公开(公告)号：MY117371A

公开(公告)日：2004-06-30

申请号：MYPI9702534

申请日：1997-06-06

Applicant: BASF AG

Inventor： FRANZ-JOSEF BROCKER DR ,  FREIRE ERDBRUGGER CRISTINA DR ,  KLEMENS FLICK DR ,  GERD KAIBEL DR ,  GERALD MEYER DR ,  HANS-JOACHIM MULLER DR ,  PETER POLANEK DR ,  EKKEHARD SCHWAB DR

IPC: B01D3/00 ,  B01D59/32 ,  B01J8/04 ,  B01J19/24 ,  B01J19/32 ,  B01J23/44 ,  B01J35/02 ,  B01J35/06 ,  B01J37/02 ,  B01J37/34 ,  C10G49/00 ,  C10G49/02

Abstract: A CATALYST PACKING WHICH CAN BE PRODUCED BY VAPOR DEPOSITION AND/OR SPUTTERING OF AT LEAST ONE SUBSTANCE ACTIVE AS CATALYST AND/OR PROMOTOR ONTO WOVEN OR KNITTED FABRICS OR SHEETS AS SUPPORT MATERIAL IS USED IN A PROCESS FOR CATALYTIC DISTILLATION IN WHICH A HETEROGENEOUSLY CATALYZED REACTION IS COMBINED WITH A SIMULTANEOUS DISTILLATION OR RECTIFICATION OVER THE CATALYST PACKING.

公开(公告)号：PT983988E

公开(公告)日：2002-06-28

申请号：PT99117101

申请日：1999-08-31

Applicant: BASF AG

Inventor： STROEZEL MANFRED ,  HEINZ ETZRODT DR ,  CARSTEN OOST DR ,  DIETMAR WELLER DR ,  BERNHARD BOCKSTIEGEL DR ,  REIMER KLAUS ,  GERD KAIBEL DR ,  HAGEN JAEDICKE DR

IPC: B01D3/00 ,  B01D3/14 ,  B01J31/14 ,  B01D3/32 ,  B01J10/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/67 ,  C07C45/68 ,  C07C45/82 ,  C07C49/203 ,  C07C67/54 ,  C07C69/72

Abstract: Continuous production of 5-alken-2-one or 3,5-alkadien-2-one derivatives (I) by reacting a 1-alken-3-ol or 1-alkyn-3-ol derivative (II) with an alkyl acetoacetate (III) in a fractionation column to form an acetoacetate and alcohol involves (i) removing the alcohol and (ii) contacting the acetoacetate with catalyst in the lower part or bottom of the column to form (I). Continuous production of unsaturated ketones of formula (I) by reacting an unsaturated alcohol of formula (II) with an alkyl acetoacetate of formula (III) in the presence of an organoaluminum catalyst is carried out by: (a) reacting (II) with (III) on the plates of a fractionation column to form the acetoacetate of (II) and an alcohol of formula R OH; (b) removing the alcohol in the overhead stream from the column; (c) contacting the acetoacetate of (II) with the catalyst in the lower part or bottom of the column to form (I) and CO2; (d) removing the CO2 in the overhead stream from the column; and (e) withdrawing (I) in the bottoms stream from the column. R = 1-4C alkyl; R = 1-37C (un)saturated aliphatic hydrocarbyl (optionally substituted by methoxy groups), 4-12C cycloalkyl or 5-30C cycloalkylalkyl; and R = 1-5C alkyl.