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公开(公告)号：DE19905712A1
公开(公告)日：2000-08-17
申请号：DE19905712
申请日：1999-02-11
Applicant: BASF AG
Inventor： KROENER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: The invention relates to a method for on-line monitoring and controlling the monomer conversion during emulsion polymerization. According to said method, a balance is continuously made, starting from an initialization point in time, of the heat amount Q?IN? fed to a reaction, the reaction enthalpy Q?RE? added by the supply with monomers and the amount of heat Q?OUT? dissipated from the reactor. A non-dissipated amount of heat Q?AD? is calculated on the basis of these values which in the case of a spontaneous adiabatic reaction would result in an increase in the internal temperature and the internal pressure of the reactor. A check is carried out whether the potential adiabatic temperatures and pressures are always within the predetermined upper limits. If said upper limits are exceeded, the addition of monomers to the reactor is slowed down or stopped.
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公开(公告)号：ES2257290T3
公开(公告)日：2006-08-01
申请号：ES00916827
申请日：2000-02-10
Applicant: BASF AG
Inventor： KRONER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: Procedimiento para la monitorización y el control en línea de la conversión de monómeros durante la polimerización en emulsión en un reactor, en el que a) se selecciona un momento t0 = 0 de inicialización y se le asigna al reactor para este momento una capacidad Q0 calórica inicial determinada, b) a partir del momento de inicialización se determina de manera continua la cantidad QIN de calor suministrada al reactor, la entalpía QRE de reacción suministrada y la cantidad QOUT de calor disipada del reactor, c) se calcula la cantidad QAD de calor no disipado según la ecuación siguiente: d) a partir de la cantidad QAD(t) de calor no disipada y de la temperatura T(t) interna instantánea del reactor se calcula la temperatura TAD interna máxima que aparece en caso de una reacción adiabática espontánea, y e) si la temperatura TAD interna máxima calculada sobrepasa la temperatura T(t) interna instantánea del reactor en un valor determinado, se llevan a cabo medidas, que impiden un ascenso adicionalde la cantidad QAD de calor no disipada.
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公开(公告)号：CA2362511A1
公开(公告)日：2000-08-17
申请号：CA2362511
申请日：2000-02-10
Applicant: BASF AG
Inventor： KRONER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: The invention relates to a method for on-line monitoring and controlling the monomer conversion during emulsion polymerization. According to said method, a balance is continuously made, starting from an initialization point in time, of the heat amount QIN fed to a reaction, the reaction enthalpy QRE added by the supply with monomers and the amount of heat QOUT dissipated from the reactor. A non-dissipated amount of heat QAD is calculated on the basis of these values which in the case of a spontaneous adiabatic reaction would result in an increase in the internal temperature and the internal pressure of the reactor. A check is carried out whether the potential adiabatic temperatures and pressures are always within the predetermined upper limits. If said upper limits are exceeded, the addition of monomers to the reactor i s slowed down or stopped.
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公开(公告)号：TR200102319T2
公开(公告)日：2001-11-21
申请号：TR200102319
申请日：2000-02-10
Applicant: BASF AG
Inventor： KROENER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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公开(公告)号：CA2362511C
公开(公告)日：2008-05-06
申请号：CA2362511
申请日：2000-02-10
Applicant: BASF AG
Inventor： KLOSTERMANN RAINER , KRONER HUBERTUS , BIRK JOACHIM , HAUFF THOMAS
Abstract: The invention relates to a method for on-line monitoring and controlling the monomer conversion during emulsion polymerization. According to said method, a balance is continuously made, starting from an initialization point in time, of the heat amount Q IN fed to a reaction, the reaction enthalpy Q RE added by the supply with monomers and the amount of heat Q OUT dissipated from the reactor. A non-dissipated amount of heat Q AD is calculated on the basis of these value s which in the case of a spontaneous adiabatic reaction would result in an increase in the internal temperature and the internal pressure of the reactor. A check is carried out whether the potential adiabatic temperatures and pressures are always within the predetermined upper limits. If said upper limits are exceeded, the addition of monomers to the reactor is slowed down or stopped.
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Patent Agency Ranking
公开(公告)号：BR0008115A
公开(公告)日：2001-11-06
申请号：BR0008115
申请日：2000-02-10
Applicant: BASF AG
Inventor： KROENER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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公开(公告)号：AU3803700A
公开(公告)日：2000-08-29
申请号：AU3803700
申请日：2000-02-10
Applicant: BASF AG
Inventor： KRONER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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公开(公告)号：DE50012127D1
公开(公告)日：2006-04-13
申请号：DE50012127
申请日：2000-02-10
Applicant: BASF AG
Inventor： KROENER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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公开(公告)号：AU772839B2
公开(公告)日：2004-05-06
申请号：AU3803700
申请日：2000-02-10
Applicant: BASF AG
Inventor： KRONER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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10.发明专利
公开(公告)号：ZA200107439B
公开(公告)日：2002-09-10
申请号：ZA200107439
申请日：2001-09-10
Applicant: BASF AG
Inventor： KROENER HUBERTUS , KLOSTERMANN RAINER , BIRK JOACHIM , HAUFF THOMAS
Abstract: A method of on-line monitoring and control of monomer conversion in emulsion polymerization includes continuously balancing, as from an initialization time, the heat QIN, introduced into the reactor, the reaction enthalpy QRE introduced via the monomer feed, and the heat which has been removed from the reactor QOUT, and calculating an amount of heat which has not been removed QAD which would lead to an increase in the internal temperature and the internal pressure of the reactor in the event of a spontaneous adiabatic reaction. A check is carried out as to whether the potential adiabatic temperatures and pressures always lie below prescribed upper limits. If the upper limits are exceeded, the monomer feed to the reactor is throttled back or interrupted.
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