公开(公告)号：JP2000169442A

公开(公告)日：2000-06-20

申请号：JP35637299

申请日：1999-11-10

Applicant: BASF AG

Inventor： WOO PETER ,  SCHULZE ANKE ,  STADLER EDMUND ,  TINTELNOT DIETER ,  HADICK UDO ,  HINRICHS RALF ,  HUERKAMP HORST ,  SOBOLEWSKI KLAUS

IPC: C08J9/06 ,  C07C269/04 ,  C07C271/02 ,  C08G18/28 ,  C08G18/32 ,  C08G18/38 ,  C08G18/79 ,  C08G101/00 ,  C08J9/08 ,  C08K5/16

Abstract: PROBLEM TO BE SOLVED: To obtain the subject solution improvable mechanical properties of a foam, e.g. wear resistance, tensile strength and appearance of an outer layer skin by including a specific alkanolamine and carbon dioxide in bonded state. SOLUTION: This solution is obtained by reacting at least one kind of alkanolamine with carbon dioxide in at least one organic compound having 60-600 molecular weight and at least one piece of hydroxyl group as a solvent. The resultant compound contains bonded state of carbon dioxide in an amount of at least 0.51 mol. per 1 mol. of alkanolamine and the alkanolamine is expressed by one of the formulae: NH2-X-OH, OH-X-Y-OH and OH-X-NR9-(CR7 R8)n5-Y-OH (X is formula I; n1, n3 and n5 are each 1-4; n2 and n4 are each 0 or 1-6; R1-R9 are each H, a 1-20C aliphatic or the like).

公开(公告)号：DE59911978D1

公开(公告)日：2005-06-02

申请号：DE59911978

申请日：1999-11-04

Applicant: BASF AG

Inventor： WOO PETER ,  KLANKE ANKE ,  STADLER EDMUND ,  TINTELNOT DIETER ,  HADICK UDO ,  HINRICHS RALF ,  HUERKAMP HORST ,  SOBOLEWSKI KLAUS ,  JAHNCKE MANFRED

IPC: C08J9/06 ,  C07C269/04 ,  C07C271/02 ,  C08G18/28 ,  C08G18/32 ,  C08G18/38 ,  C08G18/79 ,  C08G101/00 ,  C08J9/08 ,  C08K5/16

Abstract: Carbamate solutions obtained by reacting carbon dioxide with aminoalkyl-alkanolamines containing one or two terminal hydroxyl groups in hydroxyl group-containing organic solvents. Carbamate solutions, obtained by reacting alkanolamine(s) with carbon dioxide in hydroxyl group-containing organic solvent(s) with a mol. wt. of 60-600, in which the carbamate contains at least 0.51 mol bound CO2 per mol alkanolamine and the alkanolamine has the formula (I), (II) or (III) H2N-X-OH (I) HO-X-Y-OH (II) HO-X-NR -(CR R )n5-OH (III) X = -((CR R )n1NR )n2-((CR R )n3NR )n4-(CR )n5-; Y = -(NR -(CR R )n3)n4-(NR -(CR R )n1)n2-; n1, n3, n5 = 1, 2, 3 or 4; n2, n4 = 0, 1, 2, 3, 4, 5 or 6; (n2 + n4) = 1 or more; R -R = H or 1-20C aliphatic, cycloaliphatic, araliphatic or aromatic groups Independent claims are also included for processes for the production of foam, flexible foam and flexible or semi-rigid integral foam based on polyisocyanate-polyaddition products, with the aid of these carbamate solutions as blowing agents.

公开(公告)号：DE19852681A1

公开(公告)日：2000-05-18

申请号：DE19852681

申请日：1998-11-16

Applicant: BASF AG

Inventor： WOO PETER ,  SCHULZE ANKE ,  STADLER EDMUND ,  TINTELNOT DIETER ,  HADICK UDO ,  HINRICHS RALF ,  HUERKAMP HORST ,  SOBOLEWSKI KLAUS

IPC: C08J9/06 ,  C07C269/04 ,  C07C271/02 ,  C08G18/28 ,  C08G18/32 ,  C08G18/38 ,  C08G18/79 ,  C08G101/00 ,  C08J9/08 ,  C08K5/16 ,  C07D271/06

Abstract: Carbamate solutions obtained by reacting carbon dioxide with aminoalkyl-alkanolamines containing one or two terminal hydroxyl groups in hydroxyl group-containing organic solvents. Carbamate solutions, obtained by reacting alkanolamine(s) with carbon dioxide in hydroxyl group-containing organic solvent(s) with a mol. wt. of 60-600, in which the carbamate contains at least 0.51 mol bound CO2 per mol alkanolamine and the alkanolamine has the formula (I), (II) or (III) H2N-X-OH (I) HO-X-Y-OH (II) HO-X-NR -(CR R )n5-OH (III) X = -((CR R )n1NR )n2-((CR R )n3NR )n4-(CR )n5-; Y = -(NR -(CR R )n3)n4-(NR -(CR R )n1)n2-; n1, n3, n5 = 1, 2, 3 or 4; n2, n4 = 0, 1, 2, 3, 4, 5 or 6; (n2 + n4) = 1 or more; R -R = H or 1-20C aliphatic, cycloaliphatic, araliphatic or aromatic groups Independent claims are also included for processes for the production of foam, flexible foam and flexible or semi-rigid integral foam based on polyisocyanate-polyaddition products, with the aid of these carbamate solutions as blowing agents.

公开(公告)号：ES2241226T3

公开(公告)日：2005-10-16

申请号：ES99121812

申请日：1999-11-04

Applicant: BASF AG

Inventor： WOO PETER ,  KLANKE ANKE ,  STADLER EDMUND ,  TINTELNOT DIETER ,  HADICK UDO ,  HINRICHS RALF

IPC: C07C269/04 ,  C07C271/02 ,  C08J9/06 ,  C08G18/28 ,  C08G18/32 ,  C08G18/38 ,  C08G18/79 ,  C08G101/00 ,  C08J9/08 ,  C08K5/16

Abstract: La invención se refiere a soluciones de carbamato empleadas como agente de soplado para la producción de espuma de poliuretano, obtenido mediante reacción de dióxido de carbono con compuestos de aminoalquil-alcanolamina en disolventes que contienen grupos hidroxilo. Las soluciones de carbamato se obtienen mediante reacción de dióxido de carbono en disolventes orgánicos con aminoalquil-alcanolaminas que contiene uno o dos grupos terminales hidroxilo con un peso molcular de 60-600 en el que carbamato contiene al menos 0,51 moles de unión CO{sub,2} por cada mol de alcanolamina y la alcanolamina tiene la fórmula (I), (II) ó (III)NH{sub,2}-X-OH (I)OH-X-Y-OH (II)OH-X-NR{sup,9}-(CR{sup,7}R{sup,8}) {sub,n5}-Y-OH (III)en la que X es : -[(CR{sup,1}R{sup,2}) {sub,n1}-NR{sup,3}] {sub,n2}-[(R{sup,4}R{sup,5}) {sub,n3}-NR{sup,6}]{sub,n4}-(CR{sup,7}R{sup,8}) {sub,n5}-Y es -[NR{sup,6}-(CR{sup,4}R{sup,5}) {sub,n3}]{sub,n4}-[NR{sup,3}-(CR{sup,1}R{sup,2}) {sub,n1}]{sub,n2}-yn1, n3, n5 = 1, 2, 3, ó 4;n2, n4 = 0, 1, 2, 3, 4, 5, ó 6; (n2+n4) = 1 ó mas;R{sup,1}, R{sup,2}, R{sup,3}, R{sup,4}, R{sup,5}, R{sup,6}, R{sup,7}, R{sup,8} y R{sup,9} son hidrógeno o grupos alifáticos, cicloalifáticos, aralifáticos o aromáticos C{sub,1-20}.La reivindicación se refiere además a procedimientos para la producción de espuma, espuma flexible y espuma integral semirígida o flexible basada en productos de poliadición de poliisocianato, con la ayuda de estas soluciones de carbamato como agentes soplantes.

公开(公告)号：DE19854837A1

公开(公告)日：2000-05-31

申请号：DE19854837

申请日：1998-11-28

Applicant: BASF AG

Inventor： WOO PETER ,  SCHULZE ANKE ,  STADLER EDMUND ,  TINTELNOT DIETER ,  HADICK UDO ,  HINRICHS RALF

IPC: C08G18/12 ,  C08G18/40 ,  C08G18/16 ,  C08J9/34

Abstract: An integral foam material (I) based on polyurethane contains a comminuted microcellular polyisocyanate - poly-addition product (II). An Independent claim is included for a process for the production of the foam (I) by mixing isocyanate, isocyanate reactive compounds, propellant and optionally catalyst and/or conventional processing aids and/or additives in the presence of 0.1-40 wt.% of a comminuted, microcellular polyisocyanate-polyaddition product (II).