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公开(公告)号:GB1047045A
公开(公告)日:1966-11-02
申请号:GB310964
申请日:1964-01-24
Applicant: BASF AG
Inventor: BUSCHMANN KARL , FREY OTTO , MEYER HERMANN , TELTSCHIK WALTER
IPC: C07C7/11
Abstract: In the production of acetylene from hydrocarbons by partial combustion, quenching and separating carbon black from the gas by contacting with an aromatic hydrocarbon oil, naphthalene or an a -halonaphthalene is used as the aromatic hydrocarbon oil. A portion of the naphthalene containing carbon black may be freed from carbon black and may be recycled alone or in admixture with naphthalene containing carbon black. The carbon content of the recycle naphthalene is preferably 10 to 30% by weight and naphthalene vapours entrained in the quenched gas are condensed by aromatic hydrocarbon oils having a boiling point of 80 DEG to 170 DEG C. and a specific gravity less than 0.95 which oils are preferably free from polymerizable constituents. The heat transmitted to the naphthalene may be used to preheat the hydrocarbons to be reacted, or to produce steam.
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公开(公告)号:FR1319860A
公开(公告)日:1963-03-01
申请号:FR894647
申请日:1962-04-16
Applicant: BASF AG
Inventor: DANZ WILLI , FREY OTTO , KITTEL ERICH , MARKERT FERDINAND , TELTSCHIK WALTER
Abstract: In the production of acetylene by subjecting hydrocarbons to high temperatures, the hot gas is quenched in a single stage by injecting a hydrocarbon oil boiling above 150 DEG C. in a volume ratio to gas (measured under standard conditions) of at least 1 : 100 without any appreciable cracking of the oil and separating the hot oil containing carbon black from the gas. The oil is preferably an aromatic oil and useful heat is extracted from it before its reuse; the carbon black content is preferably reduced to below 35% by weight e.g. by removing part of the oil and replacing this by fresh oil. The gas is preferably also later washed with an oil boiling in the range 80-450 DEG C. having a specific gravity below 0.95. The examples relate to the partial combustion of gasoline and of methane; reference is also made to heating hydrocarbons by electric discharge and exposure to hot flame gases. Specification 893,504 is referred to.
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公开(公告)号:FR1309611A
公开(公告)日:1962-11-16
申请号:FR883458
申请日:1961-12-29
Applicant: BASF AG
Inventor: DANZ WILLI , FREY OTTO , KITTEL ERICH , MARKERT FERDINAND , TELTSCHIK WALTER
IPC: C07C4/02
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公开(公告)号:FR1200693A
公开(公告)日:1959-12-23
申请号:FR1200693D
申请日:1958-07-29
Applicant: BASF AG
Inventor: MARKER FERDINAND , FUNK WILLIBALD , RICHTER GOTTFRIED , FREY OTTO
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公开(公告)号:FR1368443A
公开(公告)日:1964-07-31
申请号:FR946179
申请日:1963-08-30
Applicant: BASF AG
Inventor: DANZ WILLI , FREY OTTO , MEYER HERMANN , SCHUHMANN KARL
IPC: C09C1/58
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公开(公告)号:FR1309612A
公开(公告)日:1962-11-16
申请号:FR883459
申请日:1961-12-29
Applicant: BASF AG
Inventor: DANZ WILLI , FREY OTTO , KITTEL ERICH , MARKERT FERDINAND
IPC: C07C4/02
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公开(公告)号:GB824913A
公开(公告)日:1959-12-09
申请号:GB2364158
申请日:1958-07-23
Applicant: BASF AG
Inventor: MARKERT FERDINAND , FUNK WILLIBALD , RICHTER GOTTFRIED , FREY OTTO
Abstract: In the preparation of olefines, particularly ethylene and propylene, by the high-temperature cracking of hydrocarbons the gaseous reaction stream is quenched by supplying laterally to the stream one or more compact jets of liquid in an amount sufficient to cool the gas by at least 100 DEG C. and with a pressure head such that the liquid penetrates the gas and is disintegrated therein. Cracking may be effected in the presence of a fluidized solid, at 650-850 DEG C., and 1-5 atmospheres, e.g. in reactor 1, to which oxygen is also supplied. Solids are removed from the product stream by cyclone 2 from which the gaseous product leaves by pipe 4. Jets of liquid, e.g. liquid reaction products boiling below 300 DEG C., are injected into the gas from jets 6. Preferably the product of (a) the ratio of the pressure head of liquid to that of the gas (measured at the point of entry to the cooling chamber) and (b) the ratio of the mean diameter of the liquid jet to that of the gas, should lie in the range 0.01 to 3. Where several jets are used such products may differ for each jet and the jets may be in different planes. The walls of the cooling chamber are preferably washed with the cooling liquid, e.g. from atomizer 7. Products leave by line 8.
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公开(公告)号:CA735515A
公开(公告)日:1966-05-31
申请号:CA735515D
Applicant: BASF AG
Inventor: FREY OTTO , DANZ WILLI , MARKERT FERDINAND , TELTSCHIK WALTER , KITTEL ERICH
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公开(公告)号:GB942436A
公开(公告)日:1963-11-20
申请号:GB1393362
申请日:1962-04-11
Applicant: BASF AG
Inventor: DANZ WILLI , FREY OTTO , KITTEL ERICH , MARKERT FERDINAND , TELTSCHIK WALTER
Abstract: In the production of acetylene by subjecting hydrocarbons to high temperatures, the hot gas is quenched in a single stage by injecting a hydrocarbon oil boiling above 150 DEG C. in a volume ratio to gas (measured under standard conditions) of at least 1 : 100 without any appreciable cracking of the oil and separating the hot oil containing carbon black from the gas. The oil is preferably an aromatic oil and useful heat is extracted from it before its reuse; the carbon black content is preferably reduced to below 35% by weight e.g. by removing part of the oil and replacing this by fresh oil. The gas is preferably also later washed with an oil boiling in the range 80-450 DEG C. having a specific gravity below 0.95. The examples relate to the partial combustion of gasoline and of methane; reference is also made to heating hydrocarbons by electric discharge and exposure to hot flame gases. Specification 893,504 is referred to.
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公开(公告)号:GB933301A
公开(公告)日:1963-08-08
申请号:GB464462
申请日:1962-02-07
Applicant: BASF AG
Inventor: FREY OTTO , JENKNER OTTO , SCHUHMANN KARL
IPC: C07C4/02
Abstract: In the production of olefins by the autothermal cracking of hydrocarbon oils at 630 DEG -850 DEG C. in the presence of a fluidized bed of coke particles and sufficient oxygen to supply the heat of reaction, the product boiling above 250 DEG C. being recycled, the feed has less than 2,5% Conradson carbon and is mixed with at least part of the oxygen and introduced laterally into the fluidized bed which is fluidized from below by a fluidizing agent which may contain further oxygen. The feed is preferably a crude petroleum, e.g. of Bahia or Sahara origin and is mixed with 20-100% of the oxygen and also steam if desired. The recycle is introduced with the feed or separately and may also be mixed with oxygen in the latter case. Mixing is preferably effected at the point of injection, e.g. using a nozzle having an annular feed for oxygen and an inner feed for the oil. The nozzle or nozzles may be between 20 cms. above the bottom to 1m. below the top of the fluidized bed.
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