公开(公告)号：JP2003238303A

公开(公告)日：2003-08-27

申请号：JP2002362122

申请日：2002-12-13

Applicant: BASF AG

Inventor： BRATZ MATTHIAS ,  JAEGER KARL-FRIEDRICH

IPC: A01N25/08 ,  A01N25/04 ,  A01N25/14 ,  A01N31/14 ,  A01N33/18 ,  A01N33/20 ,  A01N33/22 ,  A01N37/06 ,  A01N37/10 ,  A01N37/22 ,  A01N37/32 ,  A01N37/34 ,  A01N37/38 ,  A01N39/04 ,  A01N41/04 ,  A01N43/08 ,  A01N43/24 ,  A01N43/28 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/653 ,  A01N43/824 ,  A01N43/84 ,  A01N47/12 ,  A01N47/18 ,  A01N47/22 ,  A01N47/34 ,  A01N47/38 ,  A01N53/04 ,  A01N53/08 ,  A01N55/00 ,  A01N55/02 ,  A01N57/10 ,  A01N57/14 ,  A01N57/16 ,  A01N57/22 ,  A01N59/00 ,  A01N61/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for preparing a solvent-free suspension of low- melting point and water-insoluble solid agrochemical active ingredients. SOLUTION: The method for preparing the solvent-free suspension comprises suspending 1-40 wt.% silica-based carrier in 40-97 wt.% water in the presence of 1-40 wt.% anionic dispersant, heating the resultant suspension to a temperature not lower than that of the active ingredient and adding, with stirring, 1-25 wt.% active ingredient with a melting point of ≤80°C or mixture of at least two kinds of active ingredients, where each component of the mixture has a melting point of ≤80°C. A stable concentrated suspension, a water- dispersible powder and water-dispersible particles each using the suspension as a base are each prepared by the method. COPYRIGHT: (C)2003,JPO

公开(公告)号：JP2006036773A

公开(公告)日：2006-02-09

申请号：JP2005212835

申请日：2005-07-22

Applicant: Basf Ag ,  ビーエーエスエフ アクチェンゲゼルシャフトBASF Aktiengesellschaft

Inventor： VON DER HEYDE JUERGEN ,  KOBER REINER ,  BRATZ MATTHIAS ,  BERGHAUS RAINER ,  JAEGER KARL-FRIEDRICH ,  FRIES JUERGEN ,  PARG ADOLF

IPC: A01N35/10 ,  A01N25/04 ,  A01N35/06 ,  A01N39/02 ,  A01N43/14 ,  A01N43/16 ,  A01N43/18 ,  A01N57/20 ,  C07D309/06

CPC classification number: C07D309/06 ,  A01N43/16 ,  A01N57/20 ,  A01N43/80 ,  A01N43/56 ,  A01N43/18 ,  A01N37/44 ,  A01N35/10 ,  A01N25/04 ,  A01N25/02 ,  A01N2300/00

Abstract: PROBLEM TO BE SOLVED: To provide an oleophilic suspension formulation concentrate which is herbicidic and fully storage-storable.
SOLUTION: The crop protective active component formulation which is substantially anhydrous essentially consists of (a) a cyclohexenone oxime ether such as shown below, i. e., sethoxydim, cycloxydim, tralkoxydim, butroxydim, or 2-[1-(2-p-chlorophenoxypropyloxy)iminobutyl]-5-(tetrahydrothiopyran-3-yl)-3-hydroxycyclohex-2-enone, especially clethodium or 2-[1-(3-chloroallyloxy)iminopropyl]-5-(tetrahydropyran-4-yl)-3-hydroxycyclohex-2-enone, (b) N-phosphonomethyl glycine and DL-homoalanin-4-yl(methyl)phosphinic acid, (c) 20 to 80 wt.% aprotic or weakly protic solvent in which (a) and (b) are suspended, and (d) an emulsifier, a surfactant, and/or an activity enhancing additive.
COPYRIGHT: (C)2006,JPO&NCIPI

Abstract translation: 要解决的问题：提供一种亲油性悬浮液制剂浓缩物，其为除草剂并且完全储存可储存。 解决方案：基本上无水的作物保护性活性组分制剂基本上由（a）如下所示的环己烯酮肟醚组成， 或2- [1-（2-对氯苯氧基丙酰氧基）亚氨基丁基] -5-（四氢噻喃-3-基）-3-羟基环己-2-烯酮，尤其是Cryhodium或2- [1-（3-氯烯丙氧基）亚氨基丙基] -5-（四氢吡喃-4-基）-3-羟基环己-2-烯酮，（b）N-膦酰基甲基甘氨酸和DL-高丙氨酸-4-基（甲基）次膦酸， （c）其中悬浮有（a）和（b）的20至80重量％的非质子或弱质子溶剂，和（d）乳化剂，表面活性剂和/或活性增强添加剂。 版权所有（C）2006，JPO＆NCIPI

公开(公告)号：WO2008015280A2

公开(公告)日：2008-02-07

申请号：PCT/EP2007058092

申请日：2007-08-03

Applicant: BASF AG ,  BRATZ MATTHIAS ,  BERGHAUS RAINER ,  STEINBRENNER ULRICH

Inventor： BRATZ MATTHIAS ,  BERGHAUS RAINER ,  STEINBRENNER ULRICH

CPC classification number: A01N43/56 ,  A01N25/30 ,  A01N37/44 ,  A01N37/40 ,  A01N37/10 ,  A01N2300/00

Abstract: The invention relates to an aqueous active ingredient concentrate, comprising in dissolved form: a) at least one 4-benzoyl-substituted pyrazol compound of the formula (I), wherein R 1 , R 3 independently of each other stand for hydrogen, halogen, methyl, halogen methyl, methoxy, halogen methoxy, methylthio, methyl sulfinyl, or methyl sulfonyl; R 2 stands for a 5-membered heterocyclic residue, which is unsubstituted, or which carries 1, 2, 3, or 4 substituents, which are selected from halogen, C 1 -C 6 -alkyl, C 1 -C 4 -akoxy, C 1 -C 4 -halogenalkyl, C 1 -C 4 -halogen alkoxy, and C 1 -C 4 -alkylthio; R 4 stands for hydrogen, halogen, or methyl; R 5 stands for C 1 -C 6 -alkyl, C 3 -C 6 -cycloalkyl, or C 3 -C 6 -cycloalkyl methyl; and R 6 stands for hydrogen or C 1 -C 4 -Alkyl; or one of its salts used in agriculture; b) at least one benzoic acid compound of the formula (II), wherein R 7 stands for hydrogen, halogen, hydroxy, or methoxy, and R 8 stands for hydrogen, halogen, or amino; or one of its salts used in agriculture; and c) have at least one non-ionic surface-active substance S, selected from polyether compounds having repeat units derived from ethylene oxide, alkyl polyglycosides, and mixtures thereof.

Abstract translation: 本发明涉及一种含水的活性化合物的浓缩物，其包括，以溶解的形式：a）至少一个4-苯甲酰基取代的式（I）其中R ^{1 ，R 3 彼此独立的吡唑化合物 是氢，卤素，甲基，卤代甲基，甲氧基，卤代甲氧基，甲硫基，甲基亚磺酰基或甲基磺酰基; [R 2 表示5元杂环基团，其是未取代的或1，2，携带选自卤素3或4个取代基，C _{1 -C 6 烷基，C 1 -C 4 -Akoxy，C 1 -C 4 - 卤代烷基，C 1 -C 4 卤代烷氧基，和C 1 -C 4 烷硫基; [R 4 是氢，卤素或甲基; [R 5 C 1 -C 6 烷基，C 3 -C 6 环烷基或C 3 -C 6 代表环烷基甲基; 且R 6 1 -C 4 是烷基氢，或C; 或其农业上有用的盐之一; 式b）至少一种苯甲酸化合物（II），其中R 7 - [R 8 是氢，卤素，羟基或甲氧基并且是氢，卤素或氨基; 或其农业上有用的盐之一; 和c）至少一种非离子表面活性剂S，从具有从环氧乙烷，烷基聚糖苷和它们的混合物衍生的重复单元的聚醚化合物。}}

公开(公告)号：WO2007036494A3

公开(公告)日：2007-05-18

申请号：PCT/EP2006066663

申请日：2006-09-25

Applicant: BASF AG ,  BRATZ MATTHIAS ,  AUWETER HELMUT

Inventor： BRATZ MATTHIAS ,  AUWETER HELMUT

IPC: A01N25/10 ,  A01N25/04 ,  A01P3/00 ,  A01P7/02 ,  A01P7/04 ,  A01P13/00 ,  A01P21/00

CPC classification number: A01N25/10 ,  A01N25/04 ,  A01N25/12

Abstract: The invention relates to agrochemical formulations comprising polymer particles that contain active substances. Said agrochemical formulations comprise a vinyl polymer which is composed of 10 to 80 percent by weight of monomers containing amino groups and/or carboxyl groups and is non-soluble in one portion of the 0 to 10 pH range while being soluble in another portion. The inventive agrochemical formulations are characterized in that the polymer particles containing active substances (i) comprise 3 to 1000 parts by weight of pesticide per weight ratio of vinyl polymer as an active substance; (ii) have a particle size ranging from 10nm to 100?m; (iii) > 50 percent by weight of the vinyl polymer is composed of polymers having a molecular weight

Abstract translation: 本发明涉及到按重量计的氨基和/或羧基的包含来自10 80％包含乙烯基聚合物的活性化合物fhaltige聚合物颗粒农业化学配制剂的0-10单体基团的是在pH范围的一个部分不溶性的和可溶于区域的另一部分 其特征在于所述含活性化合物的聚合物按重量计乙烯基聚合物粒子每部分F（1）为3〜1000重量份的农药作为活性成分的; （ii）颗粒大小在10纳米的范围内 - lOOμmaufweisen; （三）> 50 <100,000道尔顿的构造与乙烯基聚合物％（重量）的分子量的聚合物的; 且其中所述农药是存在于聚合物中分子分散溶解的形式; 和用于制备这些聚合物颗粒的过程，防治植物病原性真菌和/或不希望的植物生长和/或不希望的昆虫或螨虫侵染和/或用于调节使用上述颗粒的植物的生长的方法。

公开(公告)号：WO2006094978A3

公开(公告)日：2007-07-12

申请号：PCT/EP2006060516

申请日：2006-03-07

Applicant: BASF AG ,  DYLLICK-BRENZINGER RAINER ,  BRATZ MATTHIAS ,  KRUEGER CHRISTIAN ,  OETTER GUENTER ,  GOERTH FELIX CHRISTIAN

Inventor： DYLLICK-BRENZINGER RAINER ,  BRATZ MATTHIAS ,  KRUEGER CHRISTIAN ,  OETTER GUENTER ,  GOERTH FELIX CHRISTIAN

IPC: A01N25/04 ,  A01N25/10

CPC classification number: A01N25/04 ,  A01N25/10

Abstract: The invention relates to a method for producing aqueous polymer dispersions containing pesticides, having an average particle diameter of the dispersed particles of

Abstract translation: 处理用于通过油包水乳状液，其油相保持至少一种农药对应于至少一种烯属不饱和单体，以得到溶液的自由基聚合制备农药，含有具有<1000纳米的分散颗粒的平均粒径为水性聚合物分散体 至少一种农药至少一种表面活性剂具有在至少一种单体在水中乳化在和/或乳化过程中至少一种农药<500纳米的存在或在其后，将微乳液，然后自由基聚合的平均粒度以及使用由此获得的细乳液 色散那些用于控制有害微生物和/或调节植物的生长和/或用于控制不需要的植物生长和/或用于对植物和/ OD防治不希望的昆虫或螨虫的侵扰 他控制植物病原真菌和/或处理种子。

公开(公告)号：WO2006111327A2

公开(公告)日：2006-10-26

申请号：PCT/EP2006003429

申请日：2006-04-13

Applicant: BASF AG ,  KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  OETTER GUENTER ,  KRUEGER CHRISTIAN ,  SCHROF WOLFGANG ,  BRATZ MATTHIAS

Inventor： KOLTZENBURG SEBASTIAN ,  DOMBO PETER ,  OETTER GUENTER ,  KRUEGER CHRISTIAN ,  SCHROF WOLFGANG ,  BRATZ MATTHIAS

IPC: A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38 ,  A01P3/00 ,  C08F228/02

CPC classification number: C08F220/60 ,  A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  C08F220/18 ,  C08F220/38 ,  A01N2300/00

Abstract: The invention relates to preparations, in particular plant-protective preparations which contain a mixture of at least two different active plant-protective substances, wherein a) at least one active substance is selected from a conazole group (active substance 1) and b) another active plant-protective substance (active substance 2) whose water solubility at a temperature of 20 °C is less than 20 g/l., c) at least one type of copolymer CP consisting of M monomers comprising a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group and ß) at least one type of neutral monoethylenically unsaturated monomer M2, wherein the quantitative ratio between the active substance 1 and the other active plant-protective substance 2 ranges from 1:10 to 10:1. Said invention also relates to novel copolymers CP which are embodied in the form of polymers consisting of at least three types of different monoethylenically unsaturated monomers M and comprise, in the polymerisation incorporated form, a) at least one type of monoethylenically unsaturated monomer M1 comprising at least one sulphonic acid group, ß1) at least one type of neutral monoethylenically unsaturated monomer M2 whose water solubility at a temperature of 20 °C is less than 30 g/l and ß2) at least one type of neutral monoethylenically unsaturated monomer M2b whose water solubility at a temperature of 20 °C is greater than 50 g/l.

Abstract translation: 本发明涉及一种制剂，在用于作物保护特定制剂，其包含至少两个彼此不同的植物保护剂的混合物，其特征在于，a）从所述组conazoles的（活性成分1）至少一种活性物质被选择，和b）至少一个另外的作物保护活性化合物（活性成分2） 水在20℃下具有低于20克/升，其中，还含有c）至少一个烯属不饱和单体M共聚物CP建立起来，其中所述单体M的溶解度a）至少一种单烯属不饱和单体M1，其具有至少一个磺酸基团，和β）至少 包括中性的，单烯键式不饱和单体M2，其特征在于，活性成分1与至少一个另外的作物保护剂2在范围1：1的比例：10〜10度。 本发明还涉及新型共聚物CP，在至少三个彼此不同的单烯属不饱和单体的晶型M结构聚合物，其包括以共聚形式：a）至少一种单烯属不饱和单体M1，其具有至少一个磺酸基团，SS1）至少一种中性的，单烯键 不饱和单体M2A，其在水中具有在200℃下低于30克/升的溶解度，和SS2）至少一种中性，单烯属不饱和单体M2b的，其具有在20℃下在水中的溶解度高于50克/升。

公开(公告)号：WO03039249A2

公开(公告)日：2003-05-15

申请号：PCT/EP0212399

申请日：2002-11-06

Applicant: BASF AG ,  SCHROF WOLFGANG ,  HEGER ROBERT ,  BRATZ MATTHIAS ,  ZAGAR CYRILL

Inventor： SCHROF WOLFGANG ,  HEGER ROBERT ,  BRATZ MATTHIAS ,  ZAGAR CYRILL

IPC: A01N25/10 ,  A01N25/00 ,  A01N25/04 ,  A01N25/08 ,  A01N25/14 ,  A01N25/24 ,  C08K5/00 ,  C08L101/02 ,  A01N

CPC classification number: A01N25/10 ,  A01N25/14

Abstract: The invention relates to a solid crop protection formulation comprising a) at least one crop protection agent selected from the group consisting of herbicides, pesticides and fungicides, with the proviso that cinidon-ethyl is not included; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50% of the dispersed particles of the at least one crop protection agent in said solid crop protection formulation are in X-ray amorphous state. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture.

Abstract translation: 本发明涉及一种固体作物保护制剂，其包含a）至少一种选自除草剂，农药和杀真菌剂的作物保护剂，条件是不包括cinidon-ethyl; b）至少一种含有至少一种亲水和至少一种疏水单体作为聚合单元的无规自由基共聚物; 和c）任选的另外的添加剂，其中所述固体作物保护制剂中的至少一种作物保护剂的至少50％的分散颗粒是X射线无定形状态。 此外，本发明涉及制备所述制剂的方法和所述制剂在农业中的用途。

公开(公告)号：WO03039254A8

公开(公告)日：2004-05-21

申请号：PCT/EP0212401

申请日：2002-11-06

Applicant: BASF AG ,  SYMYX TECHNOLOGIES INC ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

Inventor： KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG ,  SEUFERT MICHAEL ,  HEGER ROBERT ,  LEHMANN STEPHAN ,  KARDORFF UWE ,  ZAGAR CYRILL ,  BRATZ MATTHIAS ,  CARLSON ERIC D ,  CHANG HAN TING ,  KUEBLER SIGRID C

IPC: A01N43/38 ,  A01N25/04 ,  A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  C08F220/60

CPC classification number: A01N25/10 ,  A01N37/32 ,  A01N37/46 ,  A01N25/12 ,  A01N25/04 ,  A01N2300/00 ,  A01N25/14

Abstract: The invention relates to a solid crop protection formulation comprising a) cinidon-ethyl as a crop protection agent; b) at least one random radical copolymer comprising as polymerized units at least one hydrophilic and at least one hydrophobic monomer; and c) optionally further additives, wherein at least 50 % of the dispersed cinidon-ethyl particles in said solid crop protection formulation are in an X-ray amorphous state and an aqueous dispersion formulation thereof. Additionally, the invention relates to processes for preparing said formulations and the use of said formulations in agriculture. Further, the invention relates to a random radical copolymer essentially consisting of as polymerized units a) 5 to 95 % by weight of styrene as component A; b) 5 to 95 % by weight of DMAPMAM (dimethylaminopropyl methacrylic amide) as component B; c) 0 to 98 % by weight of methyl acrylate and/or vinyl acetate as component C.

Abstract translation: 本发明涉及一种固体作物保护制剂，其包含a）作为作物保护剂的cinidon-ethyl; b）至少一种含有至少一种亲水和至少一种疏水单体作为聚合单元的无规自由基共聚物; 和c）任选的其它添加剂，其中所述固体作物保护制剂中至少50％的分散的cinidon-ethyl颗粒是X射线非晶态，以及其水分散体制剂。 此外，本发明涉及制备所述制剂的方法和所述制剂在农业中的用途。 此外，本发明涉及一种基本上由作为聚合单元a）5至95重量％的作为组分A的苯乙烯组成的无规自由基共聚物; b）5至95重量％的作为组分B的DMAPMAM（二甲基氨基丙基甲基丙烯酰胺）; c）0至98重量％的丙烯酸甲酯和/或作为组分C的乙酸乙烯酯。

公开(公告)号：BRPI9916237B1

公开(公告)日：2016-02-23

申请号：BR9916237

申请日：1999-12-15

Applicant: BASF AG

Inventor： PARG ADOLF ,  FRIES JÜRGEN ,  HEYDE JÜRGEN VON DER ,  JÄGER KARL-FRIEDRICH ,  BRATZ MATTHIAS ,  BERGHAUS RAINER ,  KOBER REINER

IPC: A01N35/10 ,  C07D309/20 ,  A01N39/02 ,  A01N43/16 ,  A01N43/18 ,  A01N57/20 ,  C07D309/06

Abstract: "formulação substancialmente isenta de água de agentes de proteção de plantações, processo para preparação de licor de aspersão para controle de plantas indesejáveis, composto, e, concentrado de suspensão de óleo". a invenção refere-se a formulação largamente anidra de ingredientes ativos agentes de proteção de planta consistindo essencialmente de: a) éter oxima ciclo-hexenona de fórmula (i): na qual r1 é etila, propila; r2 é hidrogênio ou um equivalente de cátion agriculturalmente útil; r3 é 2-(tioetil)propila, tetraidrotiopiran-3-ila, tetraidrotiopiran-4-ila, tetraidropiran-3-ila, tetraidropiran-4-ila, 1-(metiltio)ciclopropila, 5-(isopropil)-isoxazol-3-ila, 2,5-dimetilpirazol-3-ila, 2,4,6-trimetilfenila ou 2,4,6-trimetil-3-butirilfenila; r4, r5 são h, ch3, co-och3; alk é ch2ch2, ch2ch(ch3) ch2ch=ch, ch2ch=c(c1), ch2ch2ch=ch; r6 é h, fenila, fenil halogênio, fenil dialogênio, fenóxi, fenóxi halogênio, fenóxi dialogênio; b) n-fosfonometil glicina, seu éster ou sal, ácido dl-homoalanina-4-il (metil)fosfínico ou o seu sal de amônio; c) entre 20 e 80 % por peso de solvente aprótico ou fracamente prótico no qual os componentes a) e b) são postos em suspensão; d) possivelmente emulsificantes, tensídeos e aditivos ativos de superfície e/ou de reforço.

公开(公告)号：BRPI0610719B1

公开(公告)日：2015-11-24

申请号：BRPI0610719

申请日：2006-04-13

Applicant: BASF AG ,  BASF SE

Inventor： KRÜGER CHRISTIAN ,  OETTER GÜNTER ,  BRATZ MATTHIAS ,  DOMBO PETER ,  KOLTZENBURG SEBASTIAN ,  SCHROF WOLFGANG

IPC: C08F228/02 ,  A01N25/10 ,  A01N25/14 ,  A01N43/653 ,  A01N47/24 ,  A01N47/38

Abstract: preparação, processo para a produção da mesma, usos de preparações, e de copolímeros cp, e, copolímero cp. a invenção refere-se a preparações, em particular a preparações protetoras de plantas, que contêm uma mistura de pelo menos duas substâncias ativas protetoras de plantas diferentes, em que a) pelo menos uma substância ativa é selecionada de um grupo de conazol (substância ativa 1) e b) uma outra substância ativa protetora de plantas (substância ativa 2) cuja solubilidade em água a uma temperatura de 20º c é menor que 20 g/l, c) pelo menos um tipo de co-polímero cp que consiste de monômeros m que compreendem a) pelo menos um um tipo de monômero m1 monoetilenicamente insaturado que compreende pelo menos um grupo ácido sulfônico e b) pelo menos um tipo de monômero m2 neutro monoetilenicamente insaturado em que a razão quantitativa entre a substância ativa 1 e a outra substância ativa 2 protetora de plantas está na faixa de 1:10 até 10:1. a dita invenção também se refere a novos ciclopentenos cp que são incorporados na forma de polímeros que consistem de pelo menos três tipos de monômeros m monoetilenicamente insaturados diferentes e compreendem, na forma de polimerizção incorporada, a) pelo menos um tipo de monômero m1 monoetilenicamente insaturado que compreende pelo menos um grupo ácido sulfônico, b1) pelo menos um tipo de monômero m2 neutro monoetilenicamente insaturado cuja solubilidade em água a uma temperatura de 20ºc é menor do que 30 g/l e b2) pelo menos um tio de monômero m2b neutro monoetilenicamente insaturado cuja solubilidade em água a uma temperatura de 20ºc é maior que 50 g/l.