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    Manufacture of resilient compound foams
    1.
    发明授权
    Manufacture of resilient compound foams 失效
    弹性复合材料的制造

    公开(公告)号：US3840628A

    公开(公告)日：1974-10-08

    申请号：US25925072

    申请日：1972-06-02

    Applicant: BASF AG

    Inventor： STASTNY F ,  TRIESCHMANN H ,  GAETH R ,  KOERNER H

    IPC: B29C67/20 ,  B29C70/66 ,  C08J9/35 ,  B29D27/04

    CPC classification number: C08J9/35 ,  B29C67/207 ,  B29C70/66 ,  B29K2105/165 ,  C08J2375/04 ,  Y10S264/05 ,  Y10T428/2991

    Abstract: 1. IN A PROCESS FOR THE MANUFACTURE OF RESILIENT COMPOUND FOAMS WHEREIN A REACTION MIXTURE OF (A) PREFOAMED SOFT ELASTIC OLEFIN POLYMER PARTICLES HAVING A PARTICLE SIZE OF FROM ABOUT 5 TO 50 MM. AND (B) 20 TO 100 G., PER LITER OF SAID PREFOAMED PLASTICS PARTICLES, OF A FOAMABLE MIX OF POLYISOCYANATES, POLYOLS, WATER, CATALYST AND, OPTIONALLY, (C) OTHER AUXILIARIES, PLASTICIZERS, FINGICIDES, BACTERICIDES, ING OF STABILIZERS, PLASTICIZERS, FUNGICIDES, BACTERICIDES, FLAME RETARDANTS, DYES AND FILLERS IS FOAMED IN A MOLD HAVING A MOVABLE LID, THE IMPROVEMENT WHICH COMPRISES: (1) COATING WATER ONTO SAID PREFOAMED SOFT ELASTIC OLEFIN POLYMER PARTICLES, SAID PARTICLES HAVING A SMOOTH SURFACE AND BEVELLED OR ROUNDED EDGES AND FURTHER HAVING A BULK DENSITY OF FROM 5 TO 100 G./L.; (2) PLACING THE REMAINING COMPONENTS OF SAID FOAMABLE MIX IN THE MOLD WITH A LAYER OF SAID (3) COVERING SAID REMAINING COMPONENTS OF SAID FOAMABLE MIX IN THE MOLD WITH A LAYER OF SAID PREFOAMED SOFT ELASTIC OLEFIN POLYMER PARTICLES COATED WITH WATER; (4) CLOSING THE MOLD; (5) CAUSING SAID COATED PREFOAMED SOFT ELASTIC OLEFIN POLYMER PARTICLES TO CONTACT SAID REMAINING COMPONENTS OF SAID FOAMABLE MIX BY TURNING SAID MOLD; AND (6) ALLOWING THE REACTION MIXTURE TO FOAM WHEREBY A POLYURETHANE FOAM IS FORMED IN WHICH FROM 200 TO 800 ML. OF THE PREFOAMED SOFT ELASTIC OLEFIN POLYMER PARTICLES PER LITER OF FOAM ARE EMBEDDED IN SAID FOAM.

    Process for the manufacture of polymer foams containing esters of tertiary alcohols as side groups
    3.
    发明授权
    Process for the manufacture of polymer foams containing esters of tertiary alcohols as side groups 失效
    用于制造含有作为侧面组合物的​​醇类的聚合物的方法

    公开(公告)号：US3760047A

    公开(公告)日：1973-09-18

    申请号：US3760047D

    申请日：1970-12-04

    Applicant: BASF AG

    Inventor： GAETH R ,  SCHMITT B ,  BLUM D

    IPC: C08J9/00 ,  C08J9/02 ,  B29D27/08 ,  C08F3/50

    CPC classification number: C08J9/02

    Abstract: A process for the manufacture of foams by heating polymers containing polymerized units of esters of ethylenically unsaturated polymerizable acids having three or four carbon atoms with tert-butanol at elevated temperatures wherein a pH of from 2.0 to 0.1 is set up in aqueous systems of the polymers, the water is evaporated and the residue is heated to temperatures above the decomposition temperature of the carboxylic esters.

    Abstract translation: 通过将含有三个或四个碳原子的烯属不饱和可聚合酸的酯的聚合单元的聚合物与叔丁醇在高温下加热泡沫的方法，其中将pH为2.0至0.1的聚合单元在聚合物的水性体系中 ，将水蒸发并将残余物加热至高于羧酸酯分解温度的温度。

    Production of expanded ethylene polymers
    5.
    发明授权
    Production of expanded ethylene polymers 失效
    膨胀乙烯聚合物的生产

    公开(公告)号：US3818086A

    公开(公告)日：1974-06-18

    申请号：US2951570

    申请日：1970-04-17

    Applicant: BASF AG

    Inventor： STASTNY F ,  GAETH R ,  IKERT B

    IPC: C08J9/10 ,  C08J9/16 ,  B29C3/00 ,  B29D27/00

    CPC classification number: C08J9/16 ,  B29C44/3415 ,  B29C44/445 ,  B29C44/586 ,  C08J9/10 ,  C08J2323/00 ,  C08J2323/04 ,  Y10S264/05 ,  Y10S264/13 ,  Y10S264/17 ,  Y10S264/18 ,  Y10S264/64

    Abstract: Production of flexible expanded moldings from olefin polymers by heating a mixture comprising an olefin polymer, a peroxide and a solid expanding agent in a mold, which is gastight when closed and is filled with a volume of said mixture equal to from 95% to 100% of its capacity, to a temperature above the softening point of the olefin polymer and above the decomposition temperature of the peroxide and of the expanding agent, starting to release the pressure in the mold to atmospheric pressure, immediately increasing the volume of the mold to from 3 to 35 times the volume of the expansible melt within from 0.1 to 20 seconds and then cooling the expanded molding. The moldings are used as thermal and sound insulating materials and as upholstery padding.

    Abstract translation: 通过在模具中加热包含烯烃聚合物，过氧化物和固体发泡剂的混合物来生产柔性膨胀模制品，所述模具在封闭时气密并且填充有等于95％至100％的所述混合物的体积 的能力达到高于烯烃聚合物的软化点的温度并高于过氧化物和发泡剂的分解温度，开始将模具中的压力释放到大气压力，立即将模具的体积从 可膨胀熔体的体积的3至35倍在0.1至20秒内，然后冷却膨胀模制件。 模制品用作隔热材料和室内装饰衬垫。

    7.
    发明专利
    未知

    公开(公告)号：DK131899C

    公开(公告)日：1976-02-23

    申请号：DK285972

    申请日：1972-06-08

    Applicant: BASF AG

    Inventor： STASTNY F ,  TRIESCHMANN H G ,  GAETH R ,  KOERNER H H

    IPC: B29C67/20 ,  B29C70/66 ,  C08J9/35 ,  B29D27/00 ,  C08J9/22

    Abstract: Procedure for obtaining combined soft-elastic cellular plastics, by expansion, in a mold provided with a movable cover, of a reaction mixture of A) Foamed soft-elastic plastic particles of olefinic polymers with an approximate particle size of 3 to 50 mm and B) a foamable mixture of polyisocyanates, polyols, water, catalyst and, if necessary, other auxiliary agents for the production of polyurethane cellular plastics, characterized in that a component of the foamable mixture (33) is distributed on the plastic particles (A) Foamed soft-elastic, with a smooth surface and bevelled edges and whose apparent weight is between 5 and 100 g/liter, the remaining components of the foamable mixture (B) are introduced into the mold and covered with a layer of the prepared foamed soft-elastic plastic particles, after which, by turning the mold approximately 180 °, the foamable mixture (B) is brought into contact with the prepared foamed soft-elastic plastic particles so that, when they are subsequently formed foam, formed between the foamed soft-elastic plastic particles (A) a polyurethane foam plastic in which the soft-elastic plastic particles (A) are included foamed. (Machine-translation by Google Translate, not legally binding)

    9.
    发明专利
    未知

    公开(公告)号：FI47758B

    公开(公告)日：1973-11-30

    申请号：FI131665

    申请日：1965-06-02

    Applicant: BASF AG

    Inventor： STASTNY F ,  GAETH R ,  SCHMITT B ,  HAARDT U

    IPC: C04B28/26 ,  C08J9/22 ,  C08J9/236 ,  C04B43/00

    Abstract: Heat-insulating compositions are made by mixing porous plastic particles with an inorganic binder consisting of a suspension of water-containing particles of alkali metal silicate and inorganic fillers in an aqueous solution of an alkali metal silicate, and solidifying at a temperature above >0 DEG C. but below that at which the plastic sinters. Solidification can be assisted by extracting water down to a content of 20%, by treatment with carbon dioxide, or by the application of pressure. The porous plastic may be polyurethane, polystyrene, copolymers of styrene and acrylonitrile, acrylic acid, or butadiene, vinyl chloride, or copolymers of vinyl chloride and vinylidene chloride. Flame retardants such as inorganic halogen compounds or mixtures of chloroparaffins and antimony trioxide may be included. The alkali metal silicate powder is preferably sodium silicate containing 16-20% water and having an Na2O/SiO2 ratio of 1:2.0 to 1:4.0. The solution is of 15-60 DEG Be1 concentration, and the total water content varies between 25 and 75% of the weight of the silicate. Magnesia, talc, calcium carbonate, powdered asbestos, glass, quartz, zinc carbonate, sodium silicofluoride, or silica gel can be used as fillers in the ratio of 1:1 to 4:1 relative to the anhydrous silicate.

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