公开(公告)号：AT274028T

公开(公告)日：2004-09-15

申请号：AT99970101

申请日：1999-09-29

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  WEBER MARTIN ,  GINSS CHRISTOPHE ,  BERZ STEPHAN ,  KRESS NORBERT

IPC: C08J5/04 ,  C08F265/04 ,  C08F279/02 ,  C08K3/40 ,  C08K5/00 ,  C08K7/14 ,  C08L25/08 ,  C08L25/12 ,  C08L25/14 ,  C08L51/00 ,  C08L51/06 ,  C08L55/02 ,  C08L67/02 ,  C08L67/03 ,  C08L101/10 ,  C08L51/04

Abstract: The invention relates to a fiber-reinforced thermoplastic moulding material containing the following ingredients in relation to the sum of ingredients A-D and optionally E and F, representing a total of 100 wt. %: d) 10-97 wt. % of at least one aromatic polyester as ingredient A; e) 1-50 wt. % of at least one particle-shaped grafted copolymer with a soft phase glass transition temperature that is lower than 0 DEG C and an average particle size of 50-1000 nm as ingredient B; f) 1-50 wt. % of at least one copolymer made of monomers c1) 50-90 wt. % of at least one vinyl aromatic monomer as ingredient C1 and c2) 10-25 wt. % acrylonitrile and/or methacrylonitrile as ingredient C2, as ingredient C; 1-50 wt. % glass fibers as ingredient D; f) 0-25 wt. % other ingredients that are compatible, can be mixed in a homogenous manner with ingredients A and/or C and can be dispersed therein, as ingredient E; f) 0-10 wt. % usual additives such as UV stabilizers, oxidation retarders, lubricating agents and release agents as ingredient F. The invention also relates to moulded parts made from said moulding materials and used in the interiors of motor vehicles. The invention further relates to the use of moulding materials in the production of moulded parts.

公开(公告)号：DE50007291D1

公开(公告)日：2004-09-09

申请号：DE50007291

申请日：2000-01-14

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  B32B27/36 ,  C08K3/04 ,  C08K7/02 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: A process for the preparation of fiber-reinforced moldings for motor vehicles wherein the molding comprisesa) from 1 to 96.86% by weight of at least one polycondensate,b) from 1 to 12% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) from 1 to 12% by weight of at least one copolymer made from the following monomers,c1) from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, based in each case on component c,d) from 0 to 20% by weight ofe) from 0.01 to 15% by weight of a polycarbonate,f) from 0.01 to 2% by weight of a carbon black,g) from 0 to 12% by weight of a polymer other than component B,h) from 0 to 20% by weight of a polyester other than component A,i) from 0.1 to 10% by weight of conventional additives, such as UV stabilizers, oxidation retarders, lubricants and mold-release agents. Moldings and composites made from these molding compositions are as described as is the use of the molding compositions, the moldings and the composites.

公开(公告)号：BR0007753A

公开(公告)日：2001-10-30

申请号：BR0007753

申请日：2000-01-14

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  B32B27/36 ,  C08K3/04 ,  C08K7/02 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: A process for the preparation of fiber-reinforced moldings for motor vehicles wherein the molding comprisesa) from 1 to 96.86% by weight of at least one polycondensate,b) from 1 to 12% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) from 1 to 12% by weight of at least one copolymer made from the following monomers,c1) from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, based in each case on component c,d) from 0 to 20% by weight ofe) from 0.01 to 15% by weight of a polycarbonate,f) from 0.01 to 2% by weight of a carbon black,g) from 0 to 12% by weight of a polymer other than component B,h) from 0 to 20% by weight of a polyester other than component A,i) from 0.1 to 10% by weight of conventional additives, such as UV stabilizers, oxidation retarders, lubricants and mold-release agents. Moldings and composites made from these molding compositions are as described as is the use of the molding compositions, the moldings and the composites.

公开(公告)号：DE19903073A1

公开(公告)日：2000-08-10

申请号：DE19903073

申请日：1999-01-27

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  B32B27/36 ,  C08K3/04 ,  C08K7/02 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: The invention relates to fibre-reinforced moulding materials containing, in relation to the sum of components A to F and possibly G to I which adds up to a total of 100 % by weight, of a) between 1 and 96.86 % by weight of at least one polycondensate, as component A; b) between 1 and 12 % by weight of at least one particulate graft copolymer having a glass transition temperature in the soft phase of below 0 DEG C and a mean particle size of between 50 and 1000 nm, as component B; c) as component C between 1 and 12 % by weight of at least one copolymer which consists of the following monomers: c1) between 50 and 90 % by weight, in relation to component C, of at least one aromatic vinyl monomer, as component C1; and c2) between 10 and 50 % by weight, in relation to component C, acrylic nitrile and/or methacrylic nitrile, as component C2; d) between 1 and 20 % by weight fibres, as component D; e) between 0.01 and 15 % by weight of a polycarbonate, as component E; f) between 0.01 and 2 % by weight of a black, as component F; g) between 0 and 12 % by weight of a polymer which is different from component B, as component G; h) between 0 and 20 % by weight of a polyester which is different from component A, as component H; and i) between 0.1 and 10 % by weight of standard additives such as UV stabilizers, antioxidants, lubricants and mould-release agents as component I. The invention further relates to moulded parts and composites made from the above moulded materials and to the use of said moulded materials, moulded parts and composites.

公开(公告)号：MY122687A

公开(公告)日：2006-04-29

申请号：MYPI20000257

申请日：2000-01-26

Applicant: BASF AG

Inventor： FISCHER MICHAEL DR ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  C08K7/02 ,  B32B27/36 ,  C08K3/04 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: A PROCESS FOR THE PREPARATION OF FIBER-REINFORCED MOLDINGS FOR MOTOR VEHICLES WHEREIN THE MOLDING COMPRISES (A) FROM 1 TO 96.86% BY WEIGHT OF AT LEAST ONE POLYCONDENSATE, (B) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE PARTICULATE GRAFT COPOLYMER WHOSE SOFT PHASE HAS A GLASS TRANSITION TEMPERATURE BELOW 0?C. AND WHOSE MEDIAN PARTICLE SIZE IS FROM 50 TO 1000 NM, (C) FROM 1 TO 12% BY WEIGHT OF AT LEAST ONE COPOLYMER MADE FROM THE FOLLOWING MONOMERS, (C1) FROM 50 TO 90% BY WEIGHT OF AT LEAST ONE VINYLAROMATRIC MONOMER, AND (C2) FROM 10 TO 50% BY WEIGHT OF ACRYLONITRILE AND/OR METHACRYLONITRILE, BASED IN EACH CASE ON COMPONENT C, (D) FROM 0 TO 20% BY WEIGHT OF (E) FROM 0.01 TO 15% BY WEIGHT OF POLYCARBONATE, (F) FROM 0.01 TO 2% BY WEIGHT OF A CARBON BLACK, (G) FROM 0 TO 12% BY WEIGHT OF A POLYMER OTHER THAN COMPONENT B, (H) FROM 0 TO 20% BY WEIGHT OF A POLYESTER OTHER THAN COMPONENT A, (I) FROM 0.1 TO 10% BY WEIGHT OF CONVENTIONAL ADDITIVES, SUCH AS UV STABILIZERS, OXIDATION RETARDERS, LUBRICANTS AND MOLD-RELEASE AGENTS. MOLDINGS AND COMPOSITES MADE FROM THESE MOLDING COMPOSITIONS ARE AS DESCRIBED AS IS THE USE OF THE MOLDING COMPOSITIONS, THE MOLDINGS AND THE COMPOSITES.

公开(公告)号：DE10003270A1

公开(公告)日：2001-08-02

申请号：DE10003270

申请日：2000-01-26

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: B32B27/08 ,  C08K5/134 ,  C08K5/51 ,  C08L25/12 ,  C08L51/04 ,  C08L67/02 ,  B32B27/36 ,  C08J11/04

Abstract: The invention relates to stabilized fiber-reinforced thermoplastic molding compounds, to the molded parts, composite materials and laminates produced on the basis thereof and to the use of the molding compounds for producing molded parts, composite materials and laminates. The invention further relates to the use of a stabilizer for adjusting the properties of molding compounds, molded parts, composite materials and laminates with a thermoplastic molding compound that contains, based on the sum of components A to E and optionally F and G that adds up to 100 wt.- %, a) 10 to 96.9 wt.- % of at least one aromatic polyester as component A, b) 1 to 50 wt.- % of at least one particulate graft copolymer with a glass transition temperature of the soft phase below 0 DEG C and average particle size of 50 to 1000 nm as component B, c) 1 to 50 wt.- % of at least one copolymer consisting of the monomers c1) 50 to 90 wt.- % of at least on vinyl-aromatic monomer as component C1 and c2) 10 to 50 wt.- % acrylnitril and/or methacrynitril as component C2, as component C, d) 1 to 50 wt.- % fibers as component D, and e) 0.1 to 2 wt.- % of a stabilizer as component E. Said stabilizer consists of at least one main stabilizer and optionally at least one co-stabilizer, said main stabilizer being a hydrocarbon optionally containing N, O or S or at least two of them as a heteroatom. Said hydrocarbon is bound, via " &tilde& ", with at least one sterically hindered, optionally deprotonated phenol of the general formula (I), wherein R = tertiary butyl, cyclopentyl or cyclohexyl, and R = H, C1 to C10 hydrocarbon, and has a molecular weight in the range of 250 to 2500 g/mol. The co-stabilizer consists of at least one phosphorus with 3 hydrocarbon rests bound thereto, wherein at least one of the rests is bound via an oxygen atom, and has molecular weight in the range of 91 to 1500 g/mol. The inventive thermoplastic material further contains f) 0 to 25 wt.- % of other acceptable polymers that can be mixed with components A and/or C to give a homogeneous mixture or that can be dispersed therein, as component F, g) 0 to 10 wt.- % usual additives such as UV stabilizers, antioxidants, lubricants and mold release agents as component G.

公开(公告)号：AU2541600A

公开(公告)日：2000-08-18

申请号：AU2541600

申请日：2000-01-14

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08J5/04 ,  B32B5/18 ,  B32B27/36 ,  C08K3/04 ,  C08K7/02 ,  C08L25/12 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L67/02 ,  C08L69/00 ,  C08L87/00

Abstract: A process for the preparation of fiber-reinforced moldings for motor vehicles wherein the molding comprisesa) from 1 to 96.86% by weight of at least one polycondensate,b) from 1 to 12% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) from 1 to 12% by weight of at least one copolymer made from the following monomers,c1) from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) from 10 to 50% by weight of acrylonitrile and/or methacrylonitrile, based in each case on component c,d) from 0 to 20% by weight ofe) from 0.01 to 15% by weight of a polycarbonate,f) from 0.01 to 2% by weight of a carbon black,g) from 0 to 12% by weight of a polymer other than component B,h) from 0 to 20% by weight of a polyester other than component A,i) from 0.1 to 10% by weight of conventional additives, such as UV stabilizers, oxidation retarders, lubricants and mold-release agents. Moldings and composites made from these molding compositions are as described as is the use of the molding compositions, the moldings and the composites.

公开(公告)号：AU6467499A

公开(公告)日：2000-04-26

申请号：AU6467499

申请日：1999-10-01

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08F265/04 ,  C08F279/02 ,  C08K3/04 ,  C08K5/00 ,  C08L25/08 ,  C08L25/12 ,  C08L25/14 ,  C08L51/00 ,  C08L51/06 ,  C08L55/02 ,  C08L67/02 ,  C08L101/00

Abstract: A thermoplastic molding composition comprises, based on the total of components A to C and, if desired, D and E, which in total give 100% by weight,a) as component A, from 10 to 98% by weight of at least one aromatic polyester,b) as component B, from 1 to 50% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) as component C, from 1 to 50% by weight of at least one copolymer made from the following monomersc1) as component C1, from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) as component C2, from 10 to 25% by weight of acrylonitrile and/or methacrylonitrile,d) as component D, from 0 to 25% by weight of other compatible polymers hormogeneously miscible with components A and/or C or dispersible in these, ande) as component E, from 0 to 10% by weight of conventional additives, such as UV stabilizers, carbon black, pigments, oxidation retarders, lubricants and mold-release agents.Moldings made from these molding compositions and used in motor vehicle interiors are also described, as is the use of the molding compositions to produce the moldings.

公开(公告)号：ES2222039T3

公开(公告)日：2005-01-16

申请号：ES99952479

申请日：1999-10-01

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08F265/04 ,  C08F279/02 ,  C08K3/04 ,  C08K5/00 ,  C08L25/08 ,  C08L25/12 ,  C08L25/14 ,  C08L51/00 ,  C08L51/06 ,  C08L55/02 ,  C08L67/02 ,  C08L101/00

Abstract: Empleo de masas de moldeo termoplásticas, que contienen, referido a la suma de los componentes A hasta C y, en caso dado, D y E, que resulta un 100% en peso, a) de un 10 hasta un 98% en peso de al menos un poliéster aromático como componente A, b) de un 1 hasta un 50% en peso de al menos un copolímero de injerto en forma de partículas, con una temperatura de transición vítrea de la fase elástica por debajo de 0ºC y un tamaño de partículas medio de 50 hasta 1000 nm como componente B, c) de un 1 hasta un 50% en peso de un copolímero, formado por los monómeros c1) de un 50 hasta un 90% en peso de al menos un monómero vinilaromático como componente C1, y c2) de un 10 hasta un 25% en peso de acrilonitrilo y/o metacrilonitrilo como componente C2, como componente C, d) de un 0 hasta un 25% en peso de otros polímeros compatibles, miscibles con los componentes A y/o C o dispersables en estos, como componente D, e) de un 0 hasta un 10% en peso de aditivos escogidos de estabilizantes de UV, hollín, pigmentos, retardantes de la oxidación, lubricantes y agentes desmoldeantes como componente E. para la obtención de piezas moldeadas para el recinto interior de automóviles.

公开(公告)号：DE59909660D1

公开(公告)日：2004-07-08

申请号：DE59909660

申请日：1999-10-01

Applicant: BASF AG

Inventor： FISCHER MICHAEL ,  KNOLL MANFRED ,  GINSS CHRISTOPHE ,  BERZ STEPHAN

IPC: C08F265/04 ,  C08F279/02 ,  C08K3/04 ,  C08K5/00 ,  C08L25/08 ,  C08L25/12 ,  C08L25/14 ,  C08L51/00 ,  C08L51/06 ,  C08L55/02 ,  C08L67/02 ,  C08L101/00

Abstract: A thermoplastic molding composition comprises, based on the total of components A to C and, if desired, D and E, which in total give 100% by weight,a) as component A, from 10 to 98% by weight of at least one aromatic polyester,b) as component B, from 1 to 50% by weight of at least one particulate graft copolymer whose soft phase has a glass transition temperature below 0° C. and whose median particle size is from 50 to 1000 nm,c) as component C, from 1 to 50% by weight of at least one copolymer made from the following monomersc1) as component C1, from 50 to 90% by weight of at least one vinylaromatic monomer, andc2) as component C2, from 10 to 25% by weight of acrylonitrile and/or methacrylonitrile,d) as component D, from 0 to 25% by weight of other compatible polymers hormogeneously miscible with components A and/or C or dispersible in these, ande) as component E, from 0 to 10% by weight of conventional additives, such as UV stabilizers, carbon black, pigments, oxidation retarders, lubricants and mold-release agents.Moldings made from these molding compositions and used in motor vehicle interiors are also described, as is the use of the molding compositions to produce the moldings.