公开(公告)号：US3891511A

公开(公告)日：1975-06-24

申请号：US27236672

申请日：1972-07-17

Applicant: BASF AG

Inventor： DANNEIL AXEL ,  FLICKINGER ERICH ,  GRAEFJE HEINZ ,  PLASS REINHOLD ,  SCHNUR RUDOLF

IPC: C07C29/80 ,  C07C31/20 ,  B01D3/00

CPC classification number: C07C29/80 ,  C07C31/207

Abstract: Production of very pure butanediol-1,4 by separating in column 1 crude butanediol into a fraction A containing butanediol and lower boiling components and a fraction B containing higher boiling components, separating fraction A in column 2 into an overhead and a bottoms product consisting of very pure butanediol and separating fraction B in column 3 into butanediol of lower purity and components of higher boiling point.

Abstract translation: 通过在第1列粗丁二醇中分离成含有丁二醇和低沸点组分的级分A和含较高沸点组分的级分B，生产非常纯的丁二醇-1,4，将第2列中的馏分A分离成塔顶馏出物和由 非常纯的丁二醇和第3列中的分离馏分B为较低纯度的丁二醇和较高沸点的组分。

公开(公告)号：US3607963A

公开(公告)日：1971-09-21

申请号：US3607963D

申请日：1969-02-10

Applicant: BASF AG

Inventor： DANNEIL AXEL ,  NAGEL OTTO ,  PLATZ ROLF ,  TAGLIEBER KURT

IPC: C07C7/00 ,  F25J3/02 ,  F25J3/08 ,  F25J3/06

CPC classification number: F25J3/0238 ,  C07C7/005 ,  F25J3/0219 ,  F25J3/0271 ,  F25J2200/74 ,  F25J2205/04 ,  F25J2205/50 ,  F25J2210/12 ,  F25J2215/62 ,  F25J2245/02 ,  F25J2270/04

Abstract: Joint separation of acetylene and ethylene from cracked gas, obtained by submerged-flame methods, by condensing the hydrocarbons in one or more stages by cooling to a temperature above the solidification temperature of acetylene in admixture with the other condensable constituents, separating the condensate, washing the residual gas mixture with liquid ethylene and/or ethane, and further cooling the gas mixture free from acetylene to -140* to -170* C.

公开(公告)号：DE2055892A1

公开(公告)日：1972-05-25

申请号：DE2055892

申请日：1970-11-13

Applicant: BASF AG

Inventor： DANNEIL AXEL ,  FLICKINGER ERICH ,  GRAEFJE HEINZ ,  SCHNUR RUDOLF

IPC: C07C29/80 ,  C07C31/20

Abstract: Production of very pure butanediol -1,4 by distillation of the crude product, obtained by hydrogenation of butine -2-diol-1,4 in aq. soln., with removal of water and cpds. boiling below 120 degrees C. Process is improved by subjecting the product to a subsequent three-stage fractional distillation. In the first column, fraction A contg. 60-90 wt.% of total butanediol and components boiling below the b.pt. of butanediol and fraction B contg. 40-10 wt.% of total butanediol and higher boiling components are obtained. In the second column, fraction A is separated into a head fraction contg. low-boiling components and a still residue being high purity butanediol. In the third column, fraction B is separated into high-boiling components and butanediol, which is pref. returned to the first distillation stage. Prodn. of polyesters or polyurethanes. High-purity, water-free butanediol is obtained from the second column; less pure butanediol obtained from the third column, can be recycled or used for the prodn. of THF or butyrolactone.

公开(公告)号：CA880703A

公开(公告)日：1971-09-14

申请号：CA880703D

Applicant: BASF AG

Inventor： DANNEIL AXEL ,  TAGLIEBER KURT ,  NAGEL OTTO ,  PLATZ ROLF