公开(公告)号：DE1193487B

公开(公告)日：1965-05-26

申请号：DEB0075849

申请日：1964-03-11

Applicant: BASF AG

Inventor： CONRAD DR RICHARD ,  EBENHOECH DR FRANZ LUDWIG

IPC: B01J21/04 ,  C01F7/44

公开(公告)号：DE1005078B

公开(公告)日：1957-03-28

申请号：DEB0037996

申请日：1955-11-22

Applicant: BASF AG

Inventor： HAMPRECHT DR GUENTHER ,  EBENHOECH DR FRANZ LUDWIG

IPC: C07C241/02

公开(公告)号：DE1235866B

公开(公告)日：1967-03-09

申请号：DEB0078093

申请日：1964-08-13

Applicant: BASF AG

Inventor： EBENHOECH DR FRANZ LUDWIG ,  SCHULZE DR GERHARD

IPC: B01J21/00 ,  B01J23/86 ,  C01B3/16

公开(公告)号：DE1080084B

公开(公告)日：1960-04-21

申请号：DEB0051060

申请日：1958-11-13

Applicant: BASF AG

Inventor： SCHILLER DR GEORG ,  EBENHOECH DR FRANZ LUDWIG ,  VEIGEL WILHELM ,  WOLFFHARDT DR EMMA

IPC: B01J20/18

公开(公告)号：DE1277213B

公开(公告)日：1968-09-12

申请号：DEB0074920

申请日：1964-01-08

Applicant: BASF AG

Inventor： RABE DR HANS ,  EBENHOECH DR FRANZ LUDWIG ,  ROEHRDANZ DIPL-ING JUERGEN

IPC: B01J23/86 ,  B01J23/94 ,  C01B3/16

公开(公告)号：DE1211629B

公开(公告)日：1966-03-03

申请号：DEB0068424

申请日：1962-08-14

Applicant: BASF AG

Inventor： SPERBER DR HEINRICH ,  POEHLER DR GUENTER ,  EBENHOECH DR FRANZ LUDWIG ,  HUPFER DR LEOPOLD

IPC: B01J21/00 ,  C07C45/00

公开(公告)号：DE1272275B

公开(公告)日：1968-07-11

申请号：DE1272275

申请日：1965-05-18

Applicant: BASF AG

Inventor： EBENHOECH DR FRANZ LUDWIG ,  ZIRKER DR GUENTER ,  GUNDEL DR FRIEDRICH

IPC: B01J23/70 ,  B01J23/755 ,  C01B3/38 ,  C01B3/40 ,  F01D25/36

公开(公告)号：DE1203235B

公开(公告)日：1965-10-21

申请号：DEB0074876

申请日：1964-01-02

Applicant: BASF AG

Inventor： LANDGRAF DR ALFRED ,  MOELL DR HANS ,  KERBER DR HORST ,  WODTCKE DR FRIEDRICH ,  EBENHOECH DR FRANZ LUDWIG ,  HUPFER DR LEOPOLD

IPC: B01J23/883 ,  C07C45/50

Abstract: Ni-containing sodium molybdate/SiO2 catalysts are used to hydrogenate sulphur-containing mixtures of aldehydes, ketenes and esters such as are obtained in oxo systheses from olefins, CO and H2. In example 3 a feed stream containing inter alia n-butyhaladehyde, isobutyraldehyde, butyl formates and butyene esters is hydrogenated, the aldehydes and substantial portions of the esters being converted to the corresponding butanols.ALSO:In a method of making Ni-containing hydrogenation catalysts, an aqueous solution which is 0.5 to 3 molar in Si and having a ratio Na:Si of 0.7 to 7:1 and a Mo:Si ratio of 0.04 to 0.2:1 which has been prepared from water-glass and sodium molybdate has added to it while stirring such an amount of a 1 to 3 molar Mi salt solution that the amount of Mi added is from 10% by weight more or less equivalent to the amount of sodium contained in the solution and the resultant precipitate is separated from the solution, moulded and reduced in hydrogen at 300 to 500 DEG C. Additionally the catalyst may contain a small quantity of magnesium.