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公开(公告)号:JPH0641638B2
公开(公告)日:1994-06-01
申请号:JP12543384
申请日:1984-06-20
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , HAINTSU HANNEBAUMU , HARUDOO JIIGERU , WARUTAA GURAMURITSUHI
IPC: C07C43/307 , C25B3/02
Abstract: Benzaldehyde dialkyl acetals of the formula I wherein R1 and R2 are each alkyl, are prepared by electrochemical oxidation of an alkyltoluene of the formula II by a process in which the electrolyte used contains from 60 to 90% by weight of an alkanol of the formula R2OH, from 8.5 to 40% by weight of the alkyltoluene and from 0.01 to 1.5% by weight of an HO3S-containing acid.
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公开(公告)号:JPS6240388A
公开(公告)日:1987-02-21
申请号:JP18792886
申请日:1986-08-12
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , EBAAHARUTO SHIYUTETSUKUHAN
Abstract: Preparation of aromatic carboxylic acid ortho-esters of the formula I I where R is C1-C4-alkyl and R1 is H, halogen, alkyl, aryl, heteroaryl, alkoxy, aryloxy, acyl, acyloxy or CN, by electro-oxidizing benzene derivatives of the formula II II where R2 is CH3 or CH(OR2), in the presence of an alcohol ROH, a halogenated triarylamine compound and a base, and novel ortho-trialkyl 4-tert-butoxybenzoates, where alkyl is of 1 to 4 carbon atoms. Ortho-trialkyl 4-tert-butoxybenzoates are scents and are also used to prepared p-hydroxybenzoic acid esters.
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公开(公告)号:JPS57120681A
公开(公告)日:1982-07-27
申请号:JP18850381
申请日:1981-11-26
Applicant: Basf Ag
Inventor: DEIITAA DEEGUNAA , MANFUREEDO BAARU
IPC: C25B3/10 , C07C43/305 , C25B3/02
CPC classification number: C07C43/305 , C25B3/02
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公开(公告)号:JP2532907B2
公开(公告)日:1996-09-11
申请号:JP3296188
申请日:1988-02-17
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , WARUTAA GURAMURITSUHI , RUUDOITSUHI SHUSUTAA
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公开(公告)号:JPS63284142A
公开(公告)日:1988-11-21
申请号:JP9581688
申请日:1988-04-20
Applicant: BASF AG
IPC: C07C41/00 , C07C43/315 , C07C67/00 , C11B9/00 , C25B3/02
Abstract: Benzaldehyde dialkyl acetals of the formula where R is alkyl of 1 to 4 carbon atoms, are prepared by electrochemical oxidation of 3-tert-butyl-4-methoxytoluene in the presence of an alkanol of the formula ROH and are used as scents or scent intermediates.
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公开(公告)号:JPS5589487A
公开(公告)日:1980-07-07
申请号:JP16580779
申请日:1979-12-21
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , HARUDOO JIIGERU
IPC: C25B3/02
Abstract: A process for the preparation of benzaldehydes of the general I where R1 is hydrogen or alkyl, wherein a compound of the formula II where X is hydrogen, hydroxyl or R2-COO-, and R2 is hydrogen or alkyl of 1 to 6 carbon atoms, is oxidized electrochemically in the presence of water, of an alkanoic acid of the formula R3COOH III where R3 is hydrogen or alkyl of 1 to 6 carbon atoms, and of a conductive salt.
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公开(公告)号:JP2545420B2
公开(公告)日:1996-10-16
申请号:JP31244687
申请日:1987-12-11
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , WARUTAA GURAMURITSUHI , HAINTSU HANNEBAUMU
IPC: A61K8/35 , A61K8/00 , A61Q13/00 , C07C41/00 , C07C43/315 , C07C45/00 , C07C47/575 , C07C67/00 , C11B9/00 , C25B3/02
Abstract: Benzaldehyde derivatives of the general formula I, where X is an oxygen atom or two R2O groups and R1 and R2 are alkyl radicals of 1-4 carbon atoms, their preparation, and their use as odorants or odorant intermediates. I
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公开(公告)号:JPH0143030B2
公开(公告)日:1989-09-18
申请号:JP18850381
申请日:1981-11-26
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , MANFUREEDO BAARU
IPC: C25B3/10 , C07C43/305 , C07C50/04 , C25B3/02
Abstract: 1. A process for the preparation of a mixture of ketals of trimethyl-p-benzoquinone, of the formula see diagramm : EP0053261,P4,F2 where R**1 and R**2 are alkyl of 1 to 4 carbon atoms and R**3 is R**2 O, or the two radicals R**3 together are oxygen, wherein an alkyl trimethylphenyl ether of the formula see diagramm : EP0053261,P4,F3 is oxidized electrochemically in the presence of an alkanol of the formula R**2 OH.
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公开(公告)号:JPS63203639A
公开(公告)日:1988-08-23
申请号:JP3296188
申请日:1988-02-17
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , WARUTAA GURAMURITSUHI , RUUDOUITSUHI SHIYUSUTAA
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公开(公告)号:JPS63166843A
公开(公告)日:1988-07-11
申请号:JP31244687
申请日:1987-12-11
Applicant: BASF AG
Inventor: DEIITAA DEEGUNAA , WARUTAA GURAMURITSUHI , HAINTSU HANNEBAUMU
IPC: A61K8/35 , A61K8/00 , A61Q13/00 , C07C41/00 , C07C43/315 , C07C45/00 , C07C47/575 , C07C67/00 , C11B9/00 , C25B3/02
Abstract: Benzaldehyde derivatives of the general formula I, where X is an oxygen atom or two R2O groups and R1 and R2 are alkyl radicals of 1-4 carbon atoms, their preparation, and their use as odorants or odorant intermediates. I
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