Production of organometallic compounds of sodium or potassium with alkylaromatic hydrocarbons
    1.
    发明授权
    Production of organometallic compounds of sodium or potassium with alkylaromatic hydrocarbons 失效
    用烷基芳烃生产钠或钾的有机金属化合物

    公开(公告)号:US3903184A

    公开(公告)日:1975-09-02

    申请号:US43158174

    申请日:1974-01-07

    Applicant: BASF AG

    CPC classification number: C07F1/00

    Abstract: Production of organometallic compounds of sodium and potassium with alkylaromatic hydrocarbons (X) by reaction of the metal with a monochloride of a hydrocarbon (Y) and reaction of the organometallic compound formed with the alkylaromatic hydrocarbon (X). A fine dispersion of the metal in the alkylaromatic hydrocarbon (X) is first prepared by stirring a mixture of molten metal and hydrocarbon (X) in the presence of a dispersing agent; then the monochloride of the hydrocarbon (Y) is slowly added. The sodium or potassium compounds may be used for organometallic reactions or as monofunctional polymerization catalysts.

    Abstract translation: 通过金属与烃的一氯化物(Y)的反应和与烷基芳烃(X)形成的有机金属化合物的反应,生成具有烷基芳烃(X)的钠和钾的有机金属化合物。 首先通过在分散剂的存在下搅拌熔融金属和烃(X)的混合物来制备金属在烷基芳族烃(X)中的细分散体; 然后缓慢加入烃(Y)的一氯化物。 钠或钾化合物可用于有机金属反应或用作单官能聚合催化剂。

    Catalytic hydrogenation of polymers containing double bonds
    2.
    发明授权
    Catalytic hydrogenation of polymers containing double bonds 失效
    含双重聚合物的聚合物的催化氢化

    公开(公告)号:US3673281A

    公开(公告)日:1972-06-27

    申请号:US3673281D

    申请日:1971-01-29

    Applicant: BASF AG

    CPC classification number: C08C19/02

    Abstract: A process for the catalytic hydrogenation of polymers containing double bonds by the action of hydrogen on a solution of the polymer in an inert organic solvent in the presence of a catalyst complex comprising: A. a compound of iron, cobalt or nickel, B. an organo-aluminum compound, and C. a hexa-alkylphosphoric acid triamide of the general formula OP(NR2)3 in which R stands for alkyl of from one to four carbon atoms, the catalyst components A and B being used in a molar ratio of from 1 : 40 to 1 : 1 and the components A and C in a molar ratio of from 1 : 0.5 to 1 : 100.

    Abstract translation: 在催化剂配合物存在下,通过氢气对聚合物在惰性有机溶剂中的溶液的催化剂络合物的催化剂络合物的催化氢化催化氢化方法,包括:

    TRANSPARENT POLYMER MIXTURES HAVING HIGH IMPACT STRENGTH

    公开(公告)号:CA1087340A

    公开(公告)日:1980-10-07

    申请号:CA272390

    申请日:1977-02-21

    Applicant: BASF AG

    Abstract: Mixtures of polystyrene and a block copolymer of a monovinyl-aromatic compound and a conjugated diene. The mixture contains a thermoplastic, non-elastomeric block copolymer having a star-shaped branched structure, the branches being of at least two types of different average composition, and at least 50% by weight of the monovinyl-aromatic compound being present as terminal polymer blocks in one or more of the branches. The mixtures, which exhibit good transparency and high impact strength, are particularly suitable for the manufacture of moldings and packaging materials.

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