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公开(公告)号:DE2814814A1
公开(公告)日:1979-10-18
申请号:DE2814814
申请日:1978-04-06
Applicant: BASF AG
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公开(公告)号:DE2319361A1
公开(公告)日:1974-11-07
申请号:DE2319361
申请日:1973-04-17
Applicant: BASF AG
Inventor: SCHULZ GERHARD DIPL CHEM DR , ZIRKER GUENTER DIPL CHEM DR , WUNSCH GERD DIPL CHEM DR , GEIERHAAS HERBERT DIPL CHEM DR , KIENER VOLKER DIPL CHEM DR , KOESTER HARTWIG DIPL CHEM DR
Abstract: Cu is extracted from spent catalysts contg. Cu and/or oxides of Cu, Zn, Al and Cr which have been used for CO conversion, or methanol synthesis, by adjusting the mole ratio of ZnO/Al2O3 in the mixt. to 1:0.9 to 1:1.2 by addn. of ZnO and/or Al2O3, and heating the mixt. to at least 800 degrees C pref. 900-1100 degrees C for 1 hr before separating Cu from the other metals by dissolving in dilute nitric acid or an aq. soln. of an ammonium salt.
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公开(公告)号:DE2424818A1
公开(公告)日:1975-12-04
申请号:DE2424818
申请日:1974-05-22
Applicant: BASF AG
Inventor: GEIERHAAS HERBERT DIPL CHEM DR
IPC: B01D53/02
Abstract: Prodn. of ZnO-contg. desulphurisation compsns. having good breaking resistance, by plasticising inactive ZnO in the presence of water (pref. an aq. starch soln.) and carbonates, kneading the mixt., moulding, drying and calcining is improved by adding to the mixt. up to 20 wt.% of boehmite (w.r.t. ZnO), and using up to 20 mole % (NH4)2CO3 (w.r.t. ZnO). Desulphurisation of gases and vapours is effectively carried out using relatively inexpensive (because of the untilisation of inactive ZnO), durable absorbent (total absorption capacity at least 240 g S/kg.; breaking resistance is not 2 kg).
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