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公开(公告)号:DE19516968A1
公开(公告)日:1996-11-14
申请号:DE19516968
申请日:1995-05-12
Applicant: BASF AG
Inventor: STUERMER RAINER DR , LAUPICHLER LOTHAR DR , KNOCHEL PAUL PROF DR , FALK LANGER
IPC: C07B53/00 , C07C45/50 , C07C209/68 , C07F9/50 , C07F15/00 , C07F9/6568 , C07F19/00 , C07B35/02 , C07B41/06 , C07C45/49 , C07B37/08 , B01J31/24 , B01J31/28
Abstract: Optically active phosphines of formula XnPRm (I) and Y(PXnRm)2 (II) and their transition metal complexes of formula (III) and (IV) are new. X = an optically active terpene residue; R = opt. substd. phenyl; Y = 1-10C bridging gp.; n = 1-3, m = 0-2 and n+m = 3; r = 1-2, s = 0-1 and r+s = 2; D = 1 equiv. of an noncoordinated anion; L = an organic ligand; M = a transition metal; p, q = 0-4.