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公开(公告)号:ES2140579T3
公开(公告)日:2000-03-01
申请号:ES95108696
申请日:1995-06-07
Applicant: BASF AG
Inventor: SCHLUND RUGER DR , LUX MARTIN DR , EDELMANN FRANK PROF DR , REISSMANN ULRIKE , ROHDE WOLFGANG DR
Abstract: A catalyst system (I) for the polymerisation of olefinic hydrocarbons contains (A) a metal-amidinato complex of formula (A) and opt. (B) an acceptor cpd. for substit. X in (A) as activator; M = Sub-Gp. III, IV, V or VI metal or lanthanide metal; X = negative leaving atom or gp. (these can be identical or different if (n = m) is greater than 1); R -R = C-organic or Si-organic gps.; n = valency of M in complex (A); m = 1-5; n - m = O or more. Also claimed is a process for the prodn. of homo- or copolymers of ethylene and other olefins by insertion polymerisation using catalyst (I). Also claimed are polymers of ethylene and alkyl- and aryl-substd. olefins obtd. by this process.