开(公告)号：GB906219A

公开(公告)日：1962-09-19

申请号：GB376361

申请日：1961-02-01

Applicant: BASF AG

Inventor： SPAENIG HERMANN ,  BECK JULIUS

IPC: C07C37/14

Abstract: Para-alkyl or -cycloalkyl phenols are obtained by reacting a phenol unsubstituted in the p- and in at least one o-position with a C3-20 alkene or cycloalkene in presence of 0.1-10% wt. ZnCl2 and 0.1-3% wt. HCl (with reference to the phenol) at between 50 and 150 DEG C., the phenol and alkene or cycloalkene being reacted in stoichiometric amounts or up to 5% mol excess of one of the reagents. The examples describe the preparation of p-t-butyl, -nonyl, i-octyl and -cyclohexyl phenols and p-t-butyl-o-cresol. Specific phenols listed are phenol; o- and m-cresols and m-xylenols; o-i-butyl, o-dodecyl, 2:5-dibutyl and 2:3-diethylphenols; o- and m-chloro and -bromophenols; 2:3- and 2:5-dichloro and -dibromophenols; salicylic acid, its ethyl ester and 2-methyl-5-nitrophenol; a -naphthol and its m-methyl, -butyl, -chloro and -nitro derivatives. Alkenes mentioned are butenes-1 and -2, and isobutene; the 2-methyl derivatives of butene-2, pentene-1 and 3:4- and 4:4-dimethylpentene-2; nonene-1, undecene-1, dodecene-6, octadecene-1, cyclohexene, cyclo-octene and methylcyclohexene-1.

公开(公告)号：BE599716A

公开(公告)日：1961-07-31

申请号：BE599716

申请日：1961-01-31

Applicant: BASF AG

Inventor： SPAENIG HERMANN ,  BECK JULIUS

IPC: C07C37/14 ,  C07A

公开(公告)号：FR1377702A

公开(公告)日：1964-11-06

申请号：FR956337

申请日：1963-12-06

Applicant: BASF AG

Inventor： BECK JULIUS ,  FISCHER ADOLF ,  STUMMEYER HERBERT

IPC: C07C205/43