5.
    发明专利
    失效

    公开(公告)号:JP2574406B2

    公开(公告)日:1997-01-22

    申请号:JP15702288

    申请日:1988-06-27

    Applicant: BASF AG

    Abstract: Methacrylic acid can be prepared with advantage by gas phase oxidation of methacrolein or isobutyraldehyde over Mo- and P-containing catalysts at from 250 DEG to 400 DEG C. with cooling of the hot reaction gas to below 100 DEG C., absorption of the methacrylic acid in a water-operated absorption column, at below 100 DEG C. and partial recycling into the oxidation reactor after admixture of methacrolein or isobutyraldehyde and oxygen by feeding a quantity of methacrolein or isobutyraldehyde equal to the quantity of methacrolein or isobutyraldehyde consumed in the reaction in liquid form together with a polymerization inhibitor into the reactor gas in the lower two-thirds of the absorber column and upstream of the feed point for the fresh methacrolein or isobutyraldehyde or down-stream of the absorption column splitting off the reactor off-gas a side stream which is washed in a wash column operated with water at

    MANUFACTURE OF METHACRYLIC ACID
    7.
    发明专利

    公开(公告)号:JPS6429339A

    公开(公告)日:1989-01-31

    申请号:JP15702288

    申请日:1988-06-27

    Applicant: BASF AG

    Abstract: Methacrylic acid can be prepared with advantage by gas phase oxidation of methacrolein or isobutyraldehyde over Mo- and P-containing catalysts at from 250 DEG to 400 DEG C. with cooling of the hot reaction gas to below 100 DEG C., absorption of the methacrylic acid in a water-operated absorption column, at below 100 DEG C. and partial recycling into the oxidation reactor after admixture of methacrolein or isobutyraldehyde and oxygen by feeding a quantity of methacrolein or isobutyraldehyde equal to the quantity of methacrolein or isobutyraldehyde consumed in the reaction in liquid form together with a polymerization inhibitor into the reactor gas in the lower two-thirds of the absorber column and upstream of the feed point for the fresh methacrolein or isobutyraldehyde or down-stream of the absorption column splitting off the reactor off-gas a side stream which is washed in a wash column operated with water at

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